Radical stabilization

Delocalization or inductive effects that lower the energy of a radical intermediate.

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Synthesis Regioselectivity Diastereoselectivity GC-MS Column chromatography Yield NMR spectroscopy Kinetic studies Steric hindrance DFT calculations Free radical Ring closure Phenols Anhydrous conditions Leaving group Stereocontrol Intramolecular Reaction UV-Vis Spectroscopy Substituent Effects Stereoselectivity Substrate Radical Cyclization Radical Initiator Kinetic Control Thermodynamic Control 1-Substituted Initiator Conformational Control Magnetic Susceptibility Hydrogen Abstraction Acyclic Transition state Arrhenius equation Radical intermediate Catalytic amount Inert atmosphere Spin-Spin Coupling DFT (Density Functional Theory) Hammett plot Reaction quenching Radical trapping BOND DISSOCIATION ENERGY (BDE) Radical Allylation EPR (Electron Paramagnetic Resonance)

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