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Basic Information

Molecular Structure:
CAS No.:	112-62-9
Name:	Methyl oleate
Article Data:	158

Formula:	C₁₉H₃₆O₂
Molecular Weight:	296.494
Synonyms:	9-Octadecenoicacid (Z)-, methyl ester;Oleic acid, methyl ester (6CI,8CI);(Z)-9-Octadecenoicacid methyl ester;ADJ 100;Agnique ME 181U;Agrique ME 181-1;CE 1897;Carolube 1885;Edenor Me 90/95V;Edenor MeTiO5;Emerest 2801;Emery 2301;Esterol 112;Exceparl M-OL;Methyl (Z)-9-octadecenoate;Methylcis-9-octadecenoate;Nissan Unister M 182A;Pastel M 181;Phytorob926-67;Priolube 1400;Priolube 1403;Radia 7060;Synative ES-ME-V;Unister M182A;Witconol 2301;cis-9-Octadecenoic acid, methyl ester;
EINECS:	203-992-5
Density:	0.873 g/cm³
Melting Point:	-20 °C
Boiling Point:	351.4 °C at 760 mmHg
Flash Point:	92.4 °C
Solubility:	Insoluble in water
Appearance:	colourless liquid
Hazard Symbols:	F, Xn, N
Risk Codes:	11-38-50/53-65-67
Safety:	23-24/25-62-61-60-33-29-16-9
Transport Information:	UN 1206 3/PG 2
PSA:	26.30000
LogP:	6.19690

Synthetic route

: 67-56-1
methanol

: 112-80-1
cis-Octadecenoic acid

: 112-62-9
Methyl oleate

Conditions

Conditions	Yield
With Mesoscopically Assembled SulfatedZirconia Nanoparticles at 49.84℃; for 8h; Catalytic behavior; Reagent/catalyst; Temperature;	100%
With sulfuric acid; trimethyl orthoformate for 10h; Reflux;	100%
With ammonium cerium(IV) nitrate at 20℃; for 2h;	99%

: 67-56-1
methanol

: 122-32-7
trioleoylglycerol

: 112-62-9
Methyl oleate

Conditions

Conditions	Yield
With methanesulfonic acid at 80℃;	98%
With SO3H and NH2+ functional carbon-based solid acid at 100℃; under 760.051 Torr; for 8h; Catalytic behavior; Temperature; Sealed tube;	95%
With sulfuric acid at 30℃; Kinetics;

: 1120-32-7
stearolic acid methyl ester

: 112-62-9
Methyl oleate

Conditions

Conditions	Yield
With hydrogen; ethylenediamine In ethanol; water stereoselective reaction;	97%
With ethanol; nickel Hydrogenation;
With sodium hypophosphite; Pd/Pb/C In tetrahydrofuran for 19.5833h; Ambient temperature;	97 % Chromat.
With palladium diacetate; bis-(1,2-dimethylpropyl)borane 2.) THF, RT, overnight; Yield given. Multistep reaction;

: 112-80-1
cis-Octadecenoic acid

: 149-73-5
trimethyl orthoformate

: 112-62-9
Methyl oleate

Conditions

Conditions	Yield
With sulfuric acid In methanol at 20℃;	96%

: 112-80-1
cis-Octadecenoic acid

: 18107-18-1
diazomethyl-trimethyl-silane

: 112-62-9
Methyl oleate

Conditions

Conditions	Yield
In methanol; diethyl ether; toluene at 20℃; for 0.5h;	96%
In methanol; diethyl ether; toluene at 20℃; for 0.5h;
In hexane at 30℃; for 0.166667h;

O-methyl-N-cyclohexyl-N\-methylpolystyrene isourea: O-methyl-N-cyclohexyl-N\-methylpolystyrene isourea

: 112-80-1
cis-Octadecenoic acid

: 112-62-9
Methyl oleate

Conditions

Conditions	Yield
In acetonitrile at 120℃; for 0.0833333h; microwave irradiation;	96%

: 914805-17-7
octadec-9-enoic acid N',N'-dimethyl-hydrazide

: 67-56-1
methanol

: 112-62-9
Methyl oleate

Conditions

Conditions	Yield
With Dowex 50WX8-100 at 70℃; for 24h;	94%

: 6085-36-5, 55726-25-5, 24909-72-6
oleic anhydride

: 1125-88-8
benzaldehyde dimethyl acetal

: 112-62-9
Methyl oleate

Conditions

Conditions	Yield
With boron trifluoride diethyl etherate In chloroform at 61℃; for 4h; Acylation;	93%

: 2566-91-8
epoxidized methyl oleate

: 112-62-9
Methyl oleate

Conditions

Conditions	Yield
With aluminium(III) iodide In acetonitrile; benzene for 1h;	92%

: 914805-23-5
C27H52N2O3

: 67-56-1
methanol

: 112-62-9
Methyl oleate

Conditions

Conditions	Yield
With Dowex 50WX8-100 at 20℃; for 12h;	92%

Raw Materials

57-10-3

53657-29-7

112-39-0

122-32-7

1576-84-7

74-88-4

1125-88-8

303-43-5

Downstream Products

67-56-1

112-80-1

124-07-2

303-43-5

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Chemistry

Product Name:(Z)-9-Octadecenoic acid methyl ester(112-62-9)
CAS No:112-62-9
MF: C₁₉H₃₆O₂
MW: 296.49
mp : -20 °C
bp : 218 °C
density : 0.874 g/mL at 20 °C(lit.)
vapor pressure :10 mm Hg ( 205 °C)
refractive index : n20/D 1.452(lit.)
Fp : >230 °F
storage temp. : -20°C
Appearance:Clear to amber liquid.
Solubility in water:Insoluble
Synonyms of (Z)-9-Octadecenoic acid methyl ester(112-62-9): cis-oleic acid,methyl ester`s Synonyms: C18:1 (CIS-9) METHYL ESTER;EMERY OLEIC ACID ESTER;DELTA 9 CIS OCTADECENOIC ACID METHYL ESTER;CIS-OLEIC ACID METHYL ESTER;CIS-9-OCTADECENOIC ACID METHYL ESTER;METHYL OLEATE;METHYLOCTADECENOATE;METHYL (Z)-9-OCTADECENOATE
Molecular Structure of (Z)-9-Octadecenoic acid methyl ester(112-62-9):

Uses

Intermediate for detergents, emulsifiers, wetting agents, stabilizers, textiles treatment, plasticizers for duplicating inks, rubbers, waxes, chromatographic reference standard

Toxicity Data With Reference

RTECS : RK0895000
RTECS Class:Tumorigen

Ingestion: cis-oleic acid,methyl ester may cause irritation of the digestive tract. The toxicological properties of this substance have not been fully investigated.
Inhalation: cis-oleic acid,methyl ester may cause respiratory tract irritation. The toxicological properties of this substance have not been fully investigated.
cis-oleic acid,methyl ester may also cause skin and eye irritation.

Consensus Reports

Stability:Stable at room temperature in closed containers under normal storage and handling conditions.

First aid measures:
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.

Storage: Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.
Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation.

Safety Profile

Hazard Codes : F,Xn,N
Risk Statements :11-38-50/53-65-67
Safety Statements : 23-24/25-62-61-60-33-29-16-9
RIDADR : UN 1206 3/PG 2
WGK Germany : 1
F : 8-23

Specification

cis-oleic acid,methyl ester`s Categories: Biochemistry;Fatty Acid Esters (Plasticizer);Functional Materials;Higher Fatty Acids & Higher Alcohols;Plasticizer;Unsaturated Higher Fatty Acid Esters;Analytical Chemistry;Fatty Acid Methyl Esters (GC Standard);Standard Materials for GC

Personal Protection: Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to prevent skin exposure.

Fire Fighting:Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire use water spray, dry chemical, carbon dioxide, or appropriate foam.