CAS No.75-00-3,CHLOROETHANE Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	75-00-3
Name:	CHLOROETHANE
Article Data:	749

Formula:	C₂H₅Cl
Molecular Weight:	64.5147
Synonyms:	Aethylis;Aethylis chloridum;Anodynon;Chlorethyl;Chloridum;Chloroethane;Chloryl;Chloryl Anesthetic;Chloryle anesthetic;Cloretilo;Dublofix;Ether chloratus;Ether hydrochloric;Ether muriatic;Hydrochloric ether;Kelene;Monochloroethane;Muriaticether;Narcotile;R 160;
EINECS:	200-830-5
Density:	0.884 g/cm³
Melting Point:	-139 °C(lit.)
Boiling Point:	12.7 °C at 760 mmHg
Flash Point:	<-30 °F
Solubility:	6710 mg/L at 25℃
Appearance:	colourless gas
Hazard Symbols:	F+,Xn,T,F
Risk Codes:	45-11-20/21/22-36/37/38-52/53-40-12-39/23/24/25-23/24/25-67-66-22-19
Safety:	9-16-33-36/37-61-45-7-29-36/37/39-26-53
Transport Information:	UN 1993 3/PG 2
PSA:	0.00000
LogP:	1.24510

Synthetic route

: 87463-00-1
O-ethyl N-methyl-N-phenylthiocarbamate

A: 75-00-3
chloroethane

B: 100244-53-9
(N-methyl-N-phenylcarbamoyl)sulfenyl chloride

Conditions

Conditions	Yield
With sulfuryl dichloride In chloroform-d1 at 5℃; for 0.166667h;	A 100% B n/a
With sulfuryl dichloride In chloroform-d1 at 25℃;

: 945614-32-4
triethyloxonium tris(pentafluoroethyl)trifluorophosphate

: 65039-09-0
1-ethyl-3-methyl-1H-imidazol-3-ium chloride

A: 377739-43-0
1-ethyl-3-methyl-imidazolium tris(pentafluoroethyl)trifluorophosphate

B: 60-29-7
diethyl ether

C: 75-00-3
chloroethane

Conditions

Conditions	Yield
at 80℃; for 3h; Product distribution / selectivity;	A 98.9% B n/a C n/a

...Expand

: 945614-32-4
triethyloxonium tris(pentafluoroethyl)trifluorophosphate

: 30388-20-6
N,N,N',N',N'',N''-hexamethylguanidinium chloride

A: hexamethylguanidinium tris(pentafluoroethyl)trifluorophosphate

B: 60-29-7
diethyl ether

C: 75-00-3
chloroethane

Conditions

Conditions	Yield
at 80℃; for 3h;	A 98.9% B n/a C n/a

...Expand

: 762-04-9
phosphonic acid diethyl ester

A: 75-00-3
chloroethane

B: phosphorous acid monoethyl ester cobaltous salt

Conditions

Conditions	Yield
With CoCl2 at 120℃; Product distribution; the thermal stability of the product was investigated by DTA, DTG and TG;	A n/a B 98%

: 945614-34-6
triethyloxonium bis(trifluoromethylsulfonyl)imide

: 65039-09-0
1-ethyl-3-methyl-1H-imidazol-3-ium chloride

A: 60-29-7
diethyl ether

B: 75-00-3
chloroethane

C: 174899-82-2
1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide

Conditions

Conditions	Yield
at 80℃; for 3h;	A n/a B n/a C 97.9%

...Expand

: 1825-69-0
dimethyl chloro ethoxy silane

: 75-36-5
acetyl chloride

A: 75-00-3
chloroethane

B: acetoxydimethylsilyl isothiocyanate

Conditions

Conditions	Yield
at 30 - 40℃; for 1h;	A 97% B 87%

...Expand

: 64-17-5
ethanol

: 75-00-3
chloroethane

Conditions

Conditions	Yield
With hydrogenchloride; aluminum (III) chloride; zinc(II) chloride at 70 - 120℃; under 900.09 - 2625.26 Torr; for 2h; Large scale;	96.3%
With hydrogenchloride; zinc(II) chloride at 8 - 130℃;	65%
With hydrogenchloride

: 50966-09-1
diethyl (1-benzamido-2,2-dichlorovinyl)phosphonate

A: 75-00-3
chloroethane

B: 77113-14-5
azlactone of (1-benzamido-2,2-dichlorovinyl)phosphonochloridic acid

Conditions

Conditions	Yield
With phosphorus pentachloride at 110 - 120℃; for 5.5h;	A n/a B 96%

: 1-(chlorodimethylsilyl)-7-(ethoxydimethylsilyl)-m-carbaborane

A: 75-00-3
chloroethane

B: B10H10C2(Si(CH3)2O)(Si(CH3)2)

Conditions

Conditions	Yield
iron(III) chloride In neat (no solvent) heating (120 - 130°C), addn. of further FeCl3, heating (180°C); reprecipitation (toluene); elem. anal.;	A 96% B 94.7%

: 945614-32-4
triethyloxonium tris(pentafluoroethyl)trifluorophosphate

: 1-decyl-3-methylimidazol-3-ium chloride

A: 60-29-7
diethyl ether

B: 75-00-3
chloroethane

C: 916807-26-6
1-decyl-3-methylimidazolium tris(pentafluoroethyl)trifluorophosphate

Conditions

Conditions	Yield
at 80℃; for 3h;	A n/a B n/a C 96%

...Expand

Raw Materials

2007-97-8

1825-82-7

17640-25-4

67-66-3

107-06-2

121-44-8

42345-82-4

107-30-2

Downstream Products

994-49-0

124-18-5

103-73-1

542-90-5

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Consensus Reports

ETHYL CHLORIDE is reported in EPA TSCA Inventory. Community Right-To-Know List.

Standards and Recommendations

OSHA PEL: TWA 1000 ppm
ACGIH TLV: TWA 1000 ppm
DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans
NIOSH REL: (Chloroethane) Handle with caution
DOT Classification: 2.1; Label: Flammable Gas

Specification

The Ethane, chloro-, with the CAS registry number 75-00-3, is also known as Octamethylsilanetetramine. It belongs to the product categories of Refrigerants; Organics; Halides (Low Boiling point); Alkyl Chlorides; Gas Cylinders; Monofunctional & alpha,omega-Bifunctional Alkanes; Monofunctional Alkanes; Synthetic Organic Chemistry. Its EINECS number is 200-830-5. This chemical's molecular formula is C₂H₅Cl and molecular weight is 64.51. What's more, its systematic name is chloroethane. (1)Anesthetic [topical]; (2)Anesthetics; (3)Anesthetics, local; (4)Central Nervous System Agents; (5)Central Nervous System Depressants; (6)Drug / Therapeutic Agent; (7)Mutation data; (8)Peripheral Nervous System Agents; (9)Reproductive Effect; (10)Sensory System Agents; (11)TSCA Flag T [Subject to the Section 4 test rule under TSCA]; (12)Tumor data. It is stable at common pressure and temperature, and it should be sealed and stored in a cool and dry place. Moreover, it should be protected from oxides and water. It is used as a refrigerant, an aerosol spray propellant, an anesthetic, and a blowing agent for foam packaging.

Physical properties of Ethane, chloro- are: (1)ACD/LogP: 1.50; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.5; (4)ACD/LogD (pH 7.4): 1.5; (5)ACD/BCF (pH 5.5): 8.14; (6)ACD/BCF (pH 7.4): 8.14; (7)ACD/KOC (pH 5.5): 156.06; (8)ACD/KOC (pH 7.4): 156.06; (9)Index of Refraction: 1.361; (10)Molar Refractivity: 16.16 cm³; (11)Molar Volume: 72.9 cm³; (12)Polarizability: 6.4×10^-24cm³; (13)Surface Tension: 17.9 dyne/cm; (14)Density: 0.884 g/cm³; (15)Enthalpy of Vaporization: 24.97 kJ/mol; (16)Boiling Point: 12.7 °C at 760 mmHg; (17)Vapour Pressure: 1170 mmHg at 25°C.

Preparation: this chemical can be prepared by ethylphosphonic acid diethyl ester by heating. This reaction will need reagent SOCl₂ with the reaction time of 18 hours. This reaction will also need catalyst DMF. The yield is about 95.8%.

Ethane, chloro- can be prepared by ethylphosphonic acid diethyl ester by heating

Uses of Ethane, chloro-: it can be used to produce 1-Ethyl-4-methylpyridinium chloride at the temperature of 80 °C. It will need solvent acetonitrile with the reaction time of 5 hours. The yield is about 95%.

Ethane, chloro- can be used to produce 1-Ethyl-4-methylpyridinium chloride at the temperature of 80 °C

When you are using this chemical, please be cautious about it as the following:
This chemical is extremely flammable, so you should keep it away from sources of ignition - No smoking. It has a limited evidence of a carcinogenic effect. It is harmful to aquatic organisms as it may cause long-term adverse effects in the aquatic environment. You should keep the container in a well-ventilated place and take precautionary measures against static discharges. When using it, you need wear suitable protective clothing and gloves. You must avoid releasing it to the environment just refering to special instructions/safety data sheet.

You can still convert the following datas into molecular structure:
(1)SMILES: ClCC
(2)Std. InChI: InChI=1S/C2H5Cl/c1-2-3/h2H2,1H3
(3)Std. InChIKey: HRYZWHHZPQKTII-UHFFFAOYSA-N

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
guinea pig	LCLo	inhalation	40000ppm/45M (40000ppm)	BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: EXCITEMENT LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA	U.S. Public Health Service, Public Health Bulletin. Vol. 185, Pg. 1, 1929.
mouse	LC50	inhalation	146gm/m³/2H (146000mg/m³)		"Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 66, 1982.
rat	LC50	inhalation	152gm/m³/2H (152000mg/m³)	BRAIN AND COVERINGS: OTHER DEGENERATIVE CHANGES BEHAVIORAL: GENERAL ANESTHETIC BLOOD: HEMORRHAGE	Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. Vol. 6, Pg. 45, 1964.