Products Categories
| CAS No.: | 113664-24-7 |
|---|---|
| Name: | [1,1'-Biphenyl]-4,4'-diamine, N4,N4,N4',N4'-tetrakis(4-bromophenyl)- |
| Molecular Structure: | |
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| Formula: | C36H24Br4N2 |
| Molecular Weight: | 804.216 |
| Synonyms: | N,N,N',N'-tetrakis(p-bromophenyl)-biphenyl-4,4'-diamine;N,N,N’,N’-tetrakis(4-bromophenyl)benzidine;N4,N4,N4',N4'-tetrakis(4-bromophenyl)-[1,1'-biphenyl]-4,4'-diamine;N,N,N',N'-tetrakis(4-bromophenyl)biphenyl-4,4'-diamine;N,N,N′,N′-tetrakis(4-bromophenyl)biphenyl-4,4′-diamine;N4,N4,N4',N4'-Tetrakis-(4-bromo-phenyl)-biphenyl-4,4'-diamine;N4,N4,N4',N4'-tetrakis(4-bromophenyl)biphenyl-4,4'-diamine; |
| PSA: | 6.48000 |
| LogP: | 13.34320 |
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- 50288-62-5threo-Phenyl-2-piperidyl acetamide
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- 1219080-61-1IMIDAZOLE-2-BORONIC ACID
- 81090-53-1
N,N-bis(4-bromophenyl)aniline
- 113664-24-7
N,N,N′,N′-tetrakis(4-bromophenyl)[1,1′-biphenyl]-4,4′-diamine
| Conditions | Yield |
|---|---|
| With methanesulfonic acid; 2,3-dicyano-5,6-dichloro-p-benzoquinone In dichloromethane at 0℃; for 0.5h; | 100% |
| Stage #1: N,N-bis(4-bromophenyl)aniline With methanesulfonic acid In dichloromethane at 0℃; Stage #2: With chloranil In dichloromethane at 0 - 20℃; for 0.0166667h; | 99% |
| With tungsten(VI) chloride In dichloromethane Inert atmosphere; | 60% |
| With tetrafluoroboric acid diethyl ether; C22H42N12*2BF4(1-)*2H(1+) In acetonitrile at 20℃; Reagent/catalyst; Cooling with ice; | 95 %Spectr. |
- 15546-43-7
N,N,N',N'-tetraphenyl-4,4'-diaminobiphenyl
- 113664-24-7
N,N,N′,N′-tetrakis(4-bromophenyl)[1,1′-biphenyl]-4,4′-diamine
| Conditions | Yield |
|---|---|
| With N-Bromosuccinimide In tetrahydrofuran at 40℃; for 16h; | 91.4% |
| Stage #1: N,N,N',N'-tetraphenyl-4,4'-diaminobiphenyl With N-Bromosuccinimide In chloroform at 20℃; for 1h; Stage #2: With acetic acid In chloroform at 20℃; for 6.5h; | 88% |
| With bromine In chloroform at 0℃; | 58% |
| With N-Bromosuccinimide In 1-methyl-pyrrolidin-2-one at 80℃; for 3h; Product distribution / selectivity; Inert atmosphere; | |
| With N-Bromosuccinimide In N,N-dimethyl-formamide at 0 - 20℃; for 3h; |
- 344782-48-5
N4,N4’-bis(4-bromophenyl)-N4,N4’-diphenyl-[1,1'-biphenyl]-4,4'-diamine
- 113664-24-7
N,N,N′,N′-tetrakis(4-bromophenyl)[1,1′-biphenyl]-4,4′-diamine
| Conditions | Yield |
|---|---|
| With tetra-N-butylammonium tribromide In chloroform at 25℃; for 0.5h; | 79% |
| With tetra-N-butylammonium tribromide In chloroform at 25℃; for 0.5h; | 79% |
- 92-86-4
4-(4-bromophenyl)bromobenzene
- 106-40-1
4-bromo-aniline
- 113664-24-7
N,N,N′,N′-tetrakis(4-bromophenyl)[1,1′-biphenyl]-4,4′-diamine
| Conditions | Yield |
|---|---|
| With succinic acid anhydride; sulfuric acid; copper; sodium hydrogensulfite In water at 200℃; for 20h; | 52.3% |
- 110-18-9
N,N,N,N,-tetramethylethylenediamine
- 4316-58-9
tri(p-bromophenyl)amine
- 113664-24-7
N,N,N′,N′-tetrakis(4-bromophenyl)[1,1′-biphenyl]-4,4′-diamine
| Conditions | Yield |
|---|---|
| Stage #1: N,N,N,N,-tetramethylethylenediamine; tri(p-bromophenyl)amine With n-butyllithium In diethyl ether; hexane at -78℃; for 1h; Stage #2: With copper dichloride at 20℃; for 10h; | 50% |
- 4316-58-9
tri(p-bromophenyl)amine
- 113664-24-7
N,N,N′,N′-tetrakis(4-bromophenyl)[1,1′-biphenyl]-4,4′-diamine
| Conditions | Yield |
|---|---|
| Stage #1: tri(p-bromophenyl)amine With n-butyllithium; N,N,N,N,-tetramethylethylenediamine In hexane at -78℃; for 1h; Schlenk technique; Stage #2: With copper dichloride at 20℃; for 10h; Schlenk technique; | 50% |
A
- 4316-58-9
tri(p-bromophenyl)amine
B
- 113664-24-7
N,N,N′,N′-tetrakis(4-bromophenyl)[1,1′-biphenyl]-4,4′-diamine
| Conditions | Yield |
|---|---|
| With tetra-(n-butyl)ammonium iodide In acetonitrile at 2 - 5℃; Product distribution; | A 46% B 25% |
- 106-37-6
1.4-dibromobenzene
- 113664-24-7
N,N,N′,N′-tetrakis(4-bromophenyl)[1,1′-biphenyl]-4,4′-diamine
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: 50 percent / tris(dibenzylideneacetone)dipalladium; bis(diphenylphosphino)ferrocene; t-BuONa / toluene / 12 h / 90 °C 2: 79 percent / tetrabutylammonium tribromide / CHCl3 / 0.5 h / 25 °C View Scheme |
- 531-91-9
N,N'-diphenyl-p-phenylenediamine
- 113664-24-7
N,N,N′,N′-tetrakis(4-bromophenyl)[1,1′-biphenyl]-4,4′-diamine
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: 50 percent / tris(dibenzylideneacetone)dipalladium; bis(diphenylphosphino)ferrocene; t-BuONa / toluene / 12 h / 90 °C 2: 79 percent / tetrabutylammonium tribromide / CHCl3 / 0.5 h / 25 °C View Scheme |
- 36809-26-4
4-N,N-diphenylamino-1-bromobenzene
- 201802-67-7
4-(diphenylamino)phenyl boronic acid
- 113664-24-7
N,N,N′,N′-tetrakis(4-bromophenyl)[1,1′-biphenyl]-4,4′-diamine
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: tetrakis(triphenylphosphine) palladium(0); sodium carbonate / tetrahydrofuran / Reflux 2: N-Bromosuccinimide / N,N-dimethyl-formamide / 3 h / 0 - 20 °C View Scheme |
