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354-38-1

Basic Information
CAS No.: 354-38-1
Name: Trifluoroacetamide
Article Data: 67
Molecular Structure:
Molecular Structure of 354-38-1 (Trifluoroacetamide)
Formula: C2H2F3NO
Molecular Weight: 113.039
Synonyms: 2,2,2-Trifluoroacetamide;NSC 9449;
EINECS: 206-559-9
Density: 1.435 g/cm3
Melting Point: 65-70 °C(lit.)
Boiling Point: 162.5 °C at 760 mmHg
Flash Point: 52.1 °C
Solubility: water: 460 g/L(20 °C)
Appearance: White to pale yellow or beige crystalline powder
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 26-36-37/39
PSA: 43.09000
LogP: 0.73430
Synthetic route
383-63-1

ethyl trifluoroacetate,

354-38-1

2,2,2-trifluoroacetamide

Conditions
ConditionsYield
With hydrogenchloride; triethylamine In ethanol; ethyl acetate100%
With diethyl ether; ammonia
With methanol; ammonia
354-34-7

trifluoroacetyl fluoride

354-38-1

2,2,2-trifluoroacetamide

Conditions
ConditionsYield
With methylamine at 150℃; under 750.075 Torr; for 10h; Gas phase;99.1%
3888-00-4

nitropentafluoroacetone

A

1493-05-6

difluoro-nitro-methane

B

354-38-1

2,2,2-trifluoroacetamide

Conditions
ConditionsYield
With ammonia in bomb tube;A 14%
B 99%
With NH3 in bomb tube;A 14%
B 99%
52225-57-7

2,2,2-trifluoro-N-{2,2,2-trifluoro-1-(trifluoromethyl) ethylidene}acetamide

103-69-5

N-ethyl-N-phenylamine

A

65797-85-5

2-(4-(ethylamino)phenyl)-1,1,1,3,3,3-hexafluoropropan-2-ol

B

677-71-4

hexafluoroacetone hydrate

C

354-38-1

2,2,2-trifluoroacetamide

D

106119-57-7

2,4,4-tris(trifluoromethyl)-1-ethyl-1,4-dihydroquinazoline

E

N-[1-(Ethyl-phenyl-amino)-2,2,2-trifluoro-1-trifluoromethyl-ethyl]-2,2,2-trifluoro-acetamide

Conditions
ConditionsYield
In chloroform at 20℃; for 1440h; Mechanism;A n/a
B n/a
C n/a
D 87%
E n/a
89567-94-2

N-trifluoroacetyl-Se-(p-bromophenyl)-Se-methylselenimide

A

354-38-1

2,2,2-trifluoroacetamide

B

78238-44-5

methyl (p-bromophenyl)selenium dichloride

Conditions
ConditionsYield
With acetyl chloride In chloroform at 20℃; for 3h;A 55%
B 85%
84353-59-3

1-(2,2,2-trifluoroacetyl)-3-(E)-styrylurea

A

354-38-1

2,2,2-trifluoroacetamide

B

84353-56-0

(E)-N-(2-phenylethenyl)-2,2,2-trifluoroacetamide

Conditions
ConditionsYield
In trifluoroacetic acid at 230℃; for 0.333333h;A 69%
B 22%
84353-55-9

1-(2,2,2-trifluoroacetyl)-3-<2-(2,2,2-trifluoroacetyloxy)-2-phenylethyl>urea

A

354-38-1

2,2,2-trifluoroacetamide

B

84353-56-0

(E)-N-(2-phenylethenyl)-2,2,2-trifluoroacetamide

Conditions
ConditionsYield
In neat (no solvent) at 230℃; for 0.5h;A 69%
B 19%
84353-59-3

1-(2,2,2-trifluoroacetyl)-3-(E)-styrylurea

354-38-1

2,2,2-trifluoroacetamide

Conditions
ConditionsYield
In neat (no solvent) at 230℃; for 0.333333h;68%
126-81-8

dimedone

77571-23-4, 78780-20-8, 78780-21-9

N-(trifluoroacetyl)-di(p-methoxyphenyl)tellurimide

A

354-38-1

2,2,2-trifluoroacetamide

B

57857-72-4

di(p-metoxyphenyl)telluroniodimedonide

Conditions
ConditionsYield
In chloroform Ambient temperature; overnight;A 58%
B 67%
76-05-1

trifluoroacetic acid

354-38-1

2,2,2-trifluoroacetamide

Conditions
ConditionsYield
With zirconium(IV) chloride; ammonium carbamate In toluene at 120℃; for 24h; Inert atmosphere; Molecular sieve;67%
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    Product Name: Trifluoroacetamide Synonyms: Three fluoroacetaMide;2,2,2-TRIFLUOROACETAMIDE;TRIFLUOROACETAMIDE;TRIFLUOROACETIC ACID AMIDE;2,2,2-trifluoro-acetamid;CF3CONH2;Triflouroacetamide;TRIFLUOROACETAMIDE 98% CAS: 354-38-1 MF: C2H2F3NO

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    354-38-1

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Chemistry

IUPAC Name: 2,2,2-Trifluoroacetamide
Following is the structure of Trifluoroacetamide (CAS NO.354-38-1):

                
Molecular Formula: C2H2F3NO
Molecular Weight: 113.04g/mol
Mol File: 354-38-1.mol
EINECS: 206-559-9
Melting Point: 65-70 °C(lit.)
Boiling point: 162.5 °C(lit.)
Storage Temperature: Store at RT.
Flash Point: 162-164 °C
Water Solubility: 460 g/L (20 °C)
Surface Tension: 21.4 dyne/cm
Enthalpy of Vaporization: 39.91 kJ/mol
Vapour Pressure: 2.16 mmHg at 25°C
XLogP3-AA: 0.1
H-Bond Donor: 1
H-Bond Acceptor: 4
Appearance of Trifluoroacetamide (CAS NO.354-38-1): White to pale yellow or beige crystalline powder
Product Categories of Trifluoroacetamide (CAS NO.354-38-1): Amides; Carbonyl Compounds; Organic Building Blocks
Canonical SMILES: C(=O)(C(F)(F)F)N
InChI: InChI=1S/C2H2F3NO/c3-2(4,5)1(6)7/h(H2,6,7)
InChIKey: NRKYWOKHZRQRJR-UHFFFAOYSA-N

Safety Profile

Safety Information of Trifluoroacetamide (CAS NO.354-38-1):
Hazard Codes: XiIrritant
Risk Statements: 36/37/38  
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36-37/39
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
36:  Wear suitable protective clothing   
S37/39:Wear suitable gloves and eye/face protection.

Specification

 Trifluoroacetamide , its CAS NO. is 354-38-1, the synonyms are 2,2,2-Trifluoroacetamide ; Acetamide, 2,2,2-trifluoro- ;  2,2,2-Trifluoro-acetamide .