CAS No.15972-60-8,Alachlor Suppliers

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Basic Information

Molecular Structure:
CAS No.:	15972-60-8
Name:	Alachlor
Article Data:	21

Formula:	C₁₄H₂₀ClNO₂
Molecular Weight:	269.771
Synonyms:	Chimiclor;2-Chloro-N-(2,6-diethyl)phenyl-N-methoxymethylacetamide;Alanox;Lasagrin;Alapaz;2-Chloro-2,6-diethyl-N-(methoxymethyl)acetanilide;Alochlor;Alanex;LAZO;Alachlore [ISO-French];Lasso micro-tech;Micro-Tech;Alatox 480;
EINECS:	240-110-8
Density:	1.119 g/cm³
Melting Point:	39-42 °C
Boiling Point:	404 °C at 760 mmHg
Flash Point:	198.1 °C
Solubility:	water: 0.024 g/100 mL
Appearance:	yellowish crystal
Hazard Symbols:	Xn,N
Risk Codes:	22-40-43-50/53-67-65-38-11-52/53-39-23/24/25-51/53
Safety:	36/37-46-60-61-62-45
Transport Information:	UN 3077
PSA:	29.54000
LogP:	2.98710

Synthetic route

: 39180-88-6
2,6-diethyl-N-(methoxymethyl)aniline

: 79-04-9
chloroacetyl chloride

: 15972-60-8
Alachlor

Conditions

Conditions	Yield
In toluene for 20h; Reflux; Green chemistry; Industrial scale;	93%

: 6967-29-9
2-chloro-2',6'-diethylacetanilide

: 107-30-2
chloromethyl methyl ether

: 15972-60-8
Alachlor

Conditions

Conditions	Yield
With sodium hydroxide; PEG-400 In benzene at 15℃; for 2h; Yield given;

: 50-00-0
formaldehyd

: 579-66-8
2,6-diethylaniline

: 79-11-8
chloroacetic acid

: 149-73-5
trimethyl orthoformate

: 15972-60-8
Alachlor

Conditions

Conditions	Yield
With thionyl chloride; sodium sulfate 1.) 1,2-dichloroethane, room temperature, 1 h, 2.) 80 deg C, 3 h; Yield given. Multistep reaction;

...Expand

: 934-34-9
2(3H)-Benzothiazolone

: 15972-60-8
Alachlor

: 119584-52-0
N-(2,6-Diethyl-phenyl)-N-methoxymethyl-2-(2-oxo-benzothiazol-3-yl)-acetamide

Conditions

Conditions	Yield
With potassium hydroxide In water; N,N-dimethyl-formamide at 80 - 90℃; for 24h;	86%

: 15972-60-8
Alachlor

: 74886-79-6
N-(2,6-Diethylphenyl)-N-(methoxymethyl)acetamide

Conditions

Conditions	Yield
With [Co(4,4'-bis(hydroxymethyl)-2,2'-bipyridine)2](BF4)2 In water Kinetics; Reagent/catalyst; Electrolysis;	85%
With triethanolamine; C53H75CoN4O14(1+)*ClO4(1-); rose bengal In methanol at 20℃; for 3h; Inert atmosphere; Visible light irradiation;	84%

: 15972-60-8
Alachlor

: 71-36-3
butan-1-ol

: 23184-66-9
N-butoxymethyl-2-chloro-N-(2,6-diethylphenyl)acetamide

Conditions

Conditions	Yield
With trifluoroborane diethyl ether	83%

: 15972-60-8
Alachlor

: 961-07-9
2'-Deoxyguanosine

A: 7-[[N-(methoxymethyl)-N-(2,6-diethylphenyl)carbamoyl]methyl]guanine

B: alachlor-N1-2'-deoxyguanosine

Conditions

Conditions	Yield
With sodium hydrogencarbonate In 2-methoxy-ethanol at 50℃; for 360h; Addition;	A 6.1% B 12%

...Expand

: 15972-60-8
Alachlor

: thymidine 3'-monophosphate disodium salt

: 3-[[N-(methoxymethyl)-N-(2,6-diethylphenyl)carbamoyl]methyl]thymidine 3'-monophosphate disodium salt

Conditions

Conditions	Yield
With sodium hydrogencarbonate In 2-methoxy-ethanol; water at 75℃; for 24h; Addition;	10.8%

: 15972-60-8
Alachlor

: 2'-deoxyguanosine 3'-monophosphate ammonium salt

: 1-[[N-(methoxymethyl)-N-(2,6-diethylphenyl)carbamoyl]methyl]-2'-deoxyguanosine 3'-monophosphate ammonium salt

Conditions

Conditions	Yield
With sodium hydrogencarbonate In 2-methoxy-ethanol; water at 50℃; for 48h; Addition;	9.13%

: 15972-60-8
Alachlor

: 50-89-5
thymidine

: 3-[[N-(methoxymethyl)-N-(2,6-diethylphenyl)carbamoyl]methyl]thymidine

Conditions

Conditions	Yield
With sodium hydrogencarbonate In 2-methoxy-ethanol at 45 - 50℃; for 336h; Addition;	5.3%

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Chemistry

IUPAC Name: 2-chloro-N-(2,6-diethylphenyl)-N-(methoxymethyl)acetamide
Empirical Formula: C₁₄H₂₀ClNO₂
Molecular Weight: 269.7671g/mol
EINECS: 240-110-8
Structure of Alachlor (CAS NO.15972-60-8):

Index of Refraction: 1.539
Molar Refractivity: 75.55 cm³
Molar Volume: 240.9 cm³
Polarizability: 29.95×10^-24cm³
Surface Tension: 39.8 dyne/cm
Density: 1.119 g/cm³
Flash Point: 198.1 °C
Enthalpy of Vaporization: 65.54 kJ/mol
Melting Point: 39-42°C
Boiling Point: 404 °C at 760 mmHg
Vapour Pressure: 9.74E-07 mmHg at 25°C
Water Solubility: 0.024 g/100 mL
Product Categories: AmideMethod Specific;2000/60/EC;A;AA to ALPesticides&Metabolites;A-BAlphabetic;Alpha sort;European Community: ISO and DIN;Herbicides;Pesticides&Metabolites
Canonical SMILES: CCC1=C(C(=CC=C1)CC)N(COC)C(=O)CCl
InChI: InChI=1S/C14H20ClNO2/c1-4-11-7-6-8-12(5-2)14(11)16(10-18-3)13(17)9-15/h6-8H,4-5,9-10H2,1-3H3
InChIKey: XCSGPAVHZFQHGE-UHFFFAOYSA-N
Synonyms of Alachlor (CAS NO.15972-60-8): 2-Chloro-2',6'-diethyl-N-(methoxymethyl)acetanilide ; Acetamide, 2-chloro-N-(2,6-diethylphenyl)-N-(methoxymethyl)- ; Alachlor ; Alachlore ; Alanex ; Chimiclor ; Chloressigsaeure-N-(methoxymethyl)-2,6-diaethylanilid ; EPA Pesticide Chemical Code 090501 ; Lasagrin ; Lasso micro-tech ; Metachlor ; N-(Methoxymethyl)-2,6-diethylchloroacetanilide ; alpha-Chloro-2',6'-diethyl-N-methoxymethylacetanilide

Uses

Alachlor (15972-60-8) is a chloroacetanilide class herbicide for grasses & broadleaf weeds on corn & sorghum, soybeans, peanuts, cotton, vegetables, forage crops.

Toxicity Data With Reference

1.	mmo-omi 90 mg/L	JASIAB Journal of Agricultural Science. 104 (1985),571.
2.	mrc-smc 33 µg/plate	MUREAV Mutation Research. 136 (1984),233.
3.	cyt-hmn:lym 4 mg/L	MUREAV Mutation Research. 116 (1983),341.
4.	cyt-rat-ipr 1250 µg/kg	MUREAV Mutation Research. 116 (1983),341.
5.	orl-rat LD50:930 mg/kg	TXCYAC Toxicology. 3 (1987),383.
6.	orl-rat LD50:1200 mg/kg	WRPCA2 World Review of Pest Control. 9 (1970),119.
7.	orl-mus LD50:462 mg/kg	GTPZAB Gigiena Truda i Professionalnye Zabolevaniia. Labor Hygiene and Occupational Diseases. 21 (12)(1977),30.
8.	skn-rbt LD50:3500 mg/kg	GUCHAZ Guide to the Chemicals Used in Crop Protection 6 (1973),3.
9.	orl-mam LD50:3000 mg/kg	GUCHAZ Guide to the Chemicals Used in Crop Protection 6 (1973),3.
10.	unk-mam LD50:1200 mg/kg	30ZDA9 Chemistry of Pesticides. Melnikov, N.N.,New York, NY.: Springer-Verlag,1971,126.

Consensus Reports

EPA Genetic Toxicology Program.

Safety Profile

Hazard Codes: Harmful Xn; Dangerous N, Flammable F, Toxic T
Risk Statements: 22-40-43-50/53-67-65-38-11-52/53-39-23/24/25-51/53
R22:Harmful if swallowed.
R40:Limited evidence of a carcinogenic effect.
R43:May cause sensitization by skin contact.
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R67:Vapours may cause drowsiness and dizziness.
R65:Harmful: may cause lung damage if swallowed.
R38:Irritating to skin.
R11:Highly flammable.
R52/53:Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R39:Danger of very serious irreversible effects.
R23/24/25:Toxic by inhalation, in contact with skin and if swallowed.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Safety Statements: 36/37-46-60-61-62-45
S36/37:Wear suitable protective clothing and gloves.
S46:If swallowed, seek medical advice immediately and show this container or label.
S60:This material and its container must be disposed of as hazardous waste.
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
S62:If swallowed, do not induce vomitting; seek medical advice immediately and show this container or label.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 3077
RTECS: AE1225000
Hazardous Substances Data 15972-60-8(Hazardous Substances Data
Moderately toxic by ingestion, skin contact, and possibly other routes. Questionable carcinogen with experimental carcinogenic data. Human mutation data reported. When heated to decomposition it emits very toxic fumes of Cl⁻ and NO_x.

Standards and Recommendations

ASSAY: 90.% min