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7446-70-0

Basic Information
CAS No.: 7446-70-0
Name: Aluminium chloride
Molecular Structure:
Molecular Structure of 7446-70-0 (Aluminium chloride)
Formula: AlCl
Molecular Weight: 133.34
Synonyms: Aluminumchloride (8CI);
EINECS: 231-208-1
Density: 2.44 g/cm3
Melting Point: 194 °C
Boiling Point: 180°C
Flash Point: 88 °C
Solubility: soluble in water
Appearance: yellow to grey solid
Hazard Symbols: CorrosiveC, IrritantXi, ToxicT
Risk Codes: 36/38-34-62-51/53-48/23/24-40-23/24/25-14
Safety: 26-45-28-7/8-36/37/39-61-23-28A
Transport Information: UN 3264 8/PG 3
PSA: 0.00000
LogP: 2.06850
Synthetic route
7782-50-5

chlorine

7429-90-5

aluminium

7446-70-0

aluminium trichloride

Conditions
ConditionsYield
In neat (no solvent) passing a flow of Cl2 over Al in a combustion tube;;80%
In neat (no solvent) heating Al shavings in a flow of chlorine; distd. in vac.;
at 600 K;
75-44-5

phosgene

7727-15-3

aluminium bromide

A

7446-70-0

aluminium trichloride

B

7726-12-7

carbonyl bromide chloride

Conditions
ConditionsYield
equil. amts of educts in tube, cooling than 140-145°C, 7-8h; distn., addn. Hg, distn. 24.5-25.5°C atmospheric pressure;A n/a
B 50%
equil. amts of educts in tube, cooling than 140-145°C, 7-8h; distn., addn. Hg, distn. 24.5-25.5°C atmospheric pressure;A n/a
B 50%
16853-85-3

lithium aluminium tetrahydride

7719-12-2, 52843-90-0

phosphorus trichloride

A

7446-70-0

aluminium trichloride

B

7803-51-2

phosphan

C

lithium chloride

Conditions
ConditionsYield
In diethyl ether reduction of PCl3 with LiAlH4 in ether at 0 °C;;
In diethyl ether reduction of PCl3 with LiAlH4 in ether at 75 °C;;A n/a
B 0.25%
C n/a
In diethyl ether reduction of PCl3 with LiAlH4 in ether at 75 °C;;A n/a
B 0.25%
C n/a
In diethyl ether reduction of PCl3 with LiAlH4 in ether at 0 °C;;
14202-90-5

8-chloro-1-methoxy-phenazine

A

7446-70-0

aluminium trichloride

B

23663-42-5

8-chloro-phenazin-1-ol

Conditions
ConditionsYield
With benzene
108-77-0

1,3,5-trichloro-2,4,6-triazine

60-29-7

diethyl ether

LiAlH4

LiAlH4

A

7446-70-0

aluminium trichloride

B

LiCl

LiCl

C

lithium tetracyanoalanate

lithium tetracyanoalanate

78-78-4

methylbutane

507-20-0

tertiary butyl chloride

7727-15-3

aluminium bromide

A

7446-70-0

aluminium trichloride

B

75-28-5

Isobutane

C

507-36-8

2-bromo-2-methylbutane

D

18295-25-5, 26561-37-5

3-bromo-2-methylbutane

7647-01-0

hydrogenchloride

816-27-3

ethyl 2-ethoxy-2-iminoacetate

A

7446-70-0

aluminium trichloride

B

95-92-1

oxalic acid diethyl ester

778-22-3

2,2-diphenylpropane

36293-05-7

2-methyl-2-phenylpropanoyl chloride

carbon monoxide

carbon monoxide

A

7446-70-0

aluminium trichloride

B

71-43-2

benzene

1667-01-2

2,4,6-Trimethylacetophenone

79-03-8

propionyl chloride

A

7446-70-0

aluminium trichloride

B

6335-36-0

1,3-dipropionyl-2,4,6-trimethylbenzene

79-03-8

propionyl chloride

108-67-8

1,3,5-trimethyl-benzene

A

7446-70-0

aluminium trichloride

B

6335-36-0

1,3-dipropionyl-2,4,6-trimethylbenzene

acenaphthen-5-yl-phenyl ketone; compound with aluminium trichloride

A

7446-70-0

aluminium trichloride

B

4657-89-0

5-benzoylacenaphthene

774-55-0

6-Acetyl-1,2,3,4-tetrahydronaphthalene

60-29-7

diethyl ether

75-36-5

acetyl chloride

A

7446-70-0

aluminium trichloride

B

101431-21-4

2,5-diacetyl-7-ethyl-1-methyl-indene

5-benzoyl-2,4-dibromo-benzoyl chloride

5-benzoyl-2,4-dibromo-benzoyl chloride

A

7446-70-0

aluminium trichloride

B

110877-20-8

1-benzoyl-2,4-dibromo-5-(2,4-dimethyl-benzoyl)-benzene

Conditions
ConditionsYield
With m-xylene
75-44-5

phosgene

monoaluminum phosphate

7782-50-5

chlorine

A

7446-70-0

aluminium trichloride

Conditions
ConditionsYield
In neat (no solvent) reaction at at temperatures higher than 300°C;;

monoaluminum phosphate

201230-82-2

carbon monoxide

7782-50-5

chlorine

A

7446-70-0

aluminium trichloride

Conditions
ConditionsYield
In neat (no solvent) reaction at at temperatures higher than 300°C;;

monoaluminum phosphate

7782-50-5

chlorine

A

7446-70-0

aluminium trichloride

Conditions
ConditionsYield
With pyrographite In neat (no solvent) reaction at temperatures higher than 300°C;;

aluminum sulfide

ammonium chloride

7446-70-0

aluminium trichloride

1333-84-2, 1344-28-1

aluminum oxide

ammonium chloride

7446-70-0

aluminium trichloride

Conditions
ConditionsYield
In neat (no solvent) calcination of NH4Cl and Al2O3;;

ammonium chloride

7429-90-5

aluminium

7446-70-0

aluminium trichloride

Conditions
ConditionsYield
In neat (no solvent) mixture contg. 45-50 weight-% Al-powder, 45 weight-% Al2O3 and 5-10 weight-% NH4Cl is heated to 600-830 °C yielding AlCl3 vapors;; not isolated;;

aluminum(III) sulfate

ammonium chloride

7446-70-0

aluminium trichloride

Conditions
ConditionsYield
260°C; distillation of AlCl3;
In neat (no solvent) calcination of NH4Cl and Al2(SO4)3;;

aluminum sulfide

7446-70-0

aluminium trichloride

Conditions
ConditionsYield
With sodium chloride heating;
With hydrogenchloride HCl vapor;
With potassium chloride byproducts: K2S;

aluminum sulfide

potassium chloride

7446-70-0

aluminium trichloride

aluminum sulfide

7647-14-5

sodium chloride

7446-70-0

aluminium trichloride

aluminum sulfide

barium(II) chloride

7446-70-0

aluminium trichloride

aluminum sulfide

7719-12-2, 52843-90-0

phosphorus trichloride

7446-70-0

aluminium trichloride

aluminum sulfide

7705-08-0

iron(III) chloride

7446-70-0

aluminium trichloride

7647-01-0

hydrogenchloride

aluminum sulfide

7446-70-0

aluminium trichloride

Conditions
ConditionsYield
500°C;
500°C;

aluminum sulfide

7782-50-5

chlorine

7446-70-0

aluminium trichloride

Conditions
ConditionsYield
95°C;
95°C;
7446-70-0

aluminium trichloride

7429-90-5

aluminium

Conditions
ConditionsYield
With hydrogen In neat (no solvent) byproducts: HCl; other Radiation; AlCl3 powder placed in quartz tube; tube evacuated and flushed with Ar and then heated under Ar/H2 flow to 90°C; rf discharge ignited for20 min and tube then cooled; XRD;100%
With potassium In neat (no solvent) heating AlCl3 in a rectangular glass tube and passing the vapor over pieces of K in the horizontal part of the tube;;
With lithium hydride; 1-ethyl-3-methyl-1H-imidazol-3-ium chloride In neat (no solvent) mixed by stirring; deposited at 25-45°C for 15 min - 2 h;
7446-70-0

aluminium trichloride

108-98-5

thiophenol

36453-29-9

aluminium trichloride*thiophenol

Conditions
ConditionsYield
In benzene under N2, dropwise addn. of thiol soln. to a suspension of AlCl3 in benzene, dissoln.of AlCl3, stirred for 15 min at room temp.; evapn. of solvent, dried in vac. at room temp. for 3h, elem. anal.;100%
7446-70-0

aluminium trichloride

10361-79-2

praseodymium(III) chloride

75-05-8

acetonitrile

Pr(NCCH3)9(3+)*3AlCl4(1-)*CH3CN = [Pr(NCCH3)9](AlCl4)3*CH3CN

Conditions
ConditionsYield
In acetonitrile (inert atmosphere); condensing MeCN onto AlCl3 and PrCl3, reflux until aclear soln. is obtained; solvent removal (vac.); elem. anal.;100%
7446-70-0

aluminium trichloride

75-08-1

ethanethiol

115958-68-4, 98772-97-5

aluminiumtrichloride*ethanediol

Conditions
ConditionsYield
In benzene slow addn. of ethanethiol to a suspn. of an equimolar amt. of AlCl3 in benzene; mixt. stirred for 1 h at room temp.; solvent distd. off in vac. at 60°C; residual oil distd. at 86°C (0.5 Torr); elem. anal.;100%
In benzene under N2, dropwise addn. of thiol soln. to a suspension of AlCl3 in benzene, dissoln.of AlCl3, stirred for 15 min at room temp.; evapn. of solvent, dried in vac. at room temp. for 3h, elem. anal.;100%
7446-70-0

aluminium trichloride

Fe(3+)*4Zr(4+)*18(OCH(CH3)2)(1-)*Cl(1-)

Al(3+)*Fe(3+)*4Zr(4+)*4Cl(1-)*18(OCH(CH3)2)(1-)={AlFeZr4Cl4(OCH(CH3)2)18}

Conditions
ConditionsYield
In benzene mixt. stirred until AlCl3 completely dissolved (ca 10h); evapn. under reduced pressure at room temp., dried (50°C, 0.4 mm, 3h);100%
7446-70-0

aluminium trichloride

Al(3+)*Fe(3+)*2Zr(4+)*13(OCH(CH3)2)(1-)*Cl(1-)

2Al(3+)*Fe(3+)*2Zr(4+)*4Cl(1-)*13(OCH(CH3)2)(1-)={Al2FeZr2Cl4(OCH(CH3)2)13}

Conditions
ConditionsYield
In benzene mixt. stirred until AlCl3 completely dissolved (ca 10h); evapn. under reduced pressure at room temp., dried (50°C, 0.4 mm, 3h); elem. anal.;100%
7446-70-0

aluminium trichloride

(η5-C5H4Me)2TiCl

(MeCp)2Ti(AlCl4)

Conditions
ConditionsYield
In benzene100%
7446-70-0

aluminium trichloride

[(η5-pentamethylcyclopentadienyl)2TiCl]

(M5Cp)2Ti(AlCl4)

Conditions
ConditionsYield
In benzene100%
7446-70-0

aluminium trichloride

74-93-1

methylthiol

98772-96-4

(aluminium trichloride)methanethiol

Conditions
ConditionsYield
In benzene under N2, CH3SH introduced in a suspension of AlCl3 for 5 min, dissoln.of AlCl3, stirred for 15 min at room temp.; evapn. of solvent, dried in vac. at room temp. for 3h, elem. anal.;100%
7446-70-0

aluminium trichloride

3908-55-2

Trimethyl(methylthio)silane

112908-11-9

aluminium trichloride*trimethylsilyl methyl sulphide

Conditions
ConditionsYield
In benzene a benzene soln. of Me3SiSMe was added dropwise under N2 to a suspn. of AlCl3 in benzene, mixt. was stirred for 15 min at room temp.; solvent was evapd.; elem. anal.;100%
7446-70-0

aluminium trichloride

5573-62-6

(ethylthio)trimethylsilane

112908-12-0

aluminium trichloride*trimethylsilyl ethyl sulphide

Conditions
ConditionsYield
In benzene a benzene soln. of Me3SiSEt was added dropwise under N2 to a suspn. of AlCl3 in benzene, mixt. was stirred for 15 min at room temp.; solvent was evapd.; elem. anal.;100%
7446-70-0

aluminium trichloride

4551-15-9

phenylthiotrimethylsilane

112908-13-1

aluminium trichloride*trimethylsilyl phenyl sulphide

Conditions
ConditionsYield
In benzene a benzene soln. of Me3SiSPh was added dropwise under N2 to a suspn. of AlCl3 in benzene, mixt. was stirred for 15 min at room temp.; solvent was evapd.; elem. anal.;100%
7446-70-0

aluminium trichloride

6389-79-3

methyl methylphenylphosphinate

poly(aluminum methylphenylphosphinate)

Conditions
ConditionsYield
In further solvent(s) byproducts: MeCl; slow heating in neat Ph(Me)P(O)OMe until complete pptn.; particle size and polymerization degree depending on heating rate;100%
7446-70-0

aluminium trichloride

79917-90-1

1-butyl-3-methylimidazolium chloride

1-butyl-3-methylimidazolium heptachlorodialuminate

Conditions
ConditionsYield
In neat (no solvent) 1-butyl-3-methylimidazolium chloride was mixed with AlCl3 under N2 for 5min.;100%
E.J. Angueira, M.G. White, J. Mol. Catal. A Chem. 227 (1-2) (2005) 51-58; 238 (2005) 163-174;
7446-70-0

aluminium trichloride

13892-04-1

triethyl(trimethylsilylimino)phosphorane

[AlCl2(NP(C2H5)3)]2

Conditions
ConditionsYield
In acetonitrile byproducts: Me3SiCl; Ar atm.; equivalent amts., refluxing; evapn. (vac., to dryness); elem. anal.;100%
7446-70-0

aluminium trichloride

syn-Li2[N(SiMe2CH2P(Ph)CH2SiMe2)2N](1,4-dioxane)

219594-43-1, 219594-45-3

syn-AlCl[PhP(CH2SiMe2NSiMe2CH2)2PPh]

Conditions
ConditionsYield
In toluene byproducts: LiCl; inert atmosphere; stirring for 12 h; filtration off of LiCl (Celite), solvent removal (vac.), recrystn. (PhMe, slow evapn.);100%
678172-48-0

[N-(2-diphenylphosphinophenyl)-2,6-dimethylanilide]Li(THF)2

7446-70-0

aluminium trichloride

678172-45-7

[N-(2-diphenylphosphinophenyl)-2,6-dimethylanilide]AlCl2

Conditions
ConditionsYield
In toluene under N2 atm. AlCl3 was added at -35°C to soln. (N-(2-phenylphosphinophenyl)-2,6-dimethylanilide)Li(THF)2 in toluene and stirred at room temp. for 4 days; react. mixt. was filtered, solvent was stripped;100%
7446-70-0

aluminium trichloride

3043-60-5

triethylboroxine

A

2,2,8,8,13-pentachloro-4,6,10,12-tetraethyl-1,3,5,7,9,11-hexaoxa-4,6,10,12-tetrabora-2,8,13-trialuminatetracyclo{7.3.1.0(3,13)0(7,13)}tridecane

B

1739-53-3

ethyl-dichloro-borane

Conditions
ConditionsYield
In neat (no solvent) the educts were warmed with stirring to 40°C, cooled to 20°C;; distn. in vac. (removal of excess boroxine and by-products), residue sublimed in high vac. at about 130 °C; elem. anal.;;A 99.9%
B n/a
7446-70-0

aluminium trichloride

13871-93-7, 39789-20-3, 39789-21-4, 125329-92-2

trans-1,2-bis[(trimethylsilyl)oxy]cyclohexane

135366-85-7

{C6H10(O)(OSi(CH3)3)}2{AlCl2}2

Conditions
ConditionsYield
In dichloromethane a stirred suspn. of AlCl3 in CH2Cl2 at -78°C was treated dropwise under dry Ar with a soln. of the ether in CH2Cl2, the mixture was kept at 25°C for 20 h; removal of the volatiles by evapn. in vacuo;99.2%
7446-70-0

aluminium trichloride

75-24-1

trimethylaluminum

Conditions
ConditionsYield
With methylmagnesium bromide In not given react. of AlCl3 with MeMgBr;99%
7446-70-0

aluminium trichloride

7782-50-5

chlorine

Conditions
ConditionsYield
697°C,in N2;99%
697°C,in N2;99%
With oxygen glowing in O2-stream;
7446-70-0

aluminium trichloride

21050-13-5

bis(triphenylphosphine)iminium chloride

174422-38-9

N(P(C6H5)3)2(1+)*AlCl4(1-)=N(P(C6H5)3)2[AlCl4]

Conditions
ConditionsYield
In tetrahydrofuran inert atmosphere; stirring equimolar amts. (room temp., 4 h); solvent removal (vac.); elem. anal.;99%

praseodymium

7446-70-0

aluminium trichloride

75-05-8

acetonitrile

Pr(NCCH3)9(3+)*3AlCl4(1-)*CH3CN = [Pr(NCCH3)9](AlCl4)3*CH3CN

Conditions
ConditionsYield
With C2Cl6 In acetonitrile Sonication; (N2); addn. of MeCN to Pr, AlCl3 and C2Cl6, sonication for 3 h; solvent removal (vac.); elem. anal.;99%
7446-70-0

aluminium trichloride

17567-17-8

potassium hydridotris(3,5-dimethylpyrazolyl)borate

112439-53-9

{(tris(3,5-dimethyl-1-pyrazolyl)hydridoborate)2Al}(AlCl4)

Conditions
ConditionsYield
In dichloromethane stirring (18 h, room temp.), solvent removal (vacuum); extraction (CH2Cl2), recrystn. (MeCN);99%

lithium borohydride

7446-70-0

aluminium trichloride

aluminum(III) borohydride

Conditions
ConditionsYield
In toluene byproducts: LiCl; treatment of LiBH4 with AlCl3 in toluene; pptn.; distn.;99%
freezing-thawing (vac., 20 to -78°C);
7647-01-0

hydrogenchloride

7446-70-0

aluminium trichloride

227932-83-4

(P((CH3)2C6H5))3Cl2Re(N-pyrrolyl)

14710-16-8, 15613-32-8, 24627-46-1

mer-trichlorotris(dimethylphenylphosphine)rhenium(III)

Conditions
ConditionsYield
99%
7647-01-0

hydrogenchloride

7446-70-0

aluminium trichloride

227932-89-0

mer-(PMe2Ph)3Cl2Re(3,4-NC4H2Me2)

14710-16-8, 15613-32-8, 24627-46-1

mer-trichlorotris(dimethylphenylphosphine)rhenium(III)

Conditions
ConditionsYield
In chloroform-d1 N2-atmosphere; excess of HCl, 1 equiv. of AlCl3, standing for 1-2 days; not sepd.; NMR-spectroscopy;99%
7647-01-0

hydrogenchloride

7446-70-0

aluminium trichloride

mer-(PMe2Ph)3Cl2Re(3-NC4H3Me)*H2O

14710-16-8, 15613-32-8, 24627-46-1

mer-trichlorotris(dimethylphenylphosphine)rhenium(III)

Conditions
ConditionsYield
99%
7446-70-0

aluminium trichloride

32974-66-6

1-[(1-chloro-1-methylethyl)azo]-2,4,6-trichlorobenzene

622-16-2

1,3-Diphenylcarbodiimide

4,5-dihydro-4-isopropyl-5(isopropylimino)-2,3-dimethyl-4-phenyl-5-(phenylimino)-1-(2,4,6-trichlorophenyl)-1H-1,2,4-triazolinium tetrachloroaluminate

Conditions
ConditionsYield
In dichloromethane inert atmosphere; soln. of N-compounds added dropwise to suspension of AlCl3 at -60°C; stirred for 1 h at -60°C, then for 1 h at 0°C;; evapd.; pptd. from CH2Cl2/pentane; elem. anal.;;99%
7446-70-0

aluminium trichloride

74666-77-6

W(O)(CHC(CH3)3)Cl2(P(C2H5)3)2

79357-54-3

[W(O)(CHC(CH3)3)(P(C2H5)3)2](2+)*2AlCl4(1-)=[W(O)(CHC(CH3)3)(P(C2H5)3)2](AlCl4)2

Conditions
ConditionsYield
In dichloromethane AlCl3 was added to stirred soln. of W compd. in CH2Cl2 in ca. 2:1 molarratio; filtered, vol. of filtrate halved in vac., equal vol. of pentane was added, crystd., elem. anal.;99%
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  • Aluminium chloride CAS NO.7446-70-0

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    Aluminium chloride CAS NO.7446-70-0

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Chemistry

Molecule structure of Aluminium Chloride (CAS NO.7446-70-0):

Molecular Weight: 133.3405 g/mol
Molecular Formula: AlCl
Density: 2.44 g/cm3
Melting Point: 194 °C
Boiling Point: 180°C
Flash Point: 88 °C
Storage Temp.: 2-8 °C
Sensitive Moisture: sensitive
InChI: InChI=1/Al.3ClH/h;3*1H/q+3;;;/p-3
InChIKey: VSCWAEJMTAWNJL-DFZHHIFOAR 
EINECS: 231-208-1
Product Categories: Industrial/Fine Chemicals;Inorganics; Al (Alminum) Compounds; Classes of Metal Compounds; Typical Metal Compounds; Aluminum; AluminumSynthetic Reagents; Catalysis and Inorganic Chemistry; Chemical Synthesis; Lewis Acids; Aluminum SaltsEssential Chemicals; AluminumMetal and Ceramic Science; Reagent Grade; Routine Reagents; Salts; Aluminum Salts; Crystal Grade Inorganics; Reagent Plus; A-B, Puriss p.a.; Analytical Reagents for General Use; Puriss p.a.

Uses

 Aluminium Chloride  is probably the most commonly used Lewis acid and also one of the most powerful. It finds widespread application in the chemical industry as the classic catalyst for Friedel-Crafts reactions, both acylations and alkylations. The Friedel-Crafts reaction is the major use for aluminium chloride, for example in the preparation of anthraquinone (for the dyestuffs industry) from benz and phosgene. Aluminium Chloride also can be  used in polymerization and isomerization reactions of hydrocarbons. and used to introduce aldehyde groups onto aromatic rings,a wide variety of other applications in organic chemistry.

Production

Anhydrous aluminum chloride is manufactured piimarily by the reaction of chlorine vapor on molten aluminum.
             2Al + 3Cl2 → 2AlCl3
In the process, chlorine is fed in below the surface of the aluminum, and the product sublimes and is collected by condensing. These air-cooled condensers are thin-walled, vertical steel cylinders with conical bottoms. Aluminum chloride crystals form on the condenser walls and are periodically removed, crushed, screened, and packaged in steel containers.

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 oral 1130mg/kg (1130mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 30(4), Pg. 16, 1965.
mouse LD50 unreported 390mg/kg (390mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 43(4), Pg. 12, 1978.
rabbit LD50 skin > 2gm/kg (2000mg/kg)   United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. Vol. 8EHQ-0191-1109,
rat LD50 oral 3450mg/kg (3450mg/kg) BRAIN AND COVERINGS: OTHER DEGENERATIVE CHANGES

GASTROINTESTINAL: OTHER CHANGES

KIDNEY, URETER, AND BLADDER: HEMATURIA
Science Reports of the Research Institutes, Tohoku University, Series C: Medicine. Vol. 36(1-4), Pg. 10, 1989.
rat LD50 unreported 315mg/kg (315mg/kg)   Gigiena i Sanitariya. For English translation, see HYSAAV. Vol. 43(4), Pg. 12, 1978.

Safety Profile

Hazard Codes: CorrosiveC, IrritantXi, ToxicT
Risk Statements: 36/38-34-62-51/53-48/23/24-40-23/24/25-14 
R36/38:Irritating to eyes and skin. 
R20:Harmful by inhalation. 
R62:Risk of impaired fertility. 
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R48:Danger of serious damage to health by prolonged exposure. 
R23 :Toxic by inhalation. 
R24:Toxic in contact with skin. 
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed. 
R14 :Reacts violently with water.
Safety Statements: 26-45-28-7/8-36/37/39-61-23-28A 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S28:After contact with skin, wash immediately with plenty of soap-suds. 
S7:Keep container tightly closed. 
S8:Keep container dry. 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets. 
S23:Do not breathe vapour. 
S28:After contact with skin, wash immediately with plenty of soap-suds.
RIDADR: UN 3264 8/PG 3
WGK Germany: 1
RTECS: BD0525000
HazardClass: 8
PackingGroup: II
Hazardous Substances Data: 7446-70-0(Hazardous Substances Data)

Specification

 Aluminium Chloride (CAS NO.7446-70-0) is also named as AI3-01917 ; Alluminio(cloruro di) ; Alluminio(cloruro di) [Italian] ; Aluminium trichloride ; Aluminium, (chlorure d') ; Aluminium, (chlorure d') [French] ; Aluminiumchlorid ; Aluminiumchlorid [German] ; Aluminum chloride (1:3) ; Aluminum trichloride ; Aluminum, (chlorure d') ; Aluminum, (chlorure d')[French] ; CCRIS 6871 ; Caswell No. 029 ; Chlorure d'aluminium ; Chlorure d'aluminium [French] ; EPA Pesticide Chemical Code 013901 ; HSDB 607 ; NSC 143015 ; NSC 143016 ; Pearsall ; TK Flock ; Trichloroaluminum ; UNII-LIF1N9568Y . Aluminium Chloride (CAS NO.7446-70-0) is yellow to grey solid with a pungent odor. It is corrosive to tissue and toxic by ingestion. Contact with the skin or eyes in the presence of moisture causes thermal and acid burns. Aluminium Chloride behaves as an acidic salt. It can self-reactive. After long storage in closed containers, explosions often occur upon opening. Can cause ethylene(also other alkenes) to polymerize violently. Causes ethylene oxide to rearrange and polymerize, liberating heat. Can catalyze violent polymerization of allyl chloride. Addition to nitrobenzene containing about 5% phenol caused a violent explosion. Mixtures with nitromethane may explode when organic matter is present. Reacts violently with water if used in extinguishing adjacent fires.