CAS No.129-44-2,1,5-Diaminoanthraquinone Suppliers,MSDS download

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Basic Information

Molecular Structure:
CAS No.:	129-44-2
Name:	1,5-Diaminoanthraquinone
Article Data:	38

Formula:	C14H10 N2 O2
Molecular Weight:	238.246
Synonyms:	Anthraquinone,1,5-diamino- (7CI,8CI); 1,5-Anthraquinonyldiamine;1,5-Diamino-9,10-anthraquinone; 1,5-Diaminoanthraquinone; NSC 507213; NSC63791; NSC 7213; Smoke Red F
EINECS:	204-947-2
Density:	1.456 g/cm³
Melting Point:	> 300 C
Boiling Point:
Flash Point:	287.6 ºC
Solubility:	Slightly soluble AUTOIGNITION
Appearance:	yellow powder
Hazard Symbols:
Risk Codes:	R36/37/38
Safety:	Moderately toxic by intraperitoneal route. Mutation data reported. An eye irritant. When heated to decomposition it emits toxic fumes of NO_x.
Transport Information:	25kgs
PSA:	86.18000
LogP:	2.78880

Synthetic route

: 85193-25-5
N,N-(anthraquinon-1,5-diyl)-bis(triphenylphosphazene)

: 129-44-2
1,5-diaminoanthraquinone

Conditions

Conditions	Yield
With sulfuric acid at 140℃; for 0.166667h;	69%

: 82-46-2
1,5-Dichloroanthraquinone

A: 129-44-2
1,5-diaminoanthraquinone

B: 117-11-3
1-amino-5-chloroanthracene-9,10-dione

Conditions

Conditions	Yield
In ammonia; water	A 54% B n/a
In ammonia; water	A 53% B n/a
In ammonia; water	A 51.8% B n/a
With ammonium hydroxide at 170℃;

: 20717-43-5
decahydro-2-methylquinoline

: 82-35-9
1.5-dinitroanthraquinone

A: 129-44-2
1,5-diaminoanthraquinone

B: 6937-75-3
1-amino-5-nitroanthraquinone

C: 60080-32-2
1,5-bis-hydroxyamino-anthraquinone

...Expand

: 82-35-9
1.5-dinitroanthraquinone

: 129-44-2
1,5-diaminoanthraquinone

Conditions

Conditions	Yield
With acid durch elektrolytische Reduktion;
With tin oxidepotash
With phenylhydrazine

: 82-35-9
1.5-dinitroanthraquinone

A: 129-44-2
1,5-diaminoanthraquinone

B: 6937-75-3
1-amino-5-nitroanthraquinone

Conditions

Conditions	Yield
With sodium disulfite at 120 - 180℃; unter Druck;

: 79285-23-7
1,5-bis-(toluene-4-sulfonylamino)-anthraquinone

: 129-44-2
1,5-diaminoanthraquinone

Conditions

Conditions	Yield
With sulfuric acid at 50 - 60℃;

: 853-35-0
sodium anthraquinone-1,5-disulphonate

: 129-44-2
1,5-diaminoanthraquinone

Conditions

Conditions	Yield
With 3-nitrobenzenesulfonic acid anion; ammonia at 175℃; unter Druck;
With ammonium hydroxide; barium(II) chloride at 180 - 186℃; im Autoklaven;
With 3-nitrobenzenesulfonic acid anion; ammonia at 175℃; unter Druck;

: 82-46-2
1,5-Dichloroanthraquinone

: 70-55-3
toluene-4-sulfonamide

: 129-44-2
1,5-diaminoanthraquinone

Conditions

Conditions	Yield
With copper diacetate; potassium carbonate; 1,2-dichloro-benzene weiteres Reagens: Kupfer(I)-chlorid; Behandeln des Reaktionsprodukts mit Schwefelsaeure;

: 82-46-2
1,5-Dichloroanthraquinone

: 129-44-2
1,5-diaminoanthraquinone

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: 65 percent / Heating 2: 10percent aq. HCl / tetrahydrofuran View Scheme
Multi-step reaction with 2 steps 1: potassium carbonate; copper acetate; nitrobenzene 2: concentrated sulfuric acid / 50 - 60 °C View Scheme
With pyridine; aluminium trichloride at 250℃; Erwaermen des erhaltenen 1.5-Dipyridinio-anthrachinon-dichlorids mit Piperidin und Wasser;
With pyridine; aluminium trichloride at 250℃; Erwaermen des erhaltenen 1.5-Dipyridinio-anthrachinon-dichlorids mit Piperidin und Wasser;

: 82-35-9
1.5-dinitroanthraquinone

: 100-63-0
phenylhydrazine

A: 129-44-2
1,5-diaminoanthraquinone

B: 60080-32-2
1,5-bis-hydroxyamino-anthraquinone

...Expand

Raw Materials

7664-41-7

60080-32-2

1780-19-4

82-46-2

853-35-0

93804-31-0

100-63-0

84-65-1

Downstream Products

3311-73-7

82-18-8

81-60-7

3278-82-8

100693-82-1

117-06-6

128-89-2

10262-79-0

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Chemistry

Chemical Name: 1,5-Diaminoanthraquinone
IUPAC NAME: 1,5-Diaminoanthracene-9,10-dione
CAS No.: 129-44-2
EINECS: 204-947-2
RTECS: CB6400000
Molecular Formula: C₁₄H₁₀N₂O ₂
Molecular Weight: 238.24 g/mol
Melting Point: >300 °C(lit.)
Density: 1.456 g/cm³
Flash Point: 287.6 °C
Boiling Point: 551.9 °C at 760 mmHg
Following is the structure of 1,5-Diaminoanthraquinone (CAS No.129-44-2):

Product Categories about 1,5-Diaminoanthraquinone (CAS No.129-44-2) are Intermediates of Dyes and Pigments ; Aminoanthraquinones ; Anthraquinones ; C13 to C14 ; Carbonyl Compounds ; Ketones
The chemical synonymous of 1,5-Diaminoanthraquinone (CAS No.129-44-2) are 1,5-Diamino-10-Anthracenedione ; 1,5-Diamino-9,10-Anthraquinone ; 1,5-Diaminoanthrachinon ; 1,5-Diamino-Anthraquinon ; 10-Anthracenedione,1,5-Diamino-9 ; 9,10-Anthracenedione,1,5-Diamino- ; Smokeredf ; 1,5-Diaminoanthraquinone

Uses

1,5-Diaminoanthraquinone (CAS No.129-44-2) is used as dye intermediates.

Toxicity Data With Reference

1.	eye-rbt 500 mg/24H MLD	28ZPAK Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,122.
2.	mma-sat 500 µg/plate	MUREAV Mutation Research. 40 (1976),203.
3.	ipr-rat LD50:1300 mg/kg	GTPZAB Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 21 (12)(1977),27.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Moderately toxic by intraperitoneal route. Mutation data reported. An eye irritant. When heated to decomposition it emits toxic fumes of NO_x.
Hazard Codes: Xi
Risk Statements about 1,5-Diaminoanthraquinone (CAS No.129-44-2):
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements about 1,5-Diaminoanthraquinone (CAS No.129-44-2):
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39:Wear suitable gloves and eye/face protection.