The non-natural residue should be orthogonal to the endogenous amino acids, meaning it should not be recognized by the host organism's translation machinery. This requires that the structure of the residue is distinct enough from natural amino acids to prevent cross-reactivity with endogenous tRNA synthetases and ribosomes.
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FMOC-5-AMINOPENTANOIC ACID
1H-Imidazole-2-carboxylicacid,4-amino-1-methyl-(9CI)
