Dimethyl(thiophen-2-yl)silane

Base Information

• Chemical Name: Dimethyl(thiophen-2-yl)silane
• CAS No.: 23395-45-1
• Molecular Formula: C6H10SSi
• Molecular Weight: 142.297
• DSSTox Substance ID: DTXSID30782069
• Mol file: 23395-45-1.mol

Synonyms:Dimethyl(thiophen-2-yl)silane;23395-45-1;dimethyl(2-thienyl)silane;SCHEMBL8116133;DTXSID30782069

Chemical Property of Dimethyl(thiophen-2-yl)silane

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 141.01942300
• Heavy Atom Count: 8
• Complexity: 72.9

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C[Si](C)C1=CC=CS1

Technology Process of Dimethyl(thiophen-2-yl)silane

There total 4 articles about Dimethyl(thiophen-2-yl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,1,2,2-tetramethyl-1,2-di(thiophen-2-yl)disilane (124733-24-0) → dimethyl-thiophen-2-yl-silane (23395-45-1) + dimethyl-bis-(2'-thiophenyl)silane (17888-49-2) + 1,1,3,3-tetramethyl-1,3-bis(2'-thienyl)disiloxane (124733-28-4) + 1,1,3,3-tetramethyl-1-(2'-thienyl)disiloxane + phenyl-2'-thienyldimethylsilane

Guidance literature:

In benzene; for 2h; Product distribution; Mechanism; Irradiation;

DOI:10.1016/0022-328X(89)88003-9

Reference yield:

1,1,1-trideuteromethanol (1849-29-2) + 1,1,2,2-tetramethyl-1,2-di(thiophen-2-yl)disilane (124733-24-0) → dimethyl-thiophen-2-yl-silane (23395-45-1) + dimethyl-bis-(2'-thiophenyl)silane (17888-49-2) + 1,1,3,3-tetramethyl-1,3-bis(2'-thienyl)disiloxane (124733-28-4) + dimethyl-D3-methoxysilane (124733-26-2) + C7H9(2)H3OSSi

Guidance literature:

In benzene; for 3h; Mechanism; Product distribution; Irradiation;

DOI:10.1016/0022-328X(89)88003-9

Reference yield:

methanol (67-56-1) + 1,1,2,2-tetramethyl-1,2-di(thiophen-2-yl)disilane (124733-24-0) → dimethyl-thiophen-2-yl-silane (23395-45-1) + dimethyl-bis-(2'-thiophenyl)silane (17888-49-2) + dimethylmethoxysilane (18033-75-5) + Methoxy-dimethyl-thiophen-2-yl-silane (124733-25-1)

Guidance literature:

In benzene; for 2h; Mechanism; Product distribution; Irradiation;

DOI:10.1016/0022-328X(89)88003-9

upstream raw materials:

methanol

1,1,2,2-tetramethyl-1,2-di(thiophen-2-yl)disilane

1,1,1-trideuteromethanol

d⁽⁴⁾-methanol

Downstream raw materials:

1-[3-(Dimethyl-thiophen-2-yl-silanyl)-propyl]-azepane

(Z)-4-methyl-4-tert-butyl-3-[(dimethyl-α-thienylsilyl)methylene]-3-(p-tosyl)-1-azetidin-2-one