tert-Butyl hydroperoxide (TBHP) serves as the source of peroxide radicals. The peroxide radical generated from TBHP is key to the hydrogen atom transfer process, which is a central step in the hydrofunctionalization of alkenes. These radicals are involved in abstracting hydrogen atoms from the alkyl group, enabling the addition of functional groups to the alkene in a Markovnikov-selective manner.
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2-chloropropyl 4-methoxybenzoate
3-(tert-butylperoxy)-3-(4-nitrobenzyl)pentane-2,4-dione
