Trimethyl[2-(trifluoromethyl)phenyl]stannane

Base Information

Chemical Name:Trimethyl[2-(trifluoromethyl)phenyl]stannane
CAS No.:17113-80-3
Molecular Formula:C10H13F3Sn
Molecular Weight:308.918
Hs Code.:
DSSTox Substance ID:DTXSID80544457
Wikidata:Q82421559
Mol file:17113-80-3.mol

Synonyms:SCHEMBL8166939;DTXSID80544457;17113-80-3;Trimethyl[2-(trifluoromethyl)phenyl]stannane

Suppliers and Price of Trimethyl[2-(trifluoromethyl)phenyl]stannane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Trimethyl[2-(trifluoromethyl)phenyl]stannane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:1
Exact Mass:309.999137
Heavy Atom Count:14
Complexity:193

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:C[Sn](C)(C)C1=CC=CC=C1C(F)(F)F

Technology Process of Trimethyl[2-(trifluoromethyl)phenyl]stannane

There total 1 articles about Trimethyl[2-(trifluoromethyl)phenyl]stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

: 1066-45-1
trimethyltin(IV)chloride

: 395-47-1
[2-(trifluoromethyl)phenyl]magnesium bromide

: 17113-80-3
(CH₃)3SnC₆H₄-o-CF₃

Guidance literature:: In diethyl ether; refluxing for 2 h;;
DOI:10.1016/S0022-328X(00)83182-4

Reference yield: 80.0%

: 17113-80-3
(CH₃)3SnC₆H₄-o-CF₃

: 7637-07-2
boron trifluoride

: 30610-53-8
(difluoro)(2-trifluoromethylphenyl)borane

Guidance literature:: In tetrachloromethane; byproducts: (CH3)3Sn{BF4}; react. goes at ambient temp. for 2 d; in vac. fractionated; 4 traps at 0, -30, -78, -182°C, product in the second one;

Reference yield: 80.0%

: 12080-32-9
dichloro(1,5-cyclooctadiene)platinum(ll)

: 17113-80-3
(CH₃)3SnC₆H₄-o-CF₃

: 107529-79-3
chloro(1,2,5,6-η4-cyclooctadiene)[2-(trifluoromethyl)phenyl]platinum(II)

Guidance literature:: In further solvent(s); addn. of 3.0 mmol CF3C6H4Sn(CH3)3 to a soln. of 2.0 mmol (Pt(C8H12)Cl2)in CH2Cl2 at room temperature; stirring for 48 h at 100°C; evaporation of the solvent;; dissolving in CH2Cl2; overlayering with methanol; pptn. after 24 h at -20°C; purification in the same way; elem. anal.;;