Methanamine, N-[(2-methylphenyl)methylene]-

Base Information

• Chemical Name: Methanamine, N-[(2-methylphenyl)methylene]-
• CAS No.: 18100-53-3
• Molecular Formula: C9H11N
• Molecular Weight: 133.193
• Mol file: 18100-53-3.mol

Synonyms:

Chemical Property of Methanamine, N-[(2-methylphenyl)methylene]-

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Methanamine, N-[(2-methylphenyl)methylene]-

There total 2 articles about Methanamine, N-[(2-methylphenyl)methylene]- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

2-methylphenyl aldehyde (529-20-4) + methylamine (74-89-5) → N-[(2-methylphenyl)methylene]methanamine (18100-53-3)

Guidance literature:

at 20 ℃; for 12h;

DOI:10.1055/s-0029-1218796

Reference yield: 83.0%

methylamine hydrochloride (593-51-1) + 2-methylphenyl aldehyde (529-20-4) → N-[(2-methylphenyl)methylene]methanamine (18100-53-3)

Guidance literature:

With 1,1'-(1,4-butanediyl)bis(imidazole); In neat (no solvent); at 20 ℃; for 10h; Milling;

DOI:10.1071/CH18408

Reference yield: 100.0%

N-[(2-methylphenyl)methylene]methanamine (18100-53-3) → methyl-(2-methylbenzyl)amine (874-33-9)

Guidance literature:

With sodium tetrahydroborate; In ethanol; at 20 ℃; for 20h;

DOI:10.1016/j.bmc.2006.09.026

upstream raw materials:

2-methylphenyl aldehyde

methylamine

methylamine hydrochloride

Downstream raw materials:

methyl-(2-methylbenzyl)amine

2-MeBDI

2-(methyl(2-methylbenzyl)amino)benzaldehyde

C₁₇H₁₉NO

Refernces

• 1、 Khaligh, Nader Ghaffari,Ling, Ong Chiu,Mihankhah, Taraneh,Johan, Mohd Rafie,Ching, Juan Joon. "Mechanosynthesis of N-methyl imines using recyclable imidazole-based acid-scavenger: In situ formed ionic liquid as catalyst and dehydrating agent". . p. 194 - 199. Retrieved 2018/12/04.
• 2、 Song, Peidong,Li, Qing,Wang, Congcong,Wu, Wenfa,Mao, Xu,Wang, Jiajia,Hu, Xiangdong. "Four-Electron Electrocyclic Ring-Opening/Intermolecular [4+2] Cycloadditions of α-Hydroxycyclobutenones: Stereoselective Synthesis of Multiple Substituted δ-Lactams". supporting information. p. 1208 - 1212. Retrieved 2016/04/26.