Cephalosporin

A class of antibiotics with a similar structure to penicillin

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SYNTHESIS OF CEPHALOSPORIN R-SULFOXIDES AND THEIR ANTIBACTERIAL PROPERTIES
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- (5R,6R,7R)-7-[2-(3,4-Dimethoxy-phenyl)-acetylamino]-3-methyl-5,8-dioxo-5λ⁴-thia-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid
A mild and convenient synthesis of penicillin and cephalosporin sulfoxides
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- TRICHLOROETHYL 6-(PHENYLACETAMIDO)PENICILLANATE S-OXIDE
Discovery of RWJ-54428 (MC-02,479), a new cephalosporin active against resistant gram-positive bacteria
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- ethyl (2-aminothiazol-4-yl)-2-(Z)-(trityloxyimino)acetate
A novel cephalosporin dehydrothiazine ring cleavage mode
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- 4-[1-Dimethylamino-meth-(Z)-ylidene]-3-methyl-5,5,8-trioxo-7-(2-phenoxy-acetylamino)-5λ⁶-thia-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid allyl ester
Cephalosporin nitrogen mustard carbamate prodrugs for 'ADEPT'
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- (6R,7R)-3-{[Bis-(2-hydroxy-ethyl)-carbamoyloxy]-methyl}-8-oxo-7-(2-thiophen-2-yl-acetylamino)-5-thia-1-aza-bicyclo[4.2.0]oct-2-ene-2-carboxylic acid benzhydryl ester

Synthesis Antibacterial Spectrophotometry Antimicrobial activity Hydrolysis Mass spectrometry (MS) High-performance liquid chromatography (HPLC) Properties Nuclear Magnetic Resonance (NMR) Ring cleavage Nucleophilic Attack Discovery Enzymatic Hydrolysis Tautomerization Oxidative Stress Experimental Prodrugs ADEPT (Antibody-Directed Enzyme Prodrug Therapy) Convenient Mechanistic study Sulfoxides Mild Penicillin Electrophilic center Carbamate Gram-positive bacteria Degradation Pathway β-lactamase Stability testing Reactive oxygen species (ROS) Thiol group (-SH)

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