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Cas Database |
| Name |
Trifluoroacetamide |
EINECS | 206-559-9 |
| CAS No. | 354-38-1 | Density | 1.435 g/cm3 |
| PSA | 43.09000 | LogP | 0.73430 |
| Solubility | water: 460 g/L(20 °C) | Melting Point |
65-70 °C(lit.) |
| Formula | C2H2F3NO | Boiling Point | 162.5 °C at 760 mmHg |
| Molecular Weight | 113.039 | Flash Point | 52.1 °C |
| Transport Information | N/A | Appearance | White to pale yellow or beige crystalline powder |
| Safety | 26-36-37/39 | Risk Codes | 36/37/38 |
| Molecular Structure |
|
Hazard Symbols |
 Xi
|
| Synonyms |
2,2,2-Trifluoroacetamide;NSC 9449; |
Article Data | 67 |
Trifluoroacetamide Synthetic route
| Conditions | Yield |
|---|---|
| With hydrogenchloride; triethylamine In ethanol; ethyl acetate | 100% |
| With diethyl ether; ammonia | |
| With methanol; ammonia |
| Conditions | Yield |
|---|---|
| With methylamine at 150℃; under 750.075 Torr; for 10h; Gas phase; | 99.1% |
| Conditions | Yield |
|---|---|
| With ammonia in bomb tube; | A 14% B 99% |
| With NH3 in bomb tube; | A 14% B 99% |
- 52225-57-7
2,2,2-trifluoro-N-{2,2,2-trifluoro-1-(trifluoromethyl) ethylidene}acetamide
- 103-69-5
N-ethyl-N-phenylamine
A
- 65797-85-5
2-(4-(ethylamino)phenyl)-1,1,1,3,3,3-hexafluoropropan-2-ol
B
- 677-71-4
hexafluoroacetone hydrate
C
- 354-38-1
2,2,2-trifluoroacetamide
D
- 106119-57-7
2,4,4-tris(trifluoromethyl)-1-ethyl-1,4-dihydroquinazoline
| Conditions | Yield |
|---|---|
| In chloroform at 20℃; for 1440h; Mechanism; | A n/a B n/a C n/a D 87% E n/a |
- 89567-94-2
N-trifluoroacetyl-Se-(p-bromophenyl)-Se-methylselenimide
A
- 354-38-1
2,2,2-trifluoroacetamide
B
- 78238-44-5
methyl (p-bromophenyl)selenium dichloride
| Conditions | Yield |
|---|---|
| With acetyl chloride In chloroform at 20℃; for 3h; | A 55% B 85% |
- 84353-59-3
1-(2,2,2-trifluoroacetyl)-3-(E)-styrylurea
A
- 354-38-1
2,2,2-trifluoroacetamide
B
- 84353-56-0
(E)-N-(2-phenylethenyl)-2,2,2-trifluoroacetamide
| Conditions | Yield |
|---|---|
| In trifluoroacetic acid at 230℃; for 0.333333h; | A 69% B 22% |
- 84353-55-9
1-(2,2,2-trifluoroacetyl)-3-<2-(2,2,2-trifluoroacetyloxy)-2-phenylethyl>urea
A
- 354-38-1
2,2,2-trifluoroacetamide
B
- 84353-56-0
(E)-N-(2-phenylethenyl)-2,2,2-trifluoroacetamide
| Conditions | Yield |
|---|---|
| In neat (no solvent) at 230℃; for 0.5h; | A 69% B 19% |
- 84353-59-3
1-(2,2,2-trifluoroacetyl)-3-(E)-styrylurea
- 354-38-1
2,2,2-trifluoroacetamide
| Conditions | Yield |
|---|---|
| In neat (no solvent) at 230℃; for 0.333333h; | 68% |
- 126-81-8
dimedone
- 77571-23-4, 78780-20-8, 78780-21-9
N-(trifluoroacetyl)-di(p-methoxyphenyl)tellurimide
A
- 354-38-1
2,2,2-trifluoroacetamide
B
- 57857-72-4
di(p-metoxyphenyl)telluroniodimedonide
| Conditions | Yield |
|---|---|
| In chloroform Ambient temperature; overnight; | A 58% B 67% |
| Conditions | Yield |
|---|---|
| With zirconium(IV) chloride; ammonium carbamate In toluene at 120℃; for 24h; Inert atmosphere; Molecular sieve; | 67% |
Trifluoroacetamide Chemical Properties
IUPAC Name: 2,2,2-Trifluoroacetamide
Following is the structure of Trifluoroacetamide (CAS NO.354-38-1):
Molecular Formula: C2H2F3NO
Molecular Weight: 113.04g/mol
Mol File: 354-38-1.mol
EINECS: 206-559-9
Melting Point: 65-70 °C(lit.)
Boiling point: 162.5 °C(lit.)
Storage Temperature: Store at RT.
Flash Point: 162-164 °C
Water Solubility: 460 g/L (20 °C)
Surface Tension: 21.4 dyne/cm
Enthalpy of Vaporization: 39.91 kJ/mol
Vapour Pressure: 2.16 mmHg at 25°C
XLogP3-AA: 0.1
H-Bond Donor: 1
H-Bond Acceptor: 4
Appearance of Trifluoroacetamide (CAS NO.354-38-1): White to pale yellow or beige crystalline powder
Product Categories of Trifluoroacetamide (CAS NO.354-38-1): Amides; Carbonyl Compounds; Organic Building Blocks
Canonical SMILES: C(=O)(C(F)(F)F)N
InChI: InChI=1S/C2H2F3NO/c3-2(4,5)1(6)7/h(H2,6,7)
InChIKey: NRKYWOKHZRQRJR-UHFFFAOYSA-N
Trifluoroacetamide Safety Profile
Safety Information of Trifluoroacetamide (CAS NO.354-38-1):
Hazard Codes: Xi
Risk Statements: 36/37/38
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36-37/39
26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36: Wear suitable protective clothing
S37/39:Wear suitable gloves and eye/face protection.
Trifluoroacetamide Specification
Trifluoroacetamide , its CAS NO. is 354-38-1, the synonyms are 2,2,2-Trifluoroacetamide ; Acetamide, 2,2,2-trifluoro- ; 2,2,2-Trifluoro-acetamide .
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