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CAS No.: | 16523-54-9 |
---|---|
Name: | Dicyclohexylchlorophosphine |
Article Data: | 15 |
Molecular Structure: | |
Formula: | C12H22ClP |
Molecular Weight: | 232.733 |
Synonyms: | Phosphinouschloride, dicyclohexyl- (6CI,7CI,8CI,9CI);Chlorodicyclohexylphosphine;Dicyclohexylphosphinous chloride; |
Density: | 1.054g/mLat 25°C(lit.) |
Melting Point: | 126-128 °C |
Boiling Point: | 297.5 °C at 760 mmHg |
Flash Point: | 133.7 °C |
Solubility: | reacts violently with water |
Appearance: | clear colorless liquid |
Hazard Symbols: | C |
Risk Codes: | 14-34 |
Safety: | 26-27-36/37/39-45-8 |
Transport Information: | UN 3265 8/PG 2 |
PSA: | 13.59000 |
LogP: | 5.28750 |
dicyclohexylphosphane
chlorodicyclohexylphosphane
Conditions | Yield |
---|---|
With Ethyl trichloroacetate In chlorobenzene at 80℃; for 2.46667h; Product distribution / selectivity; | 80.6% |
cyclohexylmagnesiumchloride
chlorodicyclohexylphosphane
Conditions | Yield |
---|---|
With phosphorus trichloride | |
With phosphorus trichloride In diethyl ether | |
With phosphorus trichloride In toluene at 0℃; |
cyclohexylmagnesiumchloride
dichlorocyclohexylphosphine
chlorodicyclohexylphosphane
Conditions | Yield |
---|---|
Irradiation; |
chlorodicyclohexylphosphane
Conditions | Yield |
---|---|
In chloroform at 20℃; |
chlorodicyclohexylphosphane
Conditions | Yield |
---|---|
In chloroform at 20℃; |
chlorodicyclohexylphosphane
Conditions | Yield |
---|---|
In chloroform at 20℃; |
1-bromocyclohexane
chlorodicyclohexylphosphane
Conditions | Yield |
---|---|
Stage #1: 1-bromocyclohexane With magnesium In tetrahydrofuran at 20℃; for 2h; Grignard reaction; Stage #2: With diethylphosphoramidous dichloride In tetrahydrofuran at 0 - 50℃; for 3h; phosphorylation; Stage #3: With hydrogenchloride In pentane at 0℃; for 1h; Hydrolysis; |
cyclohexyl chloride
chlorodicyclohexylphosphane
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: Mg / diethyl ether / 2.5 h / Heating 2: PCl3 / diethyl ether View Scheme | |
Stage #1: cyclohexyl chloride With magnesium In diethyl ether Stage #2: With phosphorus trichloride In diethyl ether at -40 - 20℃; for 5.33333h; | |
Multi-step reaction with 2 steps 1: diethyl ether 2: phosphorus trichloride / diethyl ether / -40 - 20 °C View Scheme | |
Stage #1: cyclohexyl chloride With magnesium In diethyl ether Stage #2: With phosphorus trichloride In tetrahydrofuran; diethyl ether at -40 - 20℃; for 7h; | |
Multi-step reaction with 2 steps 1: magnesium / diethyl ether 2: phosphorus trichloride / tetrahydrofuran / 7 h / -40 - 20 °C View Scheme |
trimethylsilyldicyclohexylphosphane
chlorodicyclohexylphosphane
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: 100 percent / diethyl ether / -25 °C 2: CHCl3 / 20 °C View Scheme | |
Multi-step reaction with 2 steps 1: 100 percent / diethyl ether / -25 °C 2: CHCl3 / 20 °C View Scheme | |
Multi-step reaction with 2 steps 1: 100 percent / diethyl ether / -25 °C 2: CHCl3 / 20 °C View Scheme |
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Chemical Name: Dicyclohexylchlorophosphine
CAS No.: 16523-54-9
Molecular Formula: C12H22ClP
Formula Weight: 232.73 g/mol
Density: 1.054 g/mL at 25 °C(lit.)
Flash Point: 133.7 °C
Boiling Point: 297.5 °C at 760 mmHg
Sensitive: Air & Moisture Sensitive
Following is the structure of Dicyclohexylchlorophosphine (16523-54-9):
Product Categories about Dicyclohexylchlorophosphine (16523-54-9) are Chlorophosphines ; Phosphines ; Catalysis and Inorganic Chemistry ; Phosphorus Compounds ; Phosphorus Precursors
The chemical synonymous of Dicyclohexylchlorophosphine (16523-54-9) are Chlorodicyclohexylphosphine ; Dicyclohexylphosphinous chloride ; Dicyclohexylchlorophosphine ; Dicyclohexylchlorophosphine, 98+% ; Chlorodicyclohexylphosphine,97%
Hazard Codes:
C: Corrosive
Risk Statements about Dicyclohexylchlorophosphine (16523-54-9):
R14 Reacts violently with water.
R34 Causes burns.
Safety Statements about Dicyclohexylchlorophosphine (16523-54-9):
S8 Keep container dry.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
Attentions:
1. Storage: Store in a cool, dry place. Store in a tightly closed container.
2. Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. Handle under argon.