1H-Isoindole-1,3(2H)-dione, 2-(3-methyl-3-butenyl)-

Base Information

• Chemical Name: 1H-Isoindole-1,3(2H)-dione, 2-(3-methyl-3-butenyl)-
• CAS No.: 20213-82-5
• Molecular Formula: C13H13NO2
• Molecular Weight: 215.252
• Mol file: 20213-82-5.mol

Synonyms:N-(3-Methyl-3-butenyl)phthalimide;N-<3-Methylbuten-(3)-yl>-phthalimid;N-(3-methylbut-3-enyl)phthalimide;2-(3-Methyl-but-3-enyl)-isoindole-1,3-dione;N-(2-methyl-propenyl)-phthalimide;N-(3-methyl-but-3-enyl)-phthalimide;N-1-<3-Methyl-butenyl-(3)>-phthalimid;

Chemical Property of 1H-Isoindole-1,3(2H)-dione, 2-(3-methyl-3-butenyl)-

Chemical Property:

• Melting Point: 51.2-52.8 °C
• Boiling Point: 325.3±21.0 °C(Predicted)
• PSA: 37.38000
• Density: 1.166±0.06 g/cm3(Predicted)
• LogP: 2.18670

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 1H-Isoindole-1,3(2H)-dione, 2-(3-methyl-3-butenyl)-

There total 1 articles about 1H-Isoindole-1,3(2H)-dione, 2-(3-methyl-3-butenyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23.0%

2-(3-bromo-3-methylbutyl)-isoindoline-1,3-dione (1198105-11-1) + acetonitrile (75-05-8,26809-02-9) → N-prenylphthalimide (15936-45-5) + N-phthaloyl-3-acetamido-3-methylbutylamine + 2-(3-fluoro-3-methylbutyl)isoindoline-1,3-dione + 2-(3-methyl-but-3-enyl)-2,3-dihydro-1H-isoindole-1,3-dione (20213-82-5)

Guidance literature:

With silver fluoride; at 20 ℃; for 12h;

DOI:10.1002/anie.201708197

Reference yield: 86.0%

methanol (67-56-1) + trimethylphenylsilane (768-32-1) + 2-(3-methyl-but-3-enyl)-2,3-dihydro-1H-isoindole-1,3-dione (20213-82-5) → C20H21NO3 (1379761-57-5)

Guidance literature:

With 1-hydroxy-1,2-benzodioxol-3-(1H)-one; (triphenylphosphine)gold(I) chloride; toluene-4-sulfonic acid; In α,α,α-trifluorotoluene; at 70 ℃; for 4h;

DOI:10.1002/chem.201103061

Reference yield: 80.0%

diphenyldisulfane (882-33-7) + 2-(3-methyl-but-3-enyl)-2,3-dihydro-1H-isoindole-1,3-dione (20213-82-5) → 4-nitro-2-(2-(phenylthio)ethyl)isoindoline-1,3-dione (41010-04-2)

Guidance literature:

2-(3-methyl-but-3-enyl)-2,3-dihydro-1H-isoindole-1,3-dione; With ozone; In methanol; at -78 ℃;

diphenyldisulfane; In methanol; at -78 - 0 ℃; for 0.166667h; Inert atmosphere;

With ferrous(II) sulfate heptahydrate; In methanol; water; at 0 ℃; Inert atmosphere;

DOI:10.1021/acs.orglett.9b03186

upstream raw materials:

2-(3-bromo-3-methylbutyl)-isoindoline-1,3-dione

acetonitrile

Downstream raw materials:

C₂₈H₃₀N₂O₅S

C₁₃H₁₂FNO₂

C₁₄H₁₆FNO₃

C₂₀H₂₁NO₃