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CAS No.: | 110590-84-6 | ||
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Name: | N,N'-BIS(1-HEXYLHEPTYL)-PERYLENE-3,4:9,10-BIS-(DICARBOXIMIDE) | ||
Article Data: | 30 | ||
Molecular Structure: | |||
Formula: | C50H62 N2 O4 | ||
Molecular Weight: | 755.053 | ||
Synonyms: | 2,9-Bis(1-hexyl-hept-1-yl)anthra[2,1,9-def:6,5,10-d'e'f']diisoquinoline-1,3,8,10-tetrone;BHPD; N,N'-Bis(1-hexylheptyl)-3,4:9,10-perylenebis(dicarboximide);N,N'-Bis(1-hexylheptyl)-3,4:9,10-perylenetetracarboxylic diimide;N,N'-Bis(1-hexylheptyl)perylene-3,4:9:10-tetracarboxylic bisimide | ||
Density: | 1.149±0.06 g/cm3(Predicted) | ||
Melting Point: | 157-158 °C(Solv: methanol (67-56-1)) | ||
Boiling Point: | 842.4±38.0 °C(Predicted) | ||
Safety: |
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PSA: | 78.14000 | ||
LogP: | 12.92680 |
1-hexylheptylamine
perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride
N-(1-hexylheptyl)perylene-3,4,9,10-tetracarboxylic-3,4-anhydride-9,10-imide
Conditions | Yield |
---|---|
With 1H-imidazole at 180℃; for 5h; | 100% |
With 1H-imidazole In dichloromethane at 150℃; for 5h; | 100% |
With 1H-imidazole; zinc diacetate at 155℃; for 4h; | 99% |
1H-imidazole
1-hexylheptylamine
perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride
C
N-(1-hexylheptyl)perylene-3,4,9,10-tetracarboxylic-3,4-anhydride-9,10-imide
Conditions | Yield |
---|---|
at 160℃; for 4h; | A 0.7% B 0.07% C 82% |
propyl bromide
A
N-(1-hexylheptyl)-9,10-bis(propyloxycarbonyl)perylene-3,4-dicarboximide
B
N-(1-hexylheptyl)perylene-3,4,9,10-tetracarboxylic-3,4-anhydride-9,10-imide
Conditions | Yield |
---|---|
In N,N-dimethyl-formamide at 25℃; for 16h; | A 58% B 15% |
1-hexylheptylamine
perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride
A
PERYLENE
B
N-(1-hexylheptyl)perylene-3,4,9,10-tetracarboxylic-3,4-anhydride-9,10-imide
C
2-(1-hexylheptyl)-1H-benzo-[5,10]anthra[2,1,9-def ]isoquinolin-1,3(2H)-dione
Conditions | Yield |
---|---|
With 1H-imidazole; zinc diacetate; water at 190℃; for 24h; | A n/a B 15% C 27% |
tridecan-7-one
N-(1-hexylheptyl)perylene-3,4,9,10-tetracarboxylic-3,4-anhydride-9,10-imide
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 90 percent / NH4OAc; NaBH3CN / methanol / 48 h / 20 °C 2: imidazole / 5 h / 180 °C View Scheme | |
Multi-step reaction with 2 steps 1: ammonium acetate; sodium cyanoborohydride / methanol / 56 h / 20 °C 2: 1H-imidazole / 3 h / 130 °C View Scheme | |
Multi-step reaction with 2 steps 1: ammonium acetate; sodium cyanoborohydride / methanol / 60 h / 20 °C 2: 1H-imidazole / 4 h / 160 °C View Scheme |
tridecan-7-one oxime
N-(1-hexylheptyl)perylene-3,4,9,10-tetracarboxylic-3,4-anhydride-9,10-imide
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: sodium-dihydrobis(2-methoxyethoxy)aluminate / toluene / 4 h / 140 °C 2: 41 percent / imidazole / 4 h / 160 °C View Scheme | |
Multi-step reaction with 2 steps 1: lithium aluminium tetrahydride / tetrahydrofuran 2: 1H-imidazole / 150 °C View Scheme |
1-hexylheptylamine
4-(5,5-dimethyl-1,3-dioxan-2-yl)benzylamine
perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride
B
N-(1-hexylheptyl)perylene-3,4,9,10-tetracarboxylic-3,4-anhydride-9,10-imide
Conditions | Yield |
---|---|
With 1H-imidazole at 160℃; for 24h; |
1-hexylheptylamine
A
N-(1-hexylheptyl)-9,10-bis(propyloxycarbonyl)perylene-3,4-dicarboximide
B
N-(1-hexylheptyl)perylene-3,4,9,10-tetracarboxylic-3,4-anhydride-9,10-imide
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: 1,8-diazabicyclo[5.4.0]undec-7-ene / N,N-dimethyl-formamide / 16 h / 25 °C 1.2: 72 h / 25 °C 2.1: N,N-dimethyl-formamide / 16 h / 25 °C View Scheme |
perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride
A
N-(1-hexylheptyl)-9,10-bis(propyloxycarbonyl)perylene-3,4-dicarboximide
B
N-(1-hexylheptyl)perylene-3,4,9,10-tetracarboxylic-3,4-anhydride-9,10-imide
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1.1: 1,8-diazabicyclo[5.4.0]undec-7-ene / N,N-dimethyl-formamide / 16 h / 25 °C 1.2: 72 h / 25 °C 2.1: N,N-dimethyl-formamide / 16 h / 25 °C View Scheme |
tridecan-7-one
perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride
N-(1-hexylheptyl)perylene-3,4,9,10-tetracarboxylic-3,4-anhydride-9,10-imide
Conditions | Yield |
---|---|
Stage #1: tridecan-7-one With ammonium acetate; sodium cyanoborohydride In methanol at 20℃; for 48h; Inert atmosphere; Stage #2: perylene-3,4,9,10-tetracarboxylic acid 3,4:9,10-dianhydride With 1H-imidazole at 130℃; for 3h; Inert atmosphere; | 8.57 g |