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| CAS No.: | 148-18-5 |
|---|---|
| Name: | Sodium diethyldithiocarbamate |
| Molecular Structure: | |
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|
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| Formula: | C5H10NNaS2 |
| Molecular Weight: | 171.263 |
| Synonyms: | Sodium N,N-diethyldithiocarbamate;Carbamic acid, diethyldithio-, sodium salt;DEDC;Soxinol ESL;Diethyldithiocarbamic acid, sodium;Usaf ek-2596;DEDK;Ditiocarb sodium;Diethyldithiocarbamic acid, sodium salt;Thiocarb;GS 694A;NCI-C02835;DTC;DDC; |
| EINECS: | 205-710-6 |
| Density: | 1.086 g/cm3 |
| Melting Point: | 95 °C |
| Boiling Point: | 176.4 °C at 760 mmHg |
| Flash Point: | 60.5 °C |
| Solubility: | water: >=10 g/100 mL at 14 °C |
| Appearance: | Odorless white or slightly brown or slightly pink crystals |
| PSA: | 60.63000 |
| LogP: | 1.81060 |
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| Conditions | Yield |
|---|---|
| With sodium hydroxide In ethanol; water cooling; | 90% |
| With sodium hydroxide In ethanol at 20 - 40℃; | 73% |
| With sodium hydroxide In water at 20℃; for 1h; Cooling with ice; | 69% |
- 97-77-8
disulfiram
- 140-90-9
sodium O-ethyl dithiocarbonate
A
- 148-18-5
sodium N,N-diethyldithiocarbamate
B
- 327989-09-3
C8H15NOS4
| Conditions | Yield |
|---|---|
| With sodium nitrate; C8MoN8(3-)*3Na(1+) In water; acetone at 25℃; Rate constant; Equilibrium constant; μ 0.2 mol/l; |
- 97-77-8
disulfiram
- 4092-82-4
sodium N,N'-diisopropyldithiocarbamate
A
- 148-18-5
sodium N,N-diethyldithiocarbamate
| Conditions | Yield |
|---|---|
| With sodium nitrate; potassium hexacyanoferrate(III) In water; acetone at 25℃; Equilibrium constant; μ 0.2 mol/l; |
- 140-90-9
sodium O-ethyl dithiocarbonate
- 327989-09-3
C8H15NOS4
A
- 502-55-6
bis-ethoxythiocarbonyldisulfane
B
- 148-18-5
sodium N,N-diethyldithiocarbamate
| Conditions | Yield |
|---|---|
| With sodium nitrate; C8MoN8(3-)*3Na(1+) In water; acetone at 25℃; Rate constant; Equilibrium constant; μ 0.2 mol/l; |
- 4092-82-4
sodium N,N'-diisopropyldithiocarbamate
A
- 4136-91-8
tetraisopropylothiuram disulphide
B
- 148-18-5
sodium N,N-diethyldithiocarbamate
| Conditions | Yield |
|---|---|
| With sodium nitrate; potassium hexacyanoferrate(III) In water; acetone at 25℃; Equilibrium constant; μ 0.2 mol/l; |
- 138523-63-4
Tributyltin diethyldithiocarbamate
- 148-18-5
sodium N,N-diethyldithiocarbamate
| Conditions | Yield |
|---|---|
| With sodium hydrogensulfide In methanol at 4℃; |
- 80-05-7
BPA
- 112-34-5
Diethylene glycol monobutyl ether
- 120-32-1
chlorophene
- 148-18-5
sodium N,N-diethyldithiocarbamate
| Conditions | Yield |
|---|---|
| Stage #1: sodium N,N-diethyldithiocarbamate; 5'-I-d(TTT)-CPG resin In N,N-dimethyl-formamide at 20℃; for 0.0333333h; Stage #2: With ammonium hydroxide at 60℃; for 17h; | 100% |
- 148-18-5
sodium N,N-diethyldithiocarbamate
| Conditions | Yield |
|---|---|
| In methanol; dichloromethane at 20℃; for 1h; | 100% |
| Conditions | Yield |
|---|---|
| In acetone for 1h; Reflux; | 99% |
| In acetonitrile at 25℃; for 1h; | 63% |
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Chemistry
IUPAC Name: sodium N,N-diethylcarbamodithioate
Following is the structure of Sodium diethyldithiocarbamate (CAS NO.148-18-5):
Molecular formula: C5H10NNaS2
Molecular Weight: 171.26
EINECS: 205-710-6
Melting point: 95°C
Flash Point: 60.5 °C
Index of Refraction: 1.555
Molar Refractivity: 44.12 cm3
Molar Volume: 137.3 cm3
Density: 1.086 g/cm3
Surface Tension: 44.6 dyne/cm
Boiling Point: 176.4 °C at 760 mmHg
Enthalpy of Vaporization: 41.27 kJ/mol
Vapour Pressure: 1.1 mmHg at 25 °C
Water Solubility of Sodium diethyldithiocarbamate (CAS NO.148-18-5): >=10 g/100 mL at 14 °C
Product Categories of Sodium diethyldithiocarbamate (CAS NO.148-18-5): Pharmaceutical Intermediates; Aliphatics
Canonical SMILES: CCN(CC)C(=S)[S-].[Na+]
InChI: InChI=1S/C5H11NS2.Na/c1-3-6(4-2)5(7)8;/h3-4H2,1-2H3,(H,7,8);/q;+1/p-1
InChIKey: IOEJYZSZYUROLN-UHFFFAOYSA-M
Uses
Sodium diethyldithiocarbamate (CAS NO.148-18-5) can be used as a pesticide.
Toxicity Data With Reference
| 1. | oms-omi 100 µmol/L | BBACAQ Biochimica et Biophysica Acta. 519 (1978),65. | ||
| 2. | dnd-hmn:hla 100 µmol/L | BBACAQ Biochimica et Biophysica Acta. 519 (1978),65. | ||
| 3. | cyt-rat-orl 5200 mg/kg | MUREAV Mutation Research. 53 (1978),212. | ||
| 4. | dni-ckn:emb 4 µmol/L | BBACAQ Biochimica et Biophysica Acta. 519 (1978),65. | ||
| 5. | oms-ckn:emb 40 µmol/L | BBACAQ Biochimica et Biophysica Acta. 519 (1978),65. | ||
| 6. | orl-rat LD50:1500 mg/kg | DRFUD4 Drugs of the Future. 6 (1981),225. | ||
| 7. | ipr-rat LD50:1250 mg/kg | DRFUD4 Drugs of the Future. 6 (1981),225. | ||
| 8. | orl-mus LD50:1500 mg/kg | DRFUD4 Drugs of the Future. 6 (1981),225. | ||
| 9. | ipr-mus LD50:1302 mg/kg | DRFUD4 Drugs of the Future. 6 (1981),225. | ||
| 10. | scu-rbt LD50:500 mg/kg | APTOA6 Acta Pharmacologica et Toxicologica. 8 (1952),329. |
Consensus Reports
IARC Cancer Review: Group 3 IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 7 ,1987,p. 56.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) ; Animal Inadequate Evidence IMEMDT IARC Monographs on the Evaluation of Carcinogenic Risk of Chemicals to Man . 12 ,1976,p. 217.(World Health Organization, Internation Agency for Research on Cancer,Lyon, France.: ) (Single copies can be ordered from WHO Publications Centre U.S.A., 49 Sheridan Avenue, Albany, NY 12210) . NCI Carcinogenesis Bioassay (feed); No Evidence: mouse, rat NCITR* National Cancer Institute Carcinogenesis Technical Report Series. (Bethesda, MD 20014) No. NCI-CG-TR-172 ,1979. . Reported in EPA TSCA Inventory.
Safety Profile
Moderately is toxic by ingestion, intraperitoneal, and subcutaneous routes. Experimental reproductive effects. Questionable carcinogen with experimental neoplastigenic and teratogenic data. Human mutation data reported. When heated to decomposition it emits very toxic fumes of NOx, SOx, and Na2O. See also CARBAMATES.
Standards and Recommendations
DFG MAK: 2 mg/m3
Specification
Sodium diethyldithiocarbamate , its cas register number is 148-18-5. It also can be called Diethyldithiocarbamic acid sodium salt ; N,N-Diethyldithiocarbamic acid, sodium salt ; and Sodium N,N-diethyldithiocarbamate . Its classification code are Agricultural Chemical; Antidote for nickel and cadmium poisoning; Fungicide, bactericide, wood preservative; Mutation data ; Reproductive Effect and Tumor data.