Welcome to LookChem.com Sign In|Join Free
  • or
Home > Products >  > 

Trimethylolpropane diallyl ether
Related Products

Hot Products

Basic Information Post buying leads Suppliers Cas Database
Name

Trimethylolpropane diallyl ether

 EINECS 211-661-1
CAS No. 682-09-7 Density 0.955
PSA 38.69000 LogP 1.78030
Solubility Practically insoluble in water Melting Point N/A
Formula C12H22 O3 Boiling Point 135 ºC (13 mmHg)
Molecular Weight 214.305 Flash Point >110 ºC
Transport Information N/A Appearance N/A
Safety Mildly toxic by ingestion. When heated to decomposition it emits acrid smoke and irritating fumes. See also ETHERS and ALLYL COMPOUNDS. Risk Codes R36/37/38   
Molecular Structure Molecular Structure of 682-09-7 (Trimethylolpropane diallyl ether) Hazard Symbols
Synonyms

1-Butanol,2,2-bis[(2-propenyloxy)methyl]- (9CI); 1-Butanol, 2,2-bis[(allyloxy)methyl]-(6CI,7CI,8CI); 2,2-Bis(allyloxymethyl)-1-butanol; Diallyl trimethylolpropaneether; Neoallyl T 20; T 20; TMPDE 80; Trimethylolpropane diallyl ether;Trimethylpropane diallyl ether

Article Data 4

Trimethylolpropane diallyl ether Synthetic route

77-99-6

1,1,1-tri(hydroxymethyl)propane

107-05-1

3-chloroprop-1-ene

682-09-7

trimethylol propane diallyl ether

Conditions
ConditionsYield
With sodium hydroxide In water at 90℃; Inert atmosphere;
682-09-7

trimethylol propane diallyl ether

144900-28-7

2,4,4-trimethyl-1-pentyl hypophosphorous acid

1189189-14-7

[3-(2-hydroxymethyl-2-{3-[hydroxy-(2,4,4-trimethylpentyl)phosphinoyl]propoxymethyl}butoxy)propyl]-(2,4,4-trimethylpentyl)phosphinic acid

Conditions
ConditionsYield
With di-tert-amyl peroxide at 140℃; for 6h; Inert atmosphere;100%
3234-28-4

1,2-epoxytetradecane

682-09-7

trimethylol propane diallyl ether

C37H74O5

Conditions
ConditionsYield
With potassium methanolate at 120℃; for 20.9h; Inert atmosphere;98.2%
682-09-7

trimethylol propane diallyl ether

C33H34O2

C45H56O5

Conditions
ConditionsYield
With potassium methanolate at 120℃; for 21.7667h; Inert atmosphere;97.9%
682-09-7

trimethylol propane diallyl ether

(2,2-bis((allyloxy)methyl)butan-1-yl)dichlorophosphite

Conditions
ConditionsYield
With phosphorus trichloride In acetonitrile at -15 - 20℃; for 4h; Inert atmosphere;88%
682-09-7

trimethylol propane diallyl ether

3,5-bis(2-bromo-2-methylpropanoyloxy) benzoic acid

C27H36Br2O8

Conditions
ConditionsYield
With dmap; dicyclohexyl-carbodiimide In tetrahydrofuran at 20℃; for 12h;56%
111-83-1

1-bromo-octane

682-09-7

trimethylol propane diallyl ether

3,3-diallyloxymethyl-5-oxa-tridecane

Conditions
ConditionsYield
Stage #1: trimethylol propane diallyl ether With sodium In toluene at 110℃; for 4h;
Stage #2: 1-bromo-octane In toluene for 6 - 10h; Heating / reflux;		55%
682-09-7

trimethylol propane diallyl ether

459-64-3

4-methoxybenzenediazonium tetrafluoroborate

1147550-11-5

ammonium thiocyanate

2-allyloxymethyl-2-[3-(4-methoxy-phenyl)-2-thiocyanato-propoxymethyl]-butan-1-ol

Conditions
ConditionsYield
copper(II) bis(tetrafluoroborate) In water; acetone at 10 - 15℃;35%
682-09-7

trimethylol propane diallyl ether

1147550-11-5

ammonium thiocyanate

459-44-9

4-methylbenzenediazonium tetrafluoroborate

2-allyloxymethyl-2-(2-thiocyanato-3-p-tolyl-propoxymethyl)-butan-1-ol

Conditions
ConditionsYield
copper(II) bis(tetrafluoroborate) In water; acetone at 10 - 15℃;35%
682-09-7

trimethylol propane diallyl ether

1147550-11-5

ammonium thiocyanate

369-57-3

benzenediazonium tetrafluoroborate

2-[(allyloxy)methyl]-2-[(3-phenyl-2-thiocyanatopropoxy)methyl]butan-1-ol

Conditions
ConditionsYield
copper(II) bis(tetrafluoroborate) In water; acetone at 10 - 15℃;31%

Trimethylolpropane diallyl ether Chemical Properties

IUPAC Name: 2,2-Bis(prop-2-enoxymethyl)butan-1-ol (682-09-7)
Synonyms:1,1,1-Trimethylolpropane diallyl ether ; 1,1,1-(Trihydroxymethyl)propane diallyl ether ; 2-Ethyl-2-(hydroxymethyl)-1 3-propanediol diallyl ether ; 2,2-Bis(allyloxymethyl)-1-butanol ;Ttrimethylolpropane diallyl ether ; 1-Butanol,2,2-bis[(2-propenyloxy)methyl]- ; 2,2-Bis[(2-propenyloxy)methyl]-1-butano ; 2,2-Bis[(2-propenyloxy)methyl]-1-Butanol
CAS: 682-09-7
MF: C12H22O3
MW: 214.3
MS:
EINECS: 211-661-1
Mol File: 682-09-7.mol
Surface Tension: 31.6 dyne/cm 
Density: 0.943 g/cm3 
Flash Point: 133.7 °C 
Enthalpy of Vaporization: 62.34 kJ/mol 
Boiling Point: 297.5 °C at 760 mmHg
Vapour Pressure: 0.000136 mmHg at 25°C 
Refractive index:  n20/D 1.458(lit.)

Trimethylolpropane diallyl ether Uses

Trimethylolpropane diallyl ether (682-09-7) is used as an organic intermediate.

Trimethylolpropane diallyl ether Toxicity Data With Reference

1.    

orl-rat LD50:6500 mg/kg

     IHFCAY    Industrial Hygiene Foundation of America, Chemical and Toxicological Series, Bulletin. 6 (1967),1.

Trimethylolpropane diallyl ether Consensus Reports

Reported in EPA TSCA Inventory.

Trimethylolpropane diallyl ether Safety Profile

Hazard Codes:  Xi
Risk Statements:  36/37/38
36/37/38: Trimethylolpropane diallyl ether (682-09-7) is irritating to eyes, respiratory system and skin.
Safety Statements:  26-36
26: Trimethylolpropane diallyl ether (682-09-7) used, in case of contact with eyes,please rinse immediately with plenty of water and seek medical advice.
36:  Wear suitable protective clothing .
WGK Germany : 2
RTECS:  TY6667000

Post a RFQ

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

1

What can I do for you?
Get Best Price

Get Best Price for 682-09-7