Understanding the transition state of the reaction is crucial for diastereoselectivity control. The design of reaction conditions and reactants can be tailored to favor one transition state over another.
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(1S,3S)-3-Benzenesulfonyl-4-methyl-1-phenyl-pent-4-en-1-ol
(1S,4R,7R,8S)-7-(4-bromophenyl)-5,5-dimethyl-8-nitrobicyclo[2.2.2]octan-2-one
