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75-00-3

Basic Information
CAS No.: 75-00-3
Name: Ethane, chloro-
Article Data: 749
Cas Database
Molecular Structure:
Molecular Structure of 75-00-3 (Ethane, chloro-)
Formula: C2H5Cl
Molecular Weight: 64.5147
Synonyms: Aethylis;Aethylis chloridum;Anodynon;Chlorethyl;Chloridum;Chloroethane;Chloryl;Chloryl Anesthetic;Chloryle anesthetic;Cloretilo;Dublofix;Ether chloratus;Ether hydrochloric;Ether muriatic;Hydrochloric ether;Kelene;Monochloroethane;Muriaticether;Narcotile;R 160;
EINECS: 200-830-5
Density: 0.884 g/cm3
Melting Point: -139 °C(lit.)
Boiling Point: 12.7 °C at 760 mmHg
Flash Point: <-30 °F
Solubility: 6710 mg/L at 25℃
Appearance: colourless gas
Hazard Symbols: HighlyF+,HarmfulXn,ToxicT,FlammableF
Risk Codes: 45-11-20/21/22-36/37/38-52/53-40-12-39/23/24/25-23/24/25-67-66-22-19
Safety: 9-16-33-36/37-61-45-7-29-36/37/39-26-53
Transport Information: UN 1993 3/PG 2
PSA: 0.00000
LogP: 1.24510
Synthetic route
87463-00-1

O-ethyl N-methyl-N-phenylthiocarbamate

A

75-00-3

chloroethane

B

100244-53-9

(N-methyl-N-phenylcarbamoyl)sulfenyl chloride

Conditions
ConditionsYield
With sulfuryl dichloride In chloroform-d1 at 5℃; for 0.166667h;A 100%
B n/a
With sulfuryl dichloride In chloroform-d1 at 25℃;
945614-32-4

triethyloxonium tris(pentafluoroethyl)trifluorophosphate

65039-09-0

1-ethyl-3-methyl-1H-imidazol-3-ium chloride

A

377739-43-0

1-ethyl-3-methyl-imidazolium tris(pentafluoroethyl)trifluorophosphate

B

60-29-7

diethyl ether

C

75-00-3

chloroethane

Conditions
ConditionsYield
at 80℃; for 3h; Product distribution / selectivity;A 98.9%
B n/a
C n/a
945614-32-4

triethyloxonium tris(pentafluoroethyl)trifluorophosphate

30388-20-6

N,N,N',N',N'',N''-hexamethylguanidinium chloride

A

hexamethylguanidinium tris(pentafluoroethyl)trifluorophosphate

B

60-29-7

diethyl ether

C

75-00-3

chloroethane

Conditions
ConditionsYield
at 80℃; for 3h;A 98.9%
B n/a
C n/a
762-04-9

phosphonic acid diethyl ester

A

75-00-3

chloroethane

B

phosphorous acid monoethyl ester cobaltous salt

Conditions
ConditionsYield
With CoCl2 at 120℃; Product distribution; the thermal stability of the product was investigated by DTA, DTG and TG;A n/a
B 98%
945614-34-6

triethyloxonium bis(trifluoromethylsulfonyl)imide

65039-09-0

1-ethyl-3-methyl-1H-imidazol-3-ium chloride

A

60-29-7

diethyl ether

B

75-00-3

chloroethane

C

174899-82-2

1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide

Conditions
ConditionsYield
at 80℃; for 3h;A n/a
B n/a
C 97.9%
1825-69-0

dimethyl chloro ethoxy silane

75-36-5

acetyl chloride

A

75-00-3

chloroethane

B

acetoxydimethylsilyl isothiocyanate

Conditions
ConditionsYield
at 30 - 40℃; for 1h;A 97%
B 87%
64-17-5

ethanol

75-00-3

chloroethane

Conditions
ConditionsYield
With hydrogenchloride; aluminum (III) chloride; zinc(II) chloride at 70 - 120℃; under 900.09 - 2625.26 Torr; for 2h; Large scale;96.3%
With hydrogenchloride; zinc(II) chloride at 8 - 130℃;65%
With hydrogenchloride
50966-09-1

diethyl (1-benzamido-2,2-dichlorovinyl)phosphonate

A

75-00-3

chloroethane

B

77113-14-5

azlactone of (1-benzamido-2,2-dichlorovinyl)phosphonochloridic acid

Conditions
ConditionsYield
With phosphorus pentachloride at 110 - 120℃; for 5.5h;A n/a
B 96%

1-(chlorodimethylsilyl)-7-(ethoxydimethylsilyl)-m-carbaborane

A

75-00-3

chloroethane

B

B10H10C2(Si(CH3)2O)(Si(CH3)2)

Conditions
ConditionsYield
iron(III) chloride In neat (no solvent) heating (120 - 130°C), addn. of further FeCl3, heating (180°C); reprecipitation (toluene); elem. anal.;A 96%
B 94.7%
945614-32-4

triethyloxonium tris(pentafluoroethyl)trifluorophosphate

1-decyl-3-methylimidazol-3-ium chloride

A

60-29-7

diethyl ether

B

75-00-3

chloroethane

C

916807-26-6

1-decyl-3-methylimidazolium tris(pentafluoroethyl)trifluorophosphate

Conditions
ConditionsYield
at 80℃; for 3h;A n/a
B n/a
C 96%
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  • Casno:

    75-00-3

    chloroethane CAS NO.75-00-3

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Consensus Reports

ETHYL CHLORIDE is reported in EPA TSCA Inventory. Community Right-To-Know List.

Standards and Recommendations

OSHA PEL: TWA 1000 ppm
ACGIH TLV: TWA 1000 ppm
DFG MAK: Confirmed Animal Carcinogen with Unknown Relevance to Humans
NIOSH REL: (Chloroethane) Handle with caution
DOT Classification:  2.1; Label: Flammable Gas

Specification

The Ethane, chloro-, with the CAS registry number 75-00-3, is also known as Octamethylsilanetetramine. It belongs to the product categories of Refrigerants; Organics; Halides (Low Boiling point); Alkyl Chlorides; Gas Cylinders; Monofunctional & alpha,omega-Bifunctional Alkanes; Monofunctional Alkanes; Synthetic Organic Chemistry. Its EINECS number is 200-830-5. This chemical's molecular formula is C2H5Cl and molecular weight is 64.51. What's more, its systematic name is chloroethane. (1)Anesthetic [topical]; (2)Anesthetics; (3)Anesthetics, local; (4)Central Nervous System Agents; (5)Central Nervous System Depressants; (6)Drug / Therapeutic Agent; (7)Mutation data; (8)Peripheral Nervous System Agents; (9)Reproductive Effect; (10)Sensory System Agents; (11)TSCA Flag T [Subject to the Section 4 test rule under TSCA]; (12)Tumor data. It is stable at common pressure and temperature, and it should be sealed and stored in a cool and dry place. Moreover, it should be protected from oxides and water. It is used as a refrigerant, an aerosol spray propellant, an anesthetic, and a blowing agent for foam packaging. 

Physical properties of Ethane, chloro- are: (1)ACD/LogP: 1.50; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 1.5; (4)ACD/LogD (pH 7.4): 1.5; (5)ACD/BCF (pH 5.5): 8.14; (6)ACD/BCF (pH 7.4): 8.14; (7)ACD/KOC (pH 5.5): 156.06; (8)ACD/KOC (pH 7.4): 156.06; (9)Index of Refraction: 1.361; (10)Molar Refractivity: 16.16 cm3; (11)Molar Volume: 72.9 cm3; (12)Polarizability: 6.4×10-24cm3; (13)Surface Tension: 17.9 dyne/cm; (14)Density: 0.884 g/cm3; (15)Enthalpy of Vaporization: 24.97 kJ/mol; (16)Boiling Point: 12.7 °C at 760 mmHg; (17)Vapour Pressure: 1170 mmHg at 25°C.

Preparation: this chemical can be prepared by ethylphosphonic acid diethyl ester by heating. This reaction will need reagent SOCl2 with the reaction time of 18 hours. This reaction will also need catalyst DMF. The yield is about 95.8%.

Ethane, chloro- can be prepared by ethylphosphonic acid diethyl ester by heating

Uses of Ethane, chloro-: it can be used to produce 1-Ethyl-4-methylpyridinium chloride at the temperature of 80 °C. It will need solvent acetonitrile with the reaction time of 5 hours. The yield is about 95%.

Ethane, chloro- can be used to produce 1-Ethyl-4-methylpyridinium chloride at the temperature of 80 °C

When you are using this chemical, please be cautious about it as the following:
This chemical is extremely flammable, so you should keep it away from sources of ignition - No smoking. It has a limited evidence of a carcinogenic effect. It is harmful to aquatic organisms as it may cause long-term adverse effects in the aquatic environment. You should keep the container in a well-ventilated place and take precautionary measures against static discharges. When using it, you need wear suitable protective clothing and gloves. You must avoid releasing it to the environment just refering to special instructions/safety data sheet.

You can still convert the following datas into molecular structure:
(1)SMILES: ClCC
(2)Std. InChI: InChI=1S/C2H5Cl/c1-2-3/h2H2,1H3
(3)Std. InChIKey: HRYZWHHZPQKTII-UHFFFAOYSA-N

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
guinea pig LCLo inhalation 40000ppm/45M (40000ppm) BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)

BEHAVIORAL: EXCITEMENT

LUNGS, THORAX, OR RESPIRATION: ACUTE PULMONARY EDEMA
U.S. Public Health Service, Public Health Bulletin. Vol. 185, Pg. 1, 1929.
mouse LC50 inhalation 146gm/m3/2H (146000mg/m3)   "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 66, 1982.
rat LC50 inhalation 152gm/m3/2H (152000mg/m3) BRAIN AND COVERINGS: OTHER DEGENERATIVE CHANGES

BEHAVIORAL: GENERAL ANESTHETIC

BLOOD: HEMORRHAGE
Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv. Toxicology of New Industrial Chemical Substances. For English translation, see TNICS*. Vol. 6, Pg. 45, 1964.