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| CAS No.: | 150-86-7 |
|---|---|
| Name: | PHYTOL |
| Molecular Structure: | |
|
|
|
| Formula: | C20H40O |
| Molecular Weight: | 296.537 |
| Synonyms: | 2-Hexadecen-1-ol,3,7,11,15-tetramethyl-, [R-[R*,R*-(E)]]-;Phytol (6CI,8CI);(7R,11R,2E)-Phytol;(E)-Phytol;(E,R,R)-Phytol;trans-Phytol; |
| EINECS: | 205-776-6 |
| Density: | 0.845 g/cm3 |
| Melting Point: | <25 °C |
| Boiling Point: | 335.5 °C at 760 mmHg |
| Flash Point: | 157.5 °C |
| Hazard Symbols: |
 Xi
|
| Risk Codes: | 36/37/38 |
| Safety: | 37/39-26 |
| PSA: | 20.23000 |
| LogP: | 6.36410 |
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- 7437-61-8
2-methyl-3,4-epoxy-1-butene
- 130627-55-3
(3R,7R)-3,7,11-Trimethyldodecylmagnesium-bromid
- 150-86-7
phytol
| Conditions | Yield |
|---|---|
| With copper(l) iodide In tetrahydrofuran at -20 - 0℃; for 24h; | 95% |
- 66432-63-1
(2E,7R,11R)-Phytyl-(2'-tetrahydropyranyl)aether
- 150-86-7
phytol
| Conditions | Yield |
|---|---|
| With pyridinium p-toluenesulfonate In ethanol at 55℃; for 1.5h; | 94% |
- 92116-50-2
(E)-(7R,11R)-1-(1'-ethoxy)ethoxy-3,7,11,15-tetramethyl-2-hexadecene
- 150-86-7
phytol
| Conditions | Yield |
|---|---|
| With hydrogenchloride; ammonium chloride In tetrahydrofuran at 0 - 20℃; for 3h; | 68% |
- 679841-68-0
2',4'-dimethylpent-3'-yl (7R,11R)-3,7,11,15-tetramethyl-5-methanesulfonyloxyhexadec-2-enoate
- 150-86-7
phytol
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride In diethyl ether Heating; | 67% |
- 13853-16-2
(2E,7R,11R)-3,7,11,15-tetramethyl-hexadec-2-enoic acid methyl ester
- 150-86-7
phytol
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride; diethyl ether | |
| With lithium aluminium tetrahydride In diethyl ether at 0℃; |
- 101541-51-9
(2Z,7R,11R)-3,7,11,15-tetramethyl-hexadec-2-enoic acid ethyl ester
- 150-86-7
phytol
| Conditions | Yield |
|---|---|
| With lithium aluminium tetrahydride; aluminium trichloride |
- 150-86-7
phytol
| Conditions | Yield |
|---|---|
| With lithium hydroxide | |
| With tetramethyl ammoniumhydroxide |
- 50-00-0
formaldehyd
- 75-24-1
trimethylaluminum
- 179991-80-1
6,10,14-Trimethyl-pentadec-1-yne
B
- 150-86-7
phytol
| Conditions | Yield |
|---|---|
| Stage #1: trimethylaluminum; 6,10,14-Trimethyl-pentadec-1-yne With zirconocene dichloride In 1,2-dichloro-ethane Stage #2: With n-butyllithium In tetrahydrofuran Stage #3: formaldehyd In tetrahydrofuran Further stages.; |
- 105470-79-9
(3R,7R,5E)-3,7,11-trimethyldodecan-1-al
- 150-86-7
phytol
| Conditions | Yield |
|---|---|
| Multi-step reaction with 3 steps 1: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C 2: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C 3: 67 percent / LiAlH4 / diethyl ether / Heating View Scheme |
| Conditions | Yield |
|---|---|
| Multi-step reaction with 5 steps 1.1: 81 percent / DMAP; DCC / CH2Cl2 / 3 h / 20 °C 2.1: (i-Pr)2NLi / hexane; tetrahydrofuran / 1 h / -78 °C 2.2: 99 percent / hexane; tetrahydrofuran / 1 h / -78 - 20 °C 3.1: 67 percent / TiCl4 / CH2Cl2 / 1 h / -78 °C 4.1: 74 percent / Et3N / CH2Cl2 / 1 h / 0 °C 5.1: 67 percent / LiAlH4 / diethyl ether / Heating View Scheme |
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Chemistry
Phytol is a precursor for vitamins E and K1. It is an extremely common terpenoid, found in all plants esterified to Chlorophyll to confer lipid solubility.It has some synonyms like E)-3,7,11,15-Tetramethyl-2-hexadedcen-1-ol;(E)-phytol;2,6,10,14-Tetramethylhexadec-14-en-16-ol;2-Hexadecen-1-ol, 3,7,11,15-tetramethyl-, [R-[R*,R*-(E)]]-;3,7,11,15-tetramethyl-,(r-(r*,r*-(e)))-2-hexadecen-1-o;3,7,11,15-tetramethyl-,[R-(R*,R*-(E))]-2-Hexadedcen-1-ol,and so on.
Molecular Formula: C20H40O
Molecular Weight: 296.53
EINECS: 205-776-6
boiling point: 202-204 °C (10 mmHg)
Density: 0.85
Refractive index: 1.461-1.469
Merck: 7390
Uses
Toxicity Data With Reference
| 1. | skn-rbt 500 mg/24H MOD | FCTOD7 Food and Chemical Toxicology. 20 (1982),811. | ||
| 2. | orl-rat LD50:>5 g/kg | FCTOD7 Food and Chemical Toxicology. 20 (1982),811. | ||
| 3. | skn-rbt LD50:>5 g/kg | FCTOD7 Food and Chemical Toxicology. 20 (1982),811. |
RTECS: TJ3490000
Consensus Reports
Safety Profile
Low toxicity by ingestion and skin contact. A skin irritant. When heated to decomposition it emits acrid smoke and irritating fumes.
Hazard Codes: Xi
Risk Statements: 36/37/38
Safety Statements: 37/39-26