(2S,3S,4S,5S)-2,3,4,5-Tetrahydroxyhexanedioic acid

Base Information

• Chemical Name: (2S,3S,4S,5S)-2,3,4,5-Tetrahydroxyhexanedioic acid
• CAS No.: 22076-54-6
• Molecular Formula: C6H10O8
• Molecular Weight: 210.141
• Mol file: 22076-54-6.mol

Synonyms:mannaric acid;D-Mannarsaeure;d-Mannozuckersaeure;D-manno-2,3,4,5-Tetrahydroxy-adipinsaeure;Mannarsaeure;

Chemical Property of (2S,3S,4S,5S)-2,3,4,5-Tetrahydroxyhexanedioic acid

Chemical Property:

• PSA: 155.52000
• LogP: -3.40080

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (2S,3S,4S,5S)-2,3,4,5-Tetrahydroxyhexanedioic acid

There total 36 articles about (2S,3S,4S,5S)-2,3,4,5-Tetrahydroxyhexanedioic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(2E,4E)-2,4-hexadienedioic acid (3588-17-8) → meso-galactaric acid (526-99-8,1213827-87-2,7231-46-1) + DL-idaric acid (87-73-0,526-99-8,527-00-4,608-60-6,5627-26-9,5666-23-9,5768-54-7,6543-97-1,7558-19-2,22076-54-6,25525-21-7,33012-63-4,57030-41-8,80876-58-0,117468-78-7,117468-79-8,7231-46-1)

Guidance literature:

With sodium chlorate; osmium(VIII) oxide; acetic acid;

Reference yield:

(2E,4E)-2,4-hexadienedioic acid (3588-17-8) + acetic acid (64-19-7,77671-22-8) → DL-tartaric acid (133-37-9,138508-61-9) + meso-galactaric acid (526-99-8,1213827-87-2,7231-46-1) + DL-idaric acid (87-73-0,526-99-8,527-00-4,608-60-6,5627-26-9,5666-23-9,5768-54-7,6543-97-1,7558-19-2,22076-54-6,25525-21-7,33012-63-4,57030-41-8,80876-58-0,117468-78-7,117468-79-8,7231-46-1) + oxalic acid (144-62-7,97993-78-7)

Guidance literature:

Reference yield:

mannitol (69-65-8) + water (7732-18-5) → D-Mannose (3458-28-4) + mannonic acid (642-99-9) + D-mannaric acid (22076-54-6,7231-46-1)

Guidance literature:

at 80 - 85 ℃; Geschwindigkeit;

DOI:10.1021/ja01276a001

upstream raw materials:

D-Mannose

mannitol

D-mannaro-1,4:6,3-dilactone

nitric acid

Downstream raw materials:

furan-2,5-dicarboxylic acid

D-mannaro-1,4:6,3-dilactone

idaric acid bis-(N'-phenyl-hydrazide)

L-idaric acid

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