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| CAS No.: | 554-70-1 |
|---|---|
| Name: | Triethylphosphine |
| Molecular Structure: | |
|
|
|
| Formula: | C6H15P |
| Molecular Weight: | 118.159 |
| Synonyms: | HishicolinP 2;Triethylphosphorus; |
| EINECS: | 209-068-8 |
| Density: | 0.88g/mLat 20°C |
| Melting Point: | -3oC |
| Boiling Point: | 126.516 °C at 760 mmHg |
| Flash Point: | 27.202 °C |
| Solubility: | Insoluble in water. |
| Appearance: | clear liquid |
| Hazard Symbols: |
 F, C
|
| Risk Codes: | 11-34-67-17 |
| Safety: | 26-36/37/39-45-7/9-33-16 |
| Transport Information: | UN 2924 3/PG 2 |
| PSA: | 13.59000 |
| LogP: | 2.52800 |
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| Conditions | Yield |
|---|---|
| In dichloromethane mixing of the Mo compd. with the free phosphine (molar ratio 4.5:1) in CH2Cl2;; | A 100% B n/a |
| In toluene mixing of the Mo compd. with the free phosphine (molar ratio 2.1:1) in toluene;; | A 100% B n/a |
| Conditions | Yield |
|---|---|
| With phosphan; zinc(II) oxide In acetone at 0℃; for 12h; Solvent; Reagent/catalyst; Temperature; Irradiation; | 96% |
| Conditions | Yield |
|---|---|
| With phenylsilane; C28H16F24O8S2Si In (2)H8-toluene at 100℃; for 48h; Inert atmosphere; | 91% |
| With aluminium hydride In 1,2-dimethoxyethane at 0 - 65℃; for 12h; Inert atmosphere; Schlenk technique; | 70% |
| With chromium |
- 925-90-6
ethylmagnesium bromide
- 119841-34-8, 127780-84-1
cis-2,10-dimethyl-<1,2,3>benzothiadiphospholo<2,3-b><1,2,3>benzothiadiphosphole
A
- 554-70-1
triethylphosphine
B
- 736137-64-7
4-methyl-2-[(5-methyl-2-sulfanylphenyl)phosphanyl]benzenethiol
| Conditions | Yield |
|---|---|
| In tetrahydrofuran | A n/a B 90% |
- 16940-66-2
sodium tetrahydroborate
- 121846-72-8
cis,trans-dicarbonylbis(triethylphosphine)(dithioformate-κ2-S)manganese
B
- 554-70-1
triethylphosphine
| Conditions | Yield |
|---|---|
| In ethanol; dichloromethane Addn. of a NaBH4 soln. (EtOH) to a stirred soln. of Mn-complex in CH2Cl2 under N2, stirring (1.5 h), colour turns from deep blue to bright red.; Evapn. of solvent in vac., pumping for 1 h to eleminate the free phosphine, extg. of red solid (hexane), filtn., addn. of EtOH, slow evapn. in vac., elem. anal.; | A 90% B n/a |
| Conditions | Yield |
|---|---|
| Stage #1: chloroethane With magnesium; methyl iodide In tetrahydrofuran; 5,5-dimethyl-1,3-cyclohexadiene; ethyl acetate at 40 - 50℃; for 2.5h; Inert atmosphere; Stage #2: With phosphorus trichloride In tetrahydrofuran; 5,5-dimethyl-1,3-cyclohexadiene; ethyl acetate at 5℃; for 4h; Concentration; Temperature; Inert atmosphere; | 89.9% |
- 14177-93-6, 15692-07-6, 13965-02-1
trans-platinum(triethylphosphine)2(chloro)2
B
- 116553-43-6
(Et3P)2Pt{η2-(PSiMe3)2}
C
- 15573-38-3
Tris(trimethylsilyl)phosphane
D
- 554-70-1
triethylphosphine
| Conditions | Yield |
|---|---|
| In toluene under protective gas; 8.8 mmol of the Li salt in toluene added to 4 mmol of the Pt complex in toluene at -20°C; mixt. warmed to 20°C and stirred for 2 d; filtration; filtrate evapd. in vac.; fractionated crystn.; | A 12% B 7% C n/a D n/a |
- 60-29-7
diethyl ether
- 4303-71-3
triphenylmethyl sodium
- 4317-06-0
tetraethylphosphonium iodide
A
- 519-73-3
triphenylmethane
B
- 554-70-1
triethylphosphine
| Conditions | Yield |
|---|---|
| With phosphonium iodide at 160℃; entsteht das Hydrojodid; |
- 64-17-5
ethanol
- 141-52-6
sodium ethanolate
A
- 292638-84-7
styrene
B
- 597-50-2
triethylphosphine oxide
C
- 104-51-8
1-butylbenzene
D
- 554-70-1
triethylphosphine
| Conditions | Yield |
|---|---|
| beim anschliessenden Erhitzen unter Stickstoff; |
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Chemistry
IUPAC Name: Triethylphosphane (554-70-1)
Synonyms: Aurora ka-1111 ; Cytop(R) 320 ; Triethylphosphine ; (C2H5)3P ; Phosphorus triethyl ; Ttl409 ; Triethylphosphane ; Triethyl-phosphane
CAS: 554-70-1
MF: C6H15P
MW: 118.16
MS:
EINECS: 209-068-8
Product Categories: Tertiary Phosphines ; Organics ; Phosphine Ligands ; Catalysis and Inorganic Chemistry ; Phosphorus Compounds
Mol File: 554-70-1.mol
Flash Point: 27.2 °C
Enthalpy of Vaporization: 34.93 kJ/mol
Boiling Point: 126.5 °C at 760 mmHg
Vapour Pressure: 14.1 mmHg at 25°C
Density: 0.88 g/mL at 20 °C
Refractive index : n20/D 1.456(lit.)
Sensitive: Air & Moisture Sensitive
Merck: 14,9675
Uses
Triethyl phosphine (554-70-1) is used in organic syntheses.
Safety Profile
Hazard Codes: F.gif){kind=small}
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Risk Statements: 11-34-67-17
11: Highly Flammable
17: Spontaneously flammable in air
34: Triethyl phosphine (554-70-1) can causes burns.
67: Vapors may cause drowsiness and dizziness
Safety Statements: 26-36/37/39-45-7/9-33-16
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39: Wear suitable protective clothing, gloves and eye/face protection
45: In case of accident or if you feel unwell, seek medical advice immediately (show label where possible)
7/9: Keep container tightly closed and in a well-ventilated place
33: Take precautionary measures against static discharges
16: Keep Triethyl phosphine (554-70-1) away from sources of ignition - No smoking
RIDADR : UN 2924 3/PG 2
WGK Germany: 3
RTECS : SZ3400000
F : 10-13-23
HazardClass: 4.2
PackingGroup: I