In addition to cyclic voltammetry, you may use other techniques like spectroelectrochemistry to probe the changes in the electronic structure of the complexes during the redox processes. This can provide information about the nature of the transitions and electronic changes.
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ReOCl(N,N'-phenylenebis(salicylidene)diiminate)
2-BROMO-3-CHLORO-1-PROPENE
