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10241-05-1

Basic Information
CAS No.: 10241-05-1
Name: MOLYBDENUM(V) CHLORIDE
Article Data: 63
Molecular Structure:
Molecular Structure of 10241-05-1 (MOLYBDENUM(V) CHLORIDE)
Formula: MoCl5
Molecular Weight: 273.205
Synonyms: Molybdenumpentachloride;Molybdenum(V) chloride;Pentachloromolybdenum;
EINECS: 233-575-3
Density: 2.928 g/mL at 25 °C(lit.)
Melting Point: 194 °C(lit.)
Boiling Point: 268 °C(lit.)
Solubility: soluble in dry ether and dry alcohol, in other organic solvents [HAW93]
Appearance: dark blue to black crystals
Hazard Symbols: CorrosiveC
Risk Codes: 29-34-48/20/22
Safety: 26-36/37/39-43-45
Transport Information: UN 2508 8/PG 3
PSA: 0.00000
LogP: 3.44750
Synthetic route
7782-50-5

chlorine

7439-98-7

molybdenum

10241-05-1

molybdenum(V) chloride

Conditions
ConditionsYield
dry chlorine was passed over finely divided molebdenum at 300°C; sublimation;88%
at elevated temp.;
exotermic; reversible react. in zone at 1400 °C;
116-15-4

perfluoropropylene

molybdenum(VI) oxide

10241-05-1

molybdenum(V) chloride

Conditions
ConditionsYield
by heating;
by heating;
10545-99-0

sulfur dichloride

molybdenum(VI) oxide

10241-05-1

molybdenum(V) chloride

Conditions
ConditionsYield
reduced pressure, 160-180°C, 10h;

molybdenum(VI) oxide

A

10241-05-1

molybdenum(V) chloride

B

55171-05-6, 13814-75-0

molybdenum(VI) tetrachloride oxide

C

13637-68-8

dioxomolybdenum(VI) dichloride

Conditions
ConditionsYield
With chlorine in presence of C (C:MoO3=3:1), start at 80°C: 190-600°C;

molybdenum(VI) oxide

10241-05-1

molybdenum(V) chloride

Conditions
ConditionsYield
With chlorine in presence of C; above 600°C (>18 l/h); C:MoO3 = 4:1;
With tetrachloromethane at 400°C;
With chlorine in presence of C (C:MoO3=3:1), start at 80°C: above 600°C;
With tetrachloromethane at 400°C;
10026-04-7, 53609-55-5

tetrachlorosilane

molybdenum(VI) oxide

A

molybdenum(VI) oxide chloride

B

10241-05-1

molybdenum(V) chloride

C

13637-68-8

dioxomolybdenum(VI) dichloride

Conditions
ConditionsYield
In neat (no solvent) byproducts: Cl2; heating of SiCl4 and MoO3 in a closed tube at 260-270°C;;
56-23-5

tetrachloromethane

molybdenum(VI) oxide

10241-05-1

molybdenum(V) chloride

Conditions
ConditionsYield
In neat (no solvent) passing steam of CCl4 over MoO3 at 510 °C;;
In neat (no solvent) heating of MoO3 with CCl4 at about 280°C in a closed tube for 3 hours;;
In neat (no solvent) react. of MoO3 with CCl4 vapor at 510°C in absence of air;;
10026-13-8, 874483-75-7

phosphorus pentachloride

molybdenum(VI) oxide

10241-05-1

molybdenum(V) chloride

Conditions
ConditionsYield
In neat (no solvent) heating of a mixt. of MoO3 and PCl5 in CO2-atm.; vigorous react. with formation of white and brown vapors;;
7647-01-0

hydrogenchloride

molybdenum(VI) oxide

A

13814-74-9

oxomolybdenum(V) chloride

B

10241-05-1

molybdenum(V) chloride

C

7782-50-5

chlorine

D

55171-05-6, 13814-75-0

molybdenum(VI) tetrachloride oxide

E

13637-68-8

dioxomolybdenum(VI) dichloride

Conditions
ConditionsYield
In solid byproducts: H2O; thermal decomposition of mixt. of MoO3 with poly(vinylchloride) or cerechlor 70 with different mole ratios in air, the heating rate of 10 deg/min at 20-850°C;
7782-50-5

chlorine

molybdenum(VI) oxide

10241-05-1

molybdenum(V) chloride

Conditions
ConditionsYield
In tetrachloromethane heating of MoO3 with a dry soln. of Cl2 in CCl4 at 240°C in a closed tube for 3 hours;; crystn.; washing with CCl4 in CO2-atm.; sucking off; drying in vac.;;>99
In tetrachloromethane heating of MoO3 with a dry soln. of Cl2 in CCl4 at 240°C in a closed tube for 3 hours;; crystn.; washing with CCl4 in CO2-atm.; sucking off; drying in vac.;;>99
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    Items Standard Result MoCl5 ≥99.60 99.73 Mo ≥34.9780 35.018

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  • MOLYBDENUM(V) CHLORIDE CAS NO.: 10241-05-1

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    Formula: MoCl5Molecular Weight : 273.20 Synonyms: Molybdenumpentachloride;Molybdenum(V) chloride;Pentachloromolybdenum; EINECS: 233-575-3Density: 2.928 g/mL at 25 °C(lit.)Melting Point:Boiling Point: 268 °C(lit.) Application:Catalysi

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  • CSR160805-25694

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    CSR160805-25694

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    Purity, Prompt shipment, Price Application:surface active agent

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  • Molybdenum pentachloride

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    10241-05-1

    Molybdenum pentachloride

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    Prime Molecular Co., Ltd. is a high-tech enterprise providing comprehensive customer service for pharmaceutical companies at home and abroad in accordance with international standards. Two R&D centers and two production sites in China, all well-equip

    Prime Molecular Co., Ltd. is an advanced chemical intermediates manufacture with ?two R&D centers and two production sites in China, all well-equipped with dedicated and profession

  • PRIME MOLECULAR CO.,LIMITED

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    Address:Hong Kong

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  • Molybdenum(V) chloride

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    10241-05-1

    Molybdenum(V) chloride

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    Hangzhou Keying Chem Co., Ltd. Is a comprehensive enterprise, dedicated to the development, production and marketing of chemicals. As a technology innovative and service professional enterprise, Our company mainly engages in global pharmaceutical, ch

    Hangzhou Fenjunchem Co.,Ltd dedicated to the development, production and marketing of chemicals which is specialized in Organic compounds; Active Pharmaceutical Ingredient(s); Nutr

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    Tel:+86-0571-56263321

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  • MOLYBDENUM(V)CHLORIDE

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    MOLYBDENUM(V)CHLORIDE

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  • Sparrow Chemical Co.,Ltd

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    Tel:86-531-67865410

    Address:Jinan City,Shandong Province,China

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  • Molybdenum chloride(MoCl5)

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    10241-05-1

    Molybdenum chloride(MoCl5)

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    Molybdenum chloride(MoCl5)Appearance:Off white to slight yellow solid Storage:Stored in shaded, cool and dry places Package:1L 5L 10L 25L bottle Application:pharma intermediate Transportation:Handle with cares to avoid damaging the packages. Protect

  • Chemical Co.Ltd

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  • molybdenum pentachloride

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    10241-05-1

    molybdenum pentachloride

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    high purity Application:Drug intermediates Materials intermediates and active molecules

    Novachemistry offers a broad range of specialty chemicals and customized synthesis services to a range of pharmaceutical, agrochemical and biochemical industries. Novachemistry has

  • NovaChemistry

    United Kingdom  |  Contact Details

    Business Type:Trading Company

    Tel:+44 (0)208 191 7890

    Address:Unit11, Ark Business Centre, Gorden Road, Loughborough, United Kingdom

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Chemistry

Chemistry informtion about  Molybdenum(V) Chloride (10241-05-1) is:
IUPAC Name: Pentachloromolybdenum
Synonyms: Molybdenum(V) Chloride ; Molybdenum Chloride ; Molybdenum Pentachloride ; Molybdenum(+5)Chloride ; Mocl5 ; Molybdenum Chloride (Mocl5) ; Molybdenumchloride(Mocl5) ; Molybdenum(V) Chloride, Anhydrous, Powd&
MF: Cl5Mo
MW: 273.2
EINECS: 233-575-3
Melting Point: 194 °C(lit.)
Density: 2.928 g/mL at 25 °C(lit.)
Boiling Point: 268 °C(lit.)
Vapour Pressure: 1.75 mm Hg ( 25 °C)
Form: powder
Sensitive: Moisture Sensitive
Stability: Stable, but moisture and air-sensitive. Contact with water liberates toxic gas. Incompatible with water, strong oxidizing agents.
Following is the molecular structure of  Molybdenum(V) Chloride (10241-05-1) is:

Uses

 Molybdenum(V) Chloride (10241-05-1) can be used in chlorinations and deoxygenation reactions.

Consensus Reports

Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.

Safety Profile

A poison. A corrosive irritant to skin, eyes, and mucous membranes. Reacts with moisture to form hydrochloric acid. When heated to decomposition it emits toxic fumes of Mo and Cl. See also MOLYBDENUM COMPOUNDS and HYDROCHLORIC ACID.
Hazard Codes:
C: Corrosive
Risk Statements:
R29: Contact with water liberates toxic gas.
R34: Causes burns.
R48/20/22: Danger of serious damage to health by prolonged exposure and harmful by inhalation and if swallowed.
Safety Statements:
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S43: In case of fire use ... (there follows the type of fire-fighting equipment to be used.)
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 2508 8/PG 3
WGK Germany: 3
RTECS: QA4690000
F: 1-3-10 Sensitive to air and humidity&Hygroscopic&Keep under argon.
HazardClass: 8
PackingGroup: III

Standards and Recommendations

OSHA PEL: TWA 5 mg(Mo)/m3
ACGIH TLV: TWA Soluble Compounds: TWA 0.5 mg(Mo)/m3 Confirmed Animal Carcinogen with Unknown Relevance to Humans
DOT Classification:  8; Label: Corrosive

Specification

General description about  Molybdenum(V) Chloride (10241-05-1). It is a dark blue to black crystals.Also,it  is a green-black odorless solid. it  is toxic by ingestion and an irritant to skin. it may react with water to produce corrosive hydrochloric acid and toxic fumes.
Air & Water Reactions:  Molybdenum(V) Chloride (10241-05-1) may react with water to produce corrosive hydrochloric acid and toxic fumes.
Reactivity Profile: It is a corrosive, hygroscopic solid, on contact with water or steam it decomposes to form hydrochloric acid. When heated to decomposition it emits toxic fumes of molybdenum chlorides and metallic molybdenum [Lewis, 3rd ed., 1993, p. 892]. Explodes on contact with finely divided sodium [Berry D. H., Chem. Eng. News, 1989, 67(47), p. 2]. Reaction with finely divided sodium sulfide is violent, may lead to autoignition [Kaner, R. B., Nature, 1991, 349, p. 510].
Health Hazard: Toxic;inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Contact with molten substance may cause severe burns to skin and eyes. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire Hazard: Combustible material: may burn but does not ignite readily. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.