SUPEROXIDE-MEDIATED DEHYDROHALOGENATION REACTIONS OF THE PYRETHROID PERMETHRIN AND OTHER CHLORINATED PESTICIDES

DOI: 10.1016/S0040-4039(00)85557-4

Source and publish data:

Tetrahedron Letters p. 5003 - 5004 (1982)

Update date:2022-07-30

Topics: Oxidation Electron transfer Lewis acid QSAR (quantitative structure-activity relationship) Selectivity Bioassay Ligand Nucleophile Electrophile Addition reaction Reduction Steric hindrance Catalytic hydrogenation Hydrolysis Adsorption Thermal decomposition Cyclic voltammetry Antioxidant High-performance liquid chromatography (HPLC) Photolysis coordination complex Catalytic effect Leaving group Chelation Density functional theory (DFT) Aromaticity Substitution Reaction Reducing Agent Toxicity Assessment Elimination Reaction Electrochemical Cell Ligand Exchange Substrate Specificity Kinetic Study Photocatalysis Oxidizing agent Temperature Dependence Biotransformation Nucleophilicity Molecular Dynamics Simulation Charge separation Quantum Yield Tautomerization Electron Paramagnetic Resonance (EPR) Stoichiometry Radical Chain Reaction Oxidative Stress Gas Chromatography-Mass Spectrometry (GC-MS) Dehydrohalogenation Transition State Theory

Authors:

Dureja, Prem

Casida, John E.

Ruzo, Luis O.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)85557-4

Superoxide generated in DMF readily converts the dihalovinyl group of permethrin and related compounds to a haloethynyl moiety and yields major products from elimination reactions of DDT, cis-chlordane, and 1,2-dibromo-3-chloropropane (DBCP).

Full text of DOI:10.1016/S0040-4039(00)85557-4

Products guided by the article

Product name:(1R,3S)-3-Chloroethynyl-2,2-dimethyl-cyclopropanecarboxylic acid 3-phenoxy-benzyl ester

Cas No:85576-82-5

R&D Labs maybe for 85576-82-5

Kaymossy BioChem Tech Co., Ltd

website:http://www.kaimosi.com

Contact:0571-87191913/0571-87199097

Address:Room 215, Building 3rd, No.288 Ningxia Road, Qingdao city, China
LIANYUNGANG YC FINE CHEMICAL CO., LTD

Contact:+86-518-858 99188

Address:Shangdong Modern Bldg, South Greenpark Road, Lianyungang, Jiangsu Pro. China
Zibo Ocean International Trade Co.,Ltd(expird)

Contact:+86 533 5160706

Address:1117, Hongtai Bld., Songling rd, Zichuan,Zibo,Shandong,China
Weifang Dongxing Chitosan Factory

website:http://dxchitosan.lookchem.com/

Contact:13475651157

Address:Weifang city ,shandong province
Xiamen Goodhealth Pharmchem Co., Ltd.

Contact:0086-592-2097683

Address:404R No.2 54# Minzu Rd., Xiamen, China

Relevant to this article

A one-pot synthetic strategy for construction of the dibenzodiazepine skeleton via a transition metal-free process

Doi:10.1039/c4ob00871e
(2014)
ONE-POT PALLADIUM-CATALYZED SYNTHESIS OF 2,3-DISUBSTITUTED BICYCLO<2.2.1>HEPTANES AND BICYCLO<2.2.1>HEPT-5-ENES

Doi:10.1016/S0040-4039(00)85642-7
(1982)
Conformationally restricted analogues of both (S)-β-homoserine and (S)-aspartic acid from chiral 3-acylamino pyrrolidin-2-ones

Doi:10.1016/j.tet.2005.03.129
(2005)
A re(V)-catalyzed C-N bond-forming route to human lipoxygenase inhibitors

Doi:10.1021/ol050897a
(2005)
Design, synthesis and evaluation of novel cinnamic acid derivatives bearing N-benzyl pyridinium moiety as multifunctional cholinesterase inhibitors for Alzheimer’s disease

Doi:10.1080/14756366.2016.1256883
(2017)
Photoinduced molecular transformations. 157. A new stereo- and regioselective synthesis of 2,6-diaryl-3,7-dioxabicyclo[3.3.0]octane lignans involving a β-scission of alkoxyl radicals as the key step. New total syntheses of (±)-sesamin, (±)-eudesmin, and (±)-yangambin

Doi:10.1021/jo00115a021
(1995)

Article Doi