Preference for the dienophile to orient with substituents inside (endo) or outside (exo) the forming ring.
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1-Methylene-2-(acetoxymethyl)cyclohexane
3-endo-(p-Toluenesulfonyl)bicyclo<2.2.2>-oct-5-ene-2-exo-carbaldehyde
Silane, (1,1-dimethylethyl)dimethyl[[(2E)-1-methylene-3-(3,4,5-trimethoxyphenyl )-2-propenyl]oxy]-