CAS No.122-40-7,Amylcinnamaldehyde Suppliers

Products Categories

Pharmaceutical (81)
Organic Chemicals (38)
Others (27)
Adhesive and Sealant (25)
Reagent (7)
Synthetic Flavours & Fragrances (6)
Materials (5)
Food Additives (4)
Plant Extract (2)
Basic Inorganic Chemicals (1)

Basic Information

Molecular Structure:
CAS No.:	122-40-7
Name:	Amylcinnamaldehyde
Article Data:	24

Formula:	C₁₄H₁₈O
Molecular Weight:	202.296
Synonyms:	Cinnamaldehyde,a-amyl- (4CI);Cinnamaldehyde, a-pentyl- (6CI,7CI,8CI);2-(Phenylmethylene)heptanal;2-Benzylideneheptanal;Amylcinnamic acid aldehyde;Amylcinnamic aldehyde;Flomine;Jasminal;Jasminaldehyde;Jasmine aldehyde;Pentylcinnamaldehyde;a-Amyl-b-phenylacrolein;a-Amylcinnamal;a-Amylcinnamaldehyde;a-Pentylcinnamaldehyde;Alpha-amyl cinnamaldehyde;
EINECS:	204-541-5
Density:	0.963 g/cm³
Melting Point:	80°C
Boiling Point:	288.499 °C at 760 mmHg
Flash Point:	131.139 °C
Solubility:	181.69mg/L at 25℃
Appearance:	clear to pale yellow liquid
Hazard Symbols:	Xi
Risk Codes:	36/37/38
Safety:	26-37/39
PSA:	17.07000
LogP:	3.84920

Synthetic route

: 111-71-7
heptanal

: 100-52-7
benzaldehyde

: 122-40-7
jasminaldehyde

Conditions

Conditions	Yield
With benzoic acid; L-proline In neat (no solvent) at 125℃; for 1h; Reagent/catalyst; Time; Aldol Condensation; Inert atmosphere;	97%
With amino-functionalized [Zr6O4(OH)4(O2C-C6H4-CO2)6], UiO-66(NH2) at 159.84℃; for 1h; cross-aldol condensation; chemoselective reaction;	90%
With potassium carbonate; N-benzyl-N,N,N-triethylammonium chloride In dichloromethane for 3h;	80%

: 111-71-7
heptanal

: 100-52-7
benzaldehyde

A: 3021-89-4
2-pentyl-2-nonenal

B: 122-40-7
jasminaldehyde

Conditions

Conditions	Yield
With chitosan/titanium dioxide microspheres In toluene at 80℃; for 4h; Inert atmosphere;
With chitosan at 160℃; for 8h; chemoselective reaction;
With aluminum oxide In toluene at 120℃; Inert atmosphere;

...Expand

: 111-71-7
heptanal

: 100-52-7
benzaldehyde

A: 73757-32-1
2-n-pentyl-2-nonenal

B: 122-40-7
jasminaldehyde

Conditions

Conditions	Yield
With cetyltrimethylammonim bromide; sodium hydroxide In water at 30℃; for 4h; Concentration;

...Expand

: 111-71-7
heptanal

: 100-52-7
benzaldehyde

A: 111-14-8
oenanthic acid

B: 122-40-7
jasminaldehyde

C: 65-85-0
benzoic acid

Conditions

Conditions	Yield
With sodium hydroxide In water at 30℃; for 72h;

...Expand

: 111-71-7
heptanal

: 100-52-7
benzaldehyde

A: 3021-89-4, 49562-91-6, 49562-92-7
(E)-2-n-pentyl-2-n-nonenal

B: 122-40-7
jasminaldehyde

Conditions

Conditions	Yield
With potassium hydroxide; Aliquat 336 at 118℃; for 0.0166667h; Irradiation;	A 18% B 82%
With calcined-hydrotalcite supported on hexagonal mesoporous silica at 150℃; Mechanism; Kinetics; Aldol condensation; Inert atmosphere;

...Expand

: 111-71-7
heptanal

: 100-52-7
benzaldehyde

steel: steel

: 122-40-7
jasminaldehyde

Conditions

Conditions	Yield
at 200℃;

...Expand

: 111-71-7
heptanal

: 100-52-7
benzaldehyde

A: 111-14-8
oenanthic acid

B: 122-40-7
jasminaldehyde

Conditions

Conditions	Yield
With 4-dimethylaminopyridine functionalized zirconium-benzene-1,4-dicarboxylate-metal organic framework for 1h; Catalytic behavior; Reagent/catalyst; Aldol Condensation;

...Expand

: 111-71-7
heptanal

: 100-52-7
benzaldehyde

A: 3021-89-4
2-pentyl-2-nonenal

B: 111-14-8
oenanthic acid

C: 122-40-7
jasminaldehyde

Conditions

Conditions	Yield
With diethylamine for 1h; Catalytic behavior; Reagent/catalyst; Aldol Condensation;

...Expand

: 111-71-7
heptanal

: 64-17-5
ethanol

: 100-52-7
benzaldehyde

diluted NaOH-solution: diluted NaOH-solution

: 122-40-7
jasminaldehyde

...Expand

: 122-40-7
jasminaldehyde

: 101-85-9
α-pentylcinnamyl alcohol

Conditions

Conditions	Yield
With formic acid; iron(II) tetrafluoroborate hexahydrate; tris(2-diphenylphosphinoethyl)phosphine In tetrahydrofuran at 60℃; for 2h; Schlenk technique; Inert atmosphere;	99%
With iron(II) fluoro{tris[2-(diphenylphosphino)phenyl]phospino}tetrafluoroborate; hydrogen; trifluoroacetic acid In isopropyl alcohol at 120℃; under 15001.5 Torr; Inert atmosphere; Autoclave; chemoselective reaction;	98%
With Cp*Ir(6,6'-dionato-2,2'-bipyridine)(H2O); isopropyl alcohol at 82℃; for 6h; Inert atmosphere; Schlenk technique; chemoselective reaction;	97%

Total:149 Page 1 of 4 1 2 3 4 Next>>

Post a RFQ

Cas No.:

Product Name:

Quantity:

Email:

Company name:

Valid Period:

Detailed Requirements:

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

What can I do for you?
Get Best Price

Get Best Price for 122-40-7

Consensus Reports

Reported in EPA TSCA Inventory.

Specification

The Amylcinnamaldehyde, with the CAS registry number 122-40-7, is also known as Heptanal, 2-(phenylmethylene)-. It belongs to the product categories of Pharmaceutical Intermediates; Aldehydes; C10 to C21; Carbonyl Compounds; A-B; Alphabetical Listings; Flavors and Fragrances. Its EINECS registry number is 204-541-5. This chemical's molecular formula is C₁₄H₁₈O and molecular weight is 202.29. What's more, its systematic name is called 2-Benzylideneheptanal. It is widely used in making various types of daily chemical flavor, allocation of jasmine, lily of the valley, lilac, etc.

Physical properties about Amylcinnamaldehyde are: (1)ACD/LogP: 4.357; (2)# of Rule of 5 Violations: 0; (3)ACD/LogD (pH 5.5): 4.36; (4)ACD/LogD (pH 7.4): 4.36; (5)ACD/BCF (pH 5.5): 1204.95; (6)ACD/BCF (pH 7.4): 1204.95; (7)ACD/KOC (pH 5.5): 5584.16; (8)ACD/KOC (pH 7.4): 5584.16; (9)#H bond acceptors: 1; (10)#H bond donors: 0; (11)#Freely Rotating Bonds: 6; (12)Polar Surface Area: 17.07 Å²; (13)Index of Refraction: 1.534; (14)Molar Refractivity: 65.336 cm³; (15)Molar Volume: 210.063 cm³; (16)Polarizability: 25.901×10^-24cm³; (17)Surface Tension: 35.909 dyne/cm; (18)Density: 0.963 g/cm³; (19)Flash Point: 131.139 °C; (20)Enthalpy of Vaporization: 52.774 kJ/mol; (21)Boiling Point: 288.499 °C at 760 mmHg; (22)Vapour Pressure: 0.002 mmHg at 25 °C.

Preparation of Amylcinnamaldehyde: this chemical can be prepared by benzaldehyde with heptanal. This reaction needs reagent K₂CO₃, catalyst benzyltriethylammonium chloride and solvent CH₂Cl₂. The reaction time is 3 hours. The yield is 80 %.

Amylcinnamaldehyde can be prepared by benzaldehyde with heptanal.

When you are dealing with this chemical, you should be very careful. This chemical may cause inflammation to the skin or other mucous membranes. And it is irritating to eyes, respiratory system and skin. Therefore, you should wear gloves and eye/face protection. In case of contacting with eyes, you should rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1) SMILES: O=CC(=Cc1ccccc1)CCCCC
(2) InChI: InChI=1S/C14H18O/c1-2-3-5-10-14(12-15)11-13-8-6-4-7-9-13/h4,6-9,11-12H,2-3,5,10H2,1H3
(3) InChIKey: HMKKIXGYKWDQSV-UHFFFAOYSA-N

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
rat	LD50	oral	3730mg/kg (3730mg/kg)	SENSE ORGANS AND SPECIAL SENSES: OTHER CHANGES: OLFACTION BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) SENSE ORGANS AND SPECIAL SENSES: OTHER: EYE	Food and Cosmetics Toxicology. Vol. 2, Pg. 327, 1964.