Controlling the conformation of reactants through ring strain or other structural factors can impact diastereoselectivity.
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(1S,3S)-3-Benzenesulfonyl-4-methyl-1-phenyl-pent-4-en-1-ol
C106H105N5O14S2
Phenanthrene, 9,10-dihydro-1-phenyl-
6-O-tert-butyldiphenylsilyl-3-deoxy-1,2-O-isopropylidene-α-D-ribo-hexofuranose
(3-amino-benzyl)-pyridin-3-yl-amine
(1S,2R,3S)-2,3-Dimethyl-2-vinyl-cyclohexanol
C10H19NO2