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| CAS No.: | 10101-97-0 |
|---|---|
| Name: | Nickel sulfate hexahydrate |
| Molecular Structure: | |
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|
|
| Formula: | NiSO4.6(H2O) |
| Molecular Weight: | 262.89 |
| Synonyms: | Sulfuricacid, nickel(2+) salt (1:1), hexahydrate (8CI,9CI);Nickel monosulfatehexahydrate;Nickel sulfate (NiSO4) hexahydrate;Nickel sulfate hydrate (NiSO4.6H2O);Nickel(2+) monosulfate hexahydrate;Nickel(2+) sulfate hexahydrate;Nickel(II) sulfate hexahydrate;Sulfuric acid,nickel(2+) salt, hydrate (1:1:6); |
| EINECS: | 231-111-4 |
| Density: | 2.07 g/cm3 |
| Melting Point: | 1453 °C(lit.) |
| Boiling Point: | 330 °C at 760 mmHg |
| Solubility: | soluble in water |
| Appearance: | Green crystals |
| Hazard Symbols: |
 T, Xi, N, Xn, F
|
| Risk Codes: | 45-52/53-50/53-42/43-40-22-36/37-23/24/25-11-36/38 |
| Safety: | 53-45-61-60-36/37-22-36/37/39-26-16 |
| Transport Information: | UN 3178 4.1/PG 2 |
| PSA: | 144.02000 |
| LogP: | -0.64300 |
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Consensus Reports
Standards and Recommendations
ACGIH TLV: TWA 0.2 mg(Ni)/m3; Human Carcinogen
NIOSH REL: (Inorganic Nickel) TWA 0.015 mg(Ni)/m3
Specification
The Nickel(II) sulfate hexahydrate (1:1:6) is an organic compound with the formula NiSO4.6(H2O). The IUPAC name of this chemical is nickel(2+) sulfate hexahydrate. With the CAS registry number 10101-97-0, it is also named as Sulfuric acid, nickel(2+) salt, hexahydrate. The product's categories are Chemical Synthesis; Metals; NickelMetal and Ceramic Science; Alternative Energy; Catalysis and Inorganic Chemistry; Fuel Cell Catalysts Chemical Synthesis; Materials Science; Analytical Reagents for General Use ;M-N, Puriss p.a. ACS; Puriss p.a. ACS; ACS GradeChemical Synthesis; Essential Chemicals; Routine Reagents; HIS Select Supporting Products and Reagents; HIS-Select; Reagents and Products for use with HIS-Select; Allergens; Extractable Heavy metals Application CRMs; ICP CRMsCosmetics; ICP-OES/-MS; ICPSpectroscopy; Matrix Selection; Metals Alphabetic; Method Specific; N; NA - NISpectroscopy; NitrateMore...Close...; Oeko-Tex Standard 100; Spectroscopy. Besides, it is a green crystal, which should be stored in a cool dry and ventilated place.
The Nickel(II) sulfate hexahydrate (1:1:6) is mainly used in electroplating industry, which is the main raw material of nickel. It is used to produce brilliant blue phthalocyanine complexing agent and restore mordant dyes in printing and dyeing industry. In pharmaceutical industry, it is used to produce catalyst of vitamin C.
Physical properties about Nickel(II) sulfate hexahydrate (1:1:6) are: (1)ACD/LogP: -1.03; (2)ACD/LogD (pH 5.5): -5.53; (3)ACD/LogD (pH 7.4): -5.53; (4)ACD/BCF (pH 5.5): 1; (5)ACD/BCF (pH 7.4): 1; (6)ACD/KOC (pH 7.4): ; (7)#H bond acceptors: 4; (8)#H bond donors: 2; (9)Polar Surface Area: 82.98 Å2; (10)Enthalpy of Vaporization: 62.94 kJ/mol; (11)Boiling Point: 330 °C at 760 mmHg; (12)Vapour Pressure: 3.35E-05 mmHg at 25°C.
Preparation: this chemical can be prepared by Nickel-containing waste solution. Chemical reaction equation is as follows:
When you are using this chemical, please be cautious about it as the following:
It is highly flammable and harmful if swallowed. Please keep away from sources of ignition - No smoking and do not breathe dust. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Besides, this chemical may cause sensitisation by inhalation and skin contact and may cause cancer. It is very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment and harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment. When you are using it, wear suitable gloves and eye/face protection and avoid exposure - obtain special instructions before use. In case of accident or if you feel unwell seek medical advice immediately (show the label where possible). This material and its container must be disposed of as hazardous waste.
You can still convert the following datas into molecular structure:
(1)SMILES: [Ni+2].[O-]S([O-])(=O)=O.O.O.O.O.O.O
(2)InChI: InChI=1/Ni.H2O4S.6H2O/c;1-5(2,3)4;;;;;;/h;(H2,1,2,3,4);6*1H2/q+2;;;;;;;/p-2
(3)InChIKey: RRIWRJBSCGCBID-NUQVWONBAU
(4)Std. InChI: InChI=1S/Ni.H2O4S.6H2O/c;1-5(2,3)4;;;;;;/h;(H2,1,2,3,4);6*1H2/q+2;;;;;;;/p-2
(5)Std. InChIKey: RRIWRJBSCGCBID-UHFFFAOYSA-L
The toxicity data is as follows:
| Organism | Test Type | Route | Reported Dose (Normalized Dose) | Effect | Source |
|---|---|---|---|---|---|
| cat | LDLo | intravenous | 71600ug/kg (71.6mg/kg) | Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975. | |
| cat | LDLo | subcutaneous | 500mg/kg (500mg/kg) | Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975. | |
| dog | LDLo | intravenous | 89500ug/kg (89.5mg/kg) | Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975. | |
| guinea pig | LDLo | subcutaneous | 62mg/kg (62mg/kg) | Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975. | |
| rabbit | LDLo | intravenous | 35800ug/kg (35.8mg/kg) | Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975. | |
| rabbit | LDLo | subcutaneous | 500mg/kg (500mg/kg) | Environmental Quality and Safety, Supplement. Vol. 1, Pg. 1, 1975. | |
| rat | LD50 | oral | 264mg/kg (264mg/kg) | BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) GASTROINTESTINAL: CHANGES IN STRUCTURE OR FUNCTION OF SALIVARY GLANDS GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" | Acute Toxicity Data. Journal of the American College of Toxicology, Part B. Vol. 1, Pg. 685, 1992. |