- 101385-69-72-Chloro-1,3-dimethylimidazolidinium hexafluorophosphate
- 101385-90-4(S)-1-Benzyl-3-pyrrolidinol
- 101385-93-71-BOC-3-Pyrrolidinone
- 10138-59-71,2-Cyclohexanedicarboxylicacid, 1,2-diethyl ester
- 10138-62-2Holmium chloride(HoCl3)
- 1013-88-3Benzophenone imine
- 10138-94-0Uranate(2-),bis(acetato-kO)dioxo-,zinc (1:1)
- 10138-99-5L-Alanine,3-(dimethylamino)-
- 10-13-94-[(E)-2-(3,5-dihydroxyphenyl)ethenyl]-2-methoxy-benzene-1,3-diol
- 10139-02-3a-D-Glucopyranoside, 4-nitrophenyl2-(acetylamino)-2-deoxy-
Hot Products
- 101385-93-7N-Boc-3-pyrrolidinone
- 10139-51-2Cerium(IV) ammonium nitrate
- 101-42-8FENURON
- 101-43-92-Methyl-2-propenoic acid cyclohexyl ester
- 101484-02-0
- 101519-13-5Dipotassium tris(1,2-benzenediolato-O,O')silicate
- 101-65-5diphenyl (methylenedi-4,1-phenylene)-dicarbamate
- 101-67-7Dioctyldiphenylamine
- 104987-11-3Tacrolimus
- 141-53-7Sodium formate
- 8001-54-5Quaternary ammonium compounds, alkylbenzyldimethyl, chlorides
- 9003-39-8Povidone
- 10161-34-9Trenbolone acetate
- 402957-28-2Telaprevir
- 68-19-9Cyanocobalamin
|
Basic Information |
|
Post buying leads |
|
Suppliers |
|
Cas Database |
| Name |
Trichlorogadolinium |
EINECS | 233-386-6 |
| CAS No. | 10138-52-0 | Density | 4500 kg m-3 |
| PSA | 0.00000 | LogP | 2.06850 |
| Solubility | Soluble in water | Melting Point |
602°C-609°C |
| Formula | Cl3Gd | Boiling Point | 1580°C |
| Molecular Weight | 263.609 | Flash Point | N/A |
| Transport Information | N/A | Appearance | white crystalline solid |
| Safety | Poison by intraperitoneal route. A skin and eye irritant. When heated to decomposition it emits very toxic fumes of Cl−. See also CHLORIDES, GADOLINIUM, and RARE EARTHS. | Risk Codes | 38 |
| Molecular Structure |
|
Hazard Symbols |
 Xi
|
| Synonyms |
Gadoliniumchloride; Gadolinium trichloride; Gadolinium(III) chloride; NSC 174322 |
Article Data | 88 |
Trichlorogadolinium Synthetic route
- 10138-52-0
gadolinium(III) chloride
| Conditions | Yield |
|---|---|
| In neat (no solvent, solid phase) byproducts: H2O; Schlenk techniques; heating Gd compd. under vacuum (1E-3 Torr); | 99% |
- 10138-52-0
gadolinium(III) chloride
| Conditions | Yield |
|---|---|
| With HCl; NH4Cl In hydrogenchloride soln. evapd. at 80°C in vac.; residue heated at 1E-3 Torr to 430°C; distn. (1E-5 Torr, Ta vessel); | 90% |
| With hydrogenchloride In hydrogenchloride Gd2O3 dissolved in concd. HCl; soln. evapd., residual chloride purified by high-temperature react. with NH4Cl (J.Kutscher and A.Schneider, Z.Anorg.Allg.Chem., 389 (1972) 157); | |
| In not given | |
| J.F. Desreux, in Lanthanide Probes in Life, Chemical and Earth Science. Theory and Practice, ed. J.-C. G. Buenzli and G.R. Choppin, Elsevier Science Publ. B.V. Amsterdam, 1989, ch. 2, pp. 43-64; |
| Conditions | Yield |
|---|---|
| In hydrogenchloride metal oxide treated with 1:1 hydrochloric acid; soln. filtered, evapd. to dryness, crystals dried in vaccum dessicator over CaCl2; | 85% |
| In water dissolving of Gd2O3 in a slight excess of concd. HCl in doubly distd. water; evapn. of excess HCl; | |
| In neat (no solvent) oxide was treated with concd. HCl; evapd.; residue dissolved in H2O; evapd.; |
| Conditions | Yield |
|---|---|
| With pyrographite In gas byproducts: CO; by chlorination-chem. vapor transport react.; mixt. of Er2O3 and Gd2O3 with carbon and KCl (1:1:6:1 at. ratio) placed in alumina reactor and chlorinated with dry Cl2 (20 cm**3/min) at 800 K for 2 h; gas replace by Ar:Cl2 at 800-1300 K; detn. of separation factor; | A 40.58% B 14.91% |
B
- 10138-52-0
gadolinium(III) chloride
| Conditions | Yield |
|---|---|
| In neat (no solvent) Al2Cl6 prepd. from Al and Cl2; in Duran tube, at 400°C (Cl2); chemical vapour phase transport with Al2Cl6 from 400 to 310°C, 24 h; | A n/a B 14% |
| Conditions | Yield |
|---|---|
| according to Meyer, G., Ax, P., Mater. Res. Bull. 1982, 17, 1447.; | |
| In neat (no solvent) byproducts: NH3, H2O; (Ar); excess of NH4Cl; 520 K for 4 h; removal of excess of NH4Cl at 700 K in vac.; sublimation (1250 K); |
- 10138-52-0
gadolinium(III) chloride
| Conditions | Yield |
|---|---|
| With NH4Cl In neat (no solvent) heating of GdCl3*99H2O in the presence of NH4Cl (Handbuch der preparativen anorganischen Chemie, Herausg. G. Brauer, Studgardt, 1975); | |
| With NH4Cl; chlorine byproducts: H2O; crystalline hydrate mixt. with ammonium chloride dehydration in chlorinestream; |
- 7719-09-7
thionyl chloride
B
- 10138-52-0
gadolinium(III) chloride
| Conditions | Yield |
|---|---|
| In neat (no solvent) | |
| In neat (no solvent) |
| Conditions | Yield |
|---|---|
| In neat (no solvent) absence of moisture; large excess AlCl3, evacuated quartz tube, 573 K; fractional sublimation over 450 to 650 K gradient, removal of residual AlCl3 on heating in Cl2/N2 stream; |
| Conditions | Yield |
|---|---|
| dry box, nitrogen stream; direct chlorination using CCl4; | |
| at 550°C, 15 h; | |
| In neat (no solvent) heating to 825 K in 4 - 5 h, chlorination by isothermal treatment in a stream of CCl4 at 825 K for 5 - 6 h; elem. anal.; |
Trichlorogadolinium Chemical Properties
IUPAC Name: Trichlorogadolinium
The MF of Trichlorogadolinium (CAS NO.10138-52-0) is Cl3Gd.
The MW of Trichlorogadolinium (CAS NO.10138-52-0) is 263.61.
Synonyms of Trichlorogadolinium (CAS NO.10138-52-0): Gadolinium trichloride ; Gadolinium chloride ; Gadolinium chloride (GdCl3) ; Gadolinium(3+) chloride ; Gadolinium(III) chloride
Product Categories: Inorganics;GadoliniumAnalytical Standards;G-HChemical Synthesis;GStable Isotopes;Alphabetic;Alphabetical Listings;Analytical Standards;Catalysis and Inorganic Chemistry;NMR Reference Standards
Apperance: White to off-white powder
Sensitive: Hygroscopic
Melting Point: 609 °C
Density: 4,52 g/ml
EINECS: 233-386-6
Merck: 14,4326
Trichlorogadolinium Uses
Trichlorogadolinium (CAS NO.10138-52-0) is used in chemical reagents, organic intermediates, fine chemicals, pharmaceutical research and development.
Trichlorogadolinium Toxicity Data With Reference
| 1. | skn-rbt 500 mg MOD | BJPCAL British Journal of Pharmacology and Chemotherapy. 17 (1961),526. | ||
| 2. | eye-rbt 1 mg/1H MLD | BJPCAL British Journal of Pharmacology and Chemotherapy. 17 (1961),526. | ||
| 3. | ipr-mus LD50:378 mg/kg | AEHLAU Archives of Environmental Health. 5 (1962),437. |
Trichlorogadolinium Consensus Reports
Reported in EPA TSCA Inventory.
Trichlorogadolinium Safety Profile
Poison by intraperitoneal route. A skin and eye irritant. When heated to decomposition it emits very toxic fumes of Cl−. See also CHLORIDES, GADOLINIUM, and RARE EARTHS.Safety information of Trichlorogadolinium (CAS NO.10138-52-0):
Hazard Codes 
Xi
Risk Statements
38 Irritating to the eyes
Safety Statements
36/37 Irritating to eyes and respiratory system
WGK Germany 3
RTECS ZC0230000
F 10-21
What can I do for you?
Get Best Price
