CAS No.13080-86-9,4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline Suppliers

Products Categories

Pharmaceutical (75)
Organic Chemicals (43)
Others (23)
Materials (12)
Reagent (5)
Basic Inorganic Chemicals (2)
Dyestuff and Pigment (1)
Catalyst and Auxiliary (1)

Basic Information

Molecular Structure:
CAS No.:	13080-86-9
Name:	4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline
Article Data:	12

Formula:	C₂₇H₂₆N₂O₂
Molecular Weight:	410.516
Synonyms:	2,2-Bis[p-(4-aminophenoxy)phenyl]propane;4,4'-[Isopropylidenebis(1,4-phenylene)dioxy]dianiline;BAPP;Bisphenol Abis(4-aminophenyl) ether;2,2-Bis[4-(4-aminophenoxy)phenyl]propane;Aniline,4,4'-[isopropylidenebis(p-phenyleneoxy)]di- (7CI,8CI);
EINECS:	235-985-8
Density:	1.178 g/cm³
Melting Point:	127-130 °C
Boiling Point:	587.1 °C at 760 mmHg
Flash Point:	322.8 °C
Solubility:	Very slightly soluble in water. Soluble in acetone, Dimethyl sulfoxide(DMSO).
Hazard Symbols:	Xi,Xn
Risk Codes:	22-36/37/38
Safety:	26-36
PSA:	70.50000
LogP:	7.92390

Synthetic route

: 20653-11-6
2,2-bis(4-(4-nitrophenoxy)phenyl)propane

: 13080-86-9
2,2-bis-{4-(4-aminophenoxy)phenyl}propane

Conditions

Conditions	Yield
With Ni-B/C; hydrazine hydrate In ethanol at 45 - 75℃; for 2h; Reagent/catalyst;	98.2%
With palladium on activated charcoal; hydrogen In ethyl acetate at 20℃; under 2844.39 Torr; for 24h;	95%
With palladium on activated charcoal; hydrogen In ethyl acetate at 20℃; under 2844.39 Torr; for 24h;	95%

: 20653-11-6
2,2-bis(4-(4-nitrophenoxy)phenyl)propane

: 7803-57-8
hydrazine hydrate

: 13080-86-9
2,2-bis-{4-(4-aminophenoxy)phenyl}propane

Conditions

Conditions	Yield
Stage #1: 2,2-bis[4-(4-nitrophenoxy)phenyl]propane With palladium 10% on activated carbon In ethanol at 50℃; Reflux; Stage #2: hydrazine hydrate In ethanol at 80 - 90℃; for 3h;	85%

: 80-05-7
BPA

: 13080-86-9
2,2-bis-{4-(4-aminophenoxy)phenyl}propane

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: Na2CO3 2: Zn, AcOH View Scheme
Multi-step reaction with 2 steps 1: potassium carbonate; N,N-dimethyl-formamide / 12 h / Reflux 2: palladium 10% on activated carbon; hydrazine / ethanol; water / 12.5 h / 85 °C / Reflux View Scheme
Multi-step reaction with 2 steps 1: potassium carbonate / N,N-dimethyl-formamide / 24 h / 20 °C 2: palladium on activated charcoal; hydrogen / ethyl acetate / 24 h / 20 °C / 2844.39 Torr View Scheme
Multi-step reaction with 2 steps 1.1: potassium carbonate / N,N-dimethyl-formamide / 48 h / 130 °C / Inert atmosphere 2.1: palladium 10% on activated carbon / ethanol / 2 h / 80 - 90 °C / Inert atmosphere 2.2: 48 h / Reflux View Scheme
Multi-step reaction with 2 steps 1: potassium carbonate / N,N-dimethyl-formamide / 24 h / 20 °C / Inert atmosphere 2: palladium on activated charcoal; hydrogen / ethyl acetate / 24 h / 20 °C / 2844.39 Torr View Scheme

: 100-00-5
4-chlorobenzonitrile

: 13080-86-9
2,2-bis-{4-(4-aminophenoxy)phenyl}propane

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: Na2CO3 2: Zn, AcOH View Scheme
Multi-step reaction with 2 steps 1.1: potassium carbonate / N,N-dimethyl-formamide / 48 h / 130 °C / Inert atmosphere 2.1: palladium 10% on activated carbon / ethanol / 2 h / 80 - 90 °C / Inert atmosphere 2.2: 48 h / Reflux View Scheme

: 350-46-9
4-Fluoronitrobenzene

: 13080-86-9
2,2-bis-{4-(4-aminophenoxy)phenyl}propane

Conditions

Conditions	Yield
Multi-step reaction with 2 steps 1: potassium carbonate / N,N-dimethyl-formamide / 24 h / 20 °C 2: palladium on activated charcoal; hydrogen / ethyl acetate / 24 h / 20 °C / 2844.39 Torr View Scheme
Multi-step reaction with 2 steps 1: potassium carbonate / N,N-dimethyl-formamide / 24 h / 20 °C / Inert atmosphere 2: palladium on activated charcoal; hydrogen / ethyl acetate / 24 h / 20 °C / 2844.39 Torr View Scheme

di-tert-butyl dicarbonate: di-tert-butyl dicarbonate

: 13080-86-9
2,2-bis-{4-(4-aminophenoxy)phenyl}propane

: 2,2'-bis{4-[4-(t-butoxycarbonylamino)phenoxy]phenyl}propane

Conditions

Conditions	Yield
With triethylamine In tetrahydrofuran at 25 - 45℃; for 6.5h; Inert atmosphere;	99%

: 796974-65-7
1,3-bis(4-bromobenzoyl)-5-tert-butylbenzene

: 13080-86-9
2,2-bis-{4-(4-aminophenoxy)phenyl}propane

polymer, Mn 7000, Mw 11000 by GPC; monomer(s): 1,3-bis(4-bromobenzoyl-5-tert-butyl)benzene; 2,2-bis[4-(4-aminophenoxy)phenyl]propane: polymer, Mn 7000, Mw 11000 by GPC; monomer(s): 1,3-bis(4-bromobenzoyl-5-tert-butyl)benzene; 2,2-bis[4-(4-aminophenoxy)phenyl]propane

Conditions

Conditions	Yield
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; lithium chloride; sodium t-butanolate; tris(dibenzylideneacetone)dipalladium (0) In various solvent(s) at 165℃; Hartwig-Buchwald reaction;	98%

: 796974-65-7
1,3-bis(4-bromobenzoyl)-5-tert-butylbenzene

: 13080-86-9
2,2-bis-{4-(4-aminophenoxy)phenyl}propane

polymer, Mn 10000, Mw 42000 by GPC; monomer(s): 1,3-bis(4-bromobenzoyl-5-tert-butyl)benzene; 2,2-bis[4-(4-aminophenoxy)phenyl]propane: polymer, Mn 10000, Mw 42000 by GPC; monomer(s): 1,3-bis(4-bromobenzoyl-5-tert-butyl)benzene; 2,2-bis[4-(4-aminophenoxy)phenyl]propane

Conditions

Conditions	Yield
With 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; lithium chloride; sodium t-butanolate; tris(dibenzylideneacetone)dipalladium (0) In various solvent(s) at 100 - 165℃; Hartwig-Buchwald reaction;	96%

: 13080-86-9
2,2-bis-{4-(4-aminophenoxy)phenyl}propane

: 90-02-8
salicylaldehyde

: 35948-25-5
9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide

: 1166187-87-6
P-BAPP-HB

Conditions

Conditions	Yield
In N,N-dimethyl-formamide at 20℃; for 12h;	95%

...Expand

: 13080-86-9
2,2-bis-{4-(4-aminophenoxy)phenyl}propane

: 708-06-5
2-hydroxynaphthalene-1-carbaldehyde

: 1236010-44-8
1,1'-{(propane-2,2-diyl)bis[(1,4-phenylene)oxy(1,4-phenylene)iminomethyl]}bis(2-naphthol)

Conditions

Conditions	Yield
With formic acid In methanol; dichloromethane Reflux;	95%

Raw Materials

350-46-9

20653-11-6

80-05-7

100-00-5

Total:115 Page 1 of 4 1 2 3 4 Next>>

Post a RFQ

Cas No.:

Product Name:

Quantity:

Email:

Company name:

Valid Period:

Detailed Requirements:

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

What can I do for you?
Get Best Price

Get Best Price for 13080-86-9

Specification

The IUPAC name of 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline is 4-[4-[2-[4-(4-aminophenoxy)phenyl]propan-2-yl]phenoxy]aniline. With the CAS registry number 13080-86-9, it is also named as 2,2'-Bis(4-aminophenoxyphenyl)propane. The product's categories are Organics; Miscellaneous; Bisphenol A type Compounds (for High-Performance Polymer Research); Functional Materials; Reagent for High-Performance Polymer Research, and the other registry number is 158066-25-2. In addition, its molecular formula is C₂₇H₂₆N₂O₂ and molecular weight is 410.51.

The other characteristics of this product can be summarized as: (1)EINECS: 235-985-8; (2)ACD/LogP: 5.19; (3)# of Rule of 5 Violations: 1; (4)ACD/LogD (pH 5.5): 5.01; (5)ACD/LogD (pH 7.4): 5.18; (6)ACD/BCF (pH 5.5): 3422.21; (7)ACD/BCF (pH 7.4): 5127.43; (8)ACD/KOC (pH 5.5): 10491.47; (9)ACD/KOC (pH 7.4): 15719.17; (10)#H bond acceptors: 4; (11)#H bond donors: 4; (12)#Freely Rotating Bonds: 8; (13)Index of Refraction: 1.641; (14)Molar Refractivity: 125.76 cm³; (15)Molar Volume: 348.4 cm³; (16)Surface Tension: 49.3 dyne/cm; (17)Density: 1.178 g/cm³; (18)Flash Point: 322.8 °C; (19)Melting Point: 127-130 °C; (20)Enthalpy of Vaporization: 87.67 kJ/mol; (21)Boiling Point: 587.1 °C at 760 mmHg; (22)Vapour Pressure: 9.1E-14 mmHg at 25 °C.

Uses of 4,4'-(4,4'-Isopropylidenediphenyl-1,1'-diyldioxy)dianiline: it can react with benzene-1,4-dicarbaldehyde to get C₇₀H₅₆N₄O₄.

This reaction needs chlorobenzene at temperature of 20 °C for 18 hours. The yield is 90 %.

When you are using this chemical, please be cautious about it as the following: it is irritating to eyes, respiratory system and skin. It is also harmful if swallowed. In case of contact with eyes, please rinse immediately with plenty of water and seek medical advice. And you should wear suitable protective clothing.

People can use the following data to convert to the molecule structure.
(1)SMILES: O(c1ccc(cc1)C(c3ccc(Oc2ccc(N)cc2)cc3)(C)C)c4ccc(cc4)N
(2)InChI: InChI=1/C27H26N2O2/c1-27(2,19-3-11-23(12-4-19)30-25-15-7-21(28)8-16-25)20-5-13-24(14-6-20)31-26-17-9-22(29)10-18-26/h3-18H,28-29H2,1-2H3
(3)InChIKey: KMKWGXGSGPYISJ-UHFFFAOYAK

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
rabbit	LD	skin	> 8gm/kg (8000mg/kg)	LUNGS, THORAX, OR RESPIRATION: OTHER CHANGES SKIN AND APPENDAGES (SKIN): "DERMATITIS, OTHER: AFTER SYSTEMIC EXPOSURE"	National Technical Information Service. Vol. OTS0533991,
rat	LD50	oral	308mg/kg (308mg/kg)	BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) BEHAVIORAL: TREMOR SKIN AND APPENDAGES (SKIN): HAIR: OTHER	National Technical Information Service. Vol. OTS0533991,