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| CAS No.: | 129-44-2 | |
|---|---|---|
| Name: | 1,5-Diaminoanthraquinone | |
| Molecular Structure: | ||
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| Formula: | C14H10 N2 O2 | |
| Molecular Weight: | 238.246 | |
| Synonyms: | Anthraquinone,1,5-diamino- (7CI,8CI); 1,5-Anthraquinonyldiamine;1,5-Diamino-9,10-anthraquinone; 1,5-Diaminoanthraquinone; NSC 507213; NSC63791; NSC 7213; Smoke Red F | |
| EINECS: | 204-947-2 | |
| Density: | 1.456 g/cm3 | |
| Melting Point: | > 300 C | |
| Boiling Point: | ||
| Flash Point: | 287.6 ºC | |
| Solubility: | Slightly soluble AUTOIGNITION | |
| Appearance: | yellow powder | |
| Hazard Symbols: |
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| Risk Codes: | R36/37/38 | |
| Safety: | Moderately toxic by intraperitoneal route. Mutation data reported. An eye irritant. When heated to decomposition it emits toxic fumes of NOx. | |
| Transport Information: | 25kgs | |
| PSA: | 86.18000 | |
| LogP: | 2.78880 | |
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N,N-(anthraquinon-1,5-diyl)-bis(triphenylphosphazene)
- 129-44-2
1,5-diaminoanthraquinone
| Conditions | Yield |
|---|---|
| With sulfuric acid at 140℃; for 0.166667h; | 69% |
- 82-46-2
1,5-Dichloroanthraquinone
A
- 129-44-2
1,5-diaminoanthraquinone
B
- 117-11-3
1-amino-5-chloroanthracene-9,10-dione
| Conditions | Yield |
|---|---|
| In ammonia; water | A 54% B n/a |
| In ammonia; water | A 53% B n/a |
| In ammonia; water | A 51.8% B n/a |
| With ammonium hydroxide at 170℃; |
- 20717-43-5
decahydro-2-methylquinoline
- 82-35-9
1.5-dinitroanthraquinone
A
- 129-44-2
1,5-diaminoanthraquinone
B
- 6937-75-3
1-amino-5-nitroanthraquinone
C
- 60080-32-2
1,5-bis-hydroxyamino-anthraquinone
| Conditions | Yield |
|---|---|
| With acid durch elektrolytische Reduktion; | |
| With tin oxidepotash | |
| With phenylhydrazine |
- 82-35-9
1.5-dinitroanthraquinone
A
- 129-44-2
1,5-diaminoanthraquinone
B
- 6937-75-3
1-amino-5-nitroanthraquinone
| Conditions | Yield |
|---|---|
| With sodium disulfite at 120 - 180℃; unter Druck; |
- 79285-23-7
1,5-bis-(toluene-4-sulfonylamino)-anthraquinone
- 129-44-2
1,5-diaminoanthraquinone
| Conditions | Yield |
|---|---|
| With sulfuric acid at 50 - 60℃; |
| Conditions | Yield |
|---|---|
| With 3-nitrobenzenesulfonic acid anion; ammonia at 175℃; unter Druck; | |
| With ammonium hydroxide; barium(II) chloride at 180 - 186℃; im Autoklaven; | |
| With 3-nitrobenzenesulfonic acid anion; ammonia at 175℃; unter Druck; |
| Conditions | Yield |
|---|---|
| With copper diacetate; potassium carbonate; 1,2-dichloro-benzene weiteres Reagens: Kupfer(I)-chlorid; Behandeln des Reaktionsprodukts mit Schwefelsaeure; |
| Conditions | Yield |
|---|---|
| Multi-step reaction with 2 steps 1: 65 percent / Heating 2: 10percent aq. HCl / tetrahydrofuran View Scheme | |
| Multi-step reaction with 2 steps 1: potassium carbonate; copper acetate; nitrobenzene 2: concentrated sulfuric acid / 50 - 60 °C View Scheme | |
| With pyridine; aluminium trichloride at 250℃; Erwaermen des erhaltenen 1.5-Dipyridinio-anthrachinon-dichlorids mit Piperidin und Wasser; | |
| With pyridine; aluminium trichloride at 250℃; Erwaermen des erhaltenen 1.5-Dipyridinio-anthrachinon-dichlorids mit Piperidin und Wasser; |
- 82-35-9
1.5-dinitroanthraquinone
- 100-63-0
phenylhydrazine
A
- 129-44-2
1,5-diaminoanthraquinone
B
- 60080-32-2
1,5-bis-hydroxyamino-anthraquinone
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Chemistry
Chemical Name: 1,5-Diaminoanthraquinone
IUPAC NAME: 1,5-Diaminoanthracene-9,10-dione
CAS No.: 129-44-2
EINECS: 204-947-2
RTECS: CB6400000
Molecular Formula: C14H10N2O2
Molecular Weight: 238.24 g/mol
Melting Point: >300 °C(lit.)
Density: 1.456 g/cm3
Flash Point: 287.6 °C
Boiling Point: 551.9 °C at 760 mmHg
Following is the structure of 1,5-Diaminoanthraquinone (CAS No.129-44-2):
Product Categories about 1,5-Diaminoanthraquinone (CAS No.129-44-2) are Intermediates of Dyes and Pigments ; Aminoanthraquinones ; Anthraquinones ; C13 to C14 ; Carbonyl Compounds ; Ketones
The chemical synonymous of 1,5-Diaminoanthraquinone (CAS No.129-44-2) are 1,5-Diamino-10-Anthracenedione ; 1,5-Diamino-9,10-Anthraquinone ; 1,5-Diaminoanthrachinon ; 1,5-Diamino-Anthraquinon ; 10-Anthracenedione,1,5-Diamino-9 ; 9,10-Anthracenedione,1,5-Diamino- ; Smokeredf ; 1,5-Diaminoanthraquinone
Uses
1,5-Diaminoanthraquinone (CAS No.129-44-2) is used as dye intermediates.
Toxicity Data With Reference
| 1. | eye-rbt 500 mg/24H MLD | 28ZPAK Sbornik Vysledku Toxixologickeho Vysetreni Latek A Pripravku Marhold, J.V.,Institut Pro Vychovu Vedoucicn Pracovniku Chemickeho Prumyclu Praha,Czechoslovakia.: 1972,122. | ||
| 2. | mma-sat 500 µg/plate | MUREAV Mutation Research. 40 (1976),203. | ||
| 3. | ipr-rat LD50:1300 mg/kg | GTPZAB Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 21 (12)(1977),27. |
Consensus Reports
Reported in EPA TSCA Inventory.
Safety Profile
Moderately toxic by intraperitoneal route. Mutation data reported. An eye irritant. When heated to decomposition it emits toxic fumes of NOx.
Hazard Codes: 
Xi
Risk Statements about 1,5-Diaminoanthraquinone (CAS No.129-44-2):
R36/37/38:Irritating to eyes, respiratory system and skin.
Safety Statements about 1,5-Diaminoanthraquinone (CAS No.129-44-2):
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39:Wear suitable gloves and eye/face protection.