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110-82-7

Basic Information
CAS No.: 110-82-7
Name: Cyclohexane
Molecular Structure:
Molecular Structure of 110-82-7 (Cyclohexane)
Formula: C6H12
Molecular Weight: 84.18
Synonyms: Cyclohexan [German];RCRA waste no. U056;Cyclohexaan [Dutch];Cicloesano [Italian];Cyclohexane [UN1145] [Flammable liquid];hexahydro-;hexahydrobenzene;RCRA waste number U056;Cyclohexaan;Benzene, hexahydro-;Cyclohexan;Cykloheksan;hexanaphthene;hexamethylene;Cyclohexane (DOT;Cyclohexane ring;EPA Pesticide Chemical Code 025901;Cicloesano;10-81-1;Benzenehexahydride;Cykloheksan [Polish];Cyclobexane;Cyclohexane, Reagent;Cyclohexane, Spectrophotometric Grade;
EINECS: 203-806-2
Density: 0.791 g/cm3
Melting Point: 4-7 °C(lit.)
Boiling Point: 80.719 °C at 760 mmHg
Flash Point: -18ºC
Solubility: PRACTICALLY INSOLUBLE
Appearance: colorless liquid
Hazard Symbols: FlammableF,HarmfulXn,DangerousN
Risk Codes: 11-38-50/53-65-67
Safety: 9-16-25-33-60-61-62
Transport Information:
PSA: 0.00000
LogP: 2.34060
Synthetic route
1165952-91-9

cyclohexa-1,3-diene

110-82-7

cyclohexane

Conditions
ConditionsYield
With Pd/C; hydrogen In chloroform at 20℃; under 760.051 Torr; for 2h; Catalytic behavior;100%
With hydrogen; HRh(CO)3 at 79.9℃; under 3750.3 Torr; for 1.66667h;63%
With hydrogen In tetrahydrofuran at 20℃; under 760.051 Torr; for 10h;50%
110-83-8

cyclohexene

110-82-7

cyclohexane

Conditions
ConditionsYield
With hydrogen; mer-Os(PPh3)3HBr(CO) at 150℃; under 3800 Torr; for 1h; Product distribution;100%
With hydrogen; decacarbonyldirhenium(0) at 230℃; under 37503 Torr; for 0.25h;100%
With {(η6-C6H6)Ru(NCCH3)3}{BF4}2; water; hydrogen In benzene at 90℃; under 30400 Torr; for 4h;100%
71-43-2

benzene

110-82-7

cyclohexane

Conditions
ConditionsYield
With hydrogen; [(norbornadiene)rhodium(I)chloride]2; polydiacetylene In n-heptane at 30℃; under 60800 Torr; for 0.9h; Product distribution; various aromatic compounds and other catalyst also investigated;100%
With hydrogen; Ni-Tc on γ-Al2O3 at 175 - 250℃; under 760 Torr; Product distribution; dependence of catalytic activity on the reduction temperature; enhanced activity of bimetallic catalysts;100%
With hydrogen; decacarbonyldirhenium(0) at 230℃; under 75005.9 Torr; for 0.25h;100%
108-85-0

1-bromocyclohexane

110-82-7

cyclohexane

Conditions
ConditionsYield
With 9-borabicyclo[3.3.1]nonane dimer; triphenylstannane In toluene at 0℃;100%
With triethylsilane; aluminium trichloride In dichloromethane at 18 - 20℃; for 0.25h;95%
With water; sodium iodide; nickel dichloride; zinc; sonication In N,N,N,N,N,N-hexamethylphosphoric triamide at 60℃; for 1h; Product distribution;82%
108-90-7

chlorobenzene

110-82-7

cyclohexane

Conditions
ConditionsYield
With hydrogen; Leuna-Kontakt 6525 at 150℃; Product distribution; other halogen organic compounds, var. catalysts;100%
With hydrogen; platinum at 120℃; under 16501.7 Torr; for 1.66667h; Autoclave; Inert atmosphere;12.8%
With dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer; hydrogen; triethylamine In isopropyl alcohol at 75℃; under 31028.9 Torr; for 4h; other chloroaromatics; var. reaction time; catalytic hydrodechlorination;
1333-74-0

hydrogen

110-83-8

cyclohexene

110-82-7

cyclohexane

Conditions
ConditionsYield
With C53H82ClN3P2Ru In dichloromethane-d2 at 50℃; under 3040.2 Torr; for 3h; Reagent/catalyst; Time;100%
at 25℃; Catalytic behavior;
With ReH(NO)2(P(CH(CH3)2)3)2; Dimethylphenylsilane; tris(pentafluorophenyl)borate at 100℃; under 30003 Torr; for 1h; Catalytic behavior; Autoclave;
With [ReH(NO)2(P(C6H11)3)2]; Dimethylphenylsilane; tris(pentafluorophenyl)borate at 100℃; under 30003 Torr; for 1h; Catalytic behavior; Autoclave;
at 80℃; under 30003 Torr; for 24h;
101-84-8

diphenylether

A

110-82-7

cyclohexane

B

108-93-0

cyclohexanol

C

71-43-2

benzene

Conditions
ConditionsYield
With isopropyl alcohol at 150℃; under 7500.75 Torr; for 12h; Inert atmosphere; Autoclave;A 25.1%
B 100%
C 74.9%
With isopropyl alcohol at 160℃; for 15h; Autoclave; Inert atmosphere;
With isopropyl alcohol at 150℃; for 10h; Catalytic behavior; Reagent/catalyst; Temperature; Sealed tube;A 24.6 %Chromat.
B 47.8 %Chromat.
C 24.3 %Chromat.
With isopropyl alcohol at 150℃; for 6h; Temperature; Sealed tube;A 15.2 %Chromat.
B 17.7 %Chromat.
C 5.8 %Chromat.
120-80-9

benzene-1,2-diol

110-82-7

cyclohexane

Conditions
ConditionsYield
With hydrogen In dodecane at 200℃; under 15001.5 Torr; for 8h;99.9%
bei der katalytischen Hyrierung;
With phosphoric acid; 5% Pd(II)/C(eggshell); hydrogen In water at 249.84℃; under 37503.8 Torr; for 0.5h; Autoclave;87 %Chromat.
1965-09-9

4,4'-dihydroxydiphenyl ether

110-82-7

cyclohexane

Conditions
ConditionsYield
With hydrogen In dodecane at 200℃; under 15001.5 Torr; for 2h;99.9%
With rhodium contaminated with carbon; N-methyldiethanolamine trifluoromethanesulfonate; hydrogen at 120℃; under 30003 Torr; for 6h; Autoclave;91.5%
With carbon nanotubes-supported ruthenium; hydrogen In dodecane; water at 220℃; under 37503.8 Torr; for 3h; Autoclave;64 %Chromat.
With hydrogen at 130℃; under 15001.5 Torr; for 6h; Ionic liquid; Autoclave; Schlenk technique;99.4 %Chromat.
91-10-1

1,3-dimethoxy-2-hydroxy-benzene

110-82-7

cyclohexane

Conditions
ConditionsYield
With hydrogen In dodecane at 200℃; under 15001.5 Torr; for 12h;99.9%
Multi-step reaction with 2 steps
1: hydrogen / water / 8 h / 200 °C / 30003 Torr / Autoclave
2: hydrogen / water / 4 h / 200 °C / 30003 Torr
View Scheme
With palladium on activated charcoal; hydrogen In water at 150℃; under 30003 Torr; for 4h; Reagent/catalyst; Autoclave;
90-05-1

2-methoxy-phenol

110-82-7

cyclohexane

Conditions
ConditionsYield
With hydrogen In dodecane at 200℃; under 15001.5 Torr; for 2h;99.6%
With rhodium contaminated with carbon; N-methyldiethanolamine trifluoromethanesulfonate; hydrogen at 120℃; under 30003 Torr; for 6h; Autoclave;93.5%
With Ni-doped silica; hydrogen In decalin at 140℃; under 22502.3 Torr; for 5h; Reagent/catalyst; Autoclave;91.7%
101-84-8

diphenylether

110-82-7

cyclohexane

Conditions
ConditionsYield
With hydrogen In dodecane at 300℃; under 45004.5 Torr; for 1h; Autoclave;99.3%
With hafnium tetrakis(trifluoromethanesulfonate); Ru/Al2O3; hydrogen In octane at 250℃; under 30003 Torr; for 2h; Sealed tube;94.3%
With hydrogen In dodecane at 200℃; under 15001.5 Torr; for 2h;92%
108-93-0

cyclohexanol

110-82-7

cyclohexane

Conditions
ConditionsYield
With hydrogen; aluminum oxide; nickel at 180℃;99%
With platinum on activated charcoal; N-methyldiethanolamine trifluoromethanesulfonate; hydrogen at 120℃; under 30003 Torr; for 2h; Autoclave;93.5%
at 300℃; Leiten ueber Aktivkohle;
2719-27-9

cyclohexanylcarbonyl chloride

110-82-7

cyclohexane

Conditions
ConditionsYield
With tris-(trimethylsilyl)silane; 2,2'-azobis(isobutyronitrile) In toluene at 80℃; for 0.666667h;99%
101-84-8

diphenylether

A

110-82-7

cyclohexane

B

108-93-0

cyclohexanol

Conditions
ConditionsYield
With bis(acetylacetonate)nickel(II); cetyltrimethylammonim bromide; lithium tri-t-butoxyaluminum hydride; sodium t-butanolate; tricyclohexylphosphine In toluene at 70℃; for 5h; Micellar solution;A 99%
B 99%
With Ru0.6Ni0.4; hydrogen In water at 95℃; under 760.051 Torr; for 16h; Reagent/catalyst;A 92%
B 96%
With hydrogen In water at 110℃; under 7500.75 Torr; for 1h; Autoclave;
123-31-9

hydroquinone

110-82-7

cyclohexane

Conditions
ConditionsYield
With gold on titanium oxide In decane at 299.84℃; under 22502.3 Torr; for 12h; Temperature; High pressure; Inert atmosphere; Autoclave;98.7%
With hydrogen In water at 200℃; under 37503.8 Torr; for 2h; Autoclave; Green chemistry;
With hydrogen In dodecane at 224.84℃; under 30003 Torr; for 2h; Autoclave;
With carbon nanotubes-supported ruthenium; hydrogen In dodecane; water at 220℃; under 37503.8 Torr; for 3h; Autoclave;90 %Chromat.
108-46-3

recorcinol

110-82-7

cyclohexane

Conditions
ConditionsYield
With hydrogen In dodecane at 200℃; under 15001.5 Torr; for 8h;98.6%
With dihydrogen hexachloroplatinate; hydrogen; 3-butyl-1-methyl-1H-imidazol-3-ium hexafluorophosphate; 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide at 60℃; under 7500.75 Torr; for 15h; Autoclave;
62-53-3

aniline

A

110-82-7

cyclohexane

B

108-91-8

cyclohexylamine

C

101-83-7

N-cyclohexyl-cyclohexanamine

D

110-83-8

cyclohexene

Conditions
ConditionsYield
With ammonia; hydrogen at 180 - 200℃;A n/a
B 98.4%
C 0.08%
D n/a
With hydrogen at 160 - 200℃; under 150015 Torr;A n/a
B 95.9%
C 0.45%
D n/a
106-51-4

p-benzoquinone

110-82-7

cyclohexane

Conditions
ConditionsYield
With gold on titanium oxide In decane at 299.84℃; under 22502.3 Torr; for 12h; Time; High pressure; Inert atmosphere; Autoclave;98.2%
108-95-2

phenol

110-82-7

cyclohexane

Conditions
ConditionsYield
With hydrogen In water at 130℃; for 20h; Reagent/catalyst; Inert atmosphere; Autoclave; Heating; stereoselective reaction;97.9%
With rhodium contaminated with carbon; N-methyldiethanolamine trifluoromethanesulfonate; hydrogen at 120℃; under 30003 Torr; for 24h; Reagent/catalyst; Autoclave;97.3%
With hydrogen In water at 249.84℃; under 30003 Torr;93.7%
108-94-1

cyclohexanone

110-82-7

cyclohexane

Conditions
ConditionsYield
With hydrogen In neat (no solvent) at 200℃; under 37503.8 Torr; for 24h; Autoclave;97%
With hydrogen; aluminum oxide; nickel at 190℃;90%
With hydrogen; K-10 montmorillonite; platinum In diethylene glycol dimethyl ether under 37503 Torr; for 30h; Reduction;82%
1165952-91-9

cyclohexa-1,3-diene

A

110-82-7

cyclohexane

B

110-83-8

cyclohexene

Conditions
ConditionsYield
With hydrogen; palladium dichloride In N,N-dimethyl-formamide under 18751.5 Torr; for 0.333333h; Product distribution; Ambient temperature; various time;A 0.05%
B 95.6%
With ammonium acetate In methanol Electrochemical reaction;A 88%
B 12%
With hydrogen; (η3-C3H5)Co[P(OMe)3]3 for 24h; Ambient temperature;A 7.6%
B 48.3%
100-66-3

methoxybenzene

110-82-7

cyclohexane

Conditions
ConditionsYield
With hydrogen In decalin at 20 - 220℃; under 37503.8 - 45004.5 Torr; Reagent/catalyst; Inert atmosphere; Autoclave;95%
With ruthenium-carbon composite; N-methyldiethanolamine trifluoromethanesulfonate; hydrogen at 150℃; under 7500.75 Torr; for 6h; Autoclave;91.2%
With hydrogen; platinum unter geringem Ueberdruck;
617-86-7

triethylsilane

372-46-3

fluorocyclohexane

A

358-43-0

triethylsilyl fluoride

B

110-82-7

cyclohexane

Conditions
ConditionsYield
With C21H16N3P(2+) In dichloromethane at 25℃; for 4h; Reagent/catalyst;A 95%
B n/a
With [(SIMes)PFMe2][B(C6F5)4]2 In dichloromethane-d2 for 1h; Catalytic behavior; Inert atmosphere;
150-19-6

O-methylresorcine

110-82-7

cyclohexane

Conditions
ConditionsYield
With hydrogen In dodecane at 200℃; under 15001.5 Torr; for 2h;95%
2695-47-8

6-Bromo-1-hexene

A

592-41-6

1-hexene

B

96-37-7

methyl-cyclopentane

C

110-82-7

cyclohexane

Conditions
ConditionsYield
With tris-(trimethylsilyl)silane; 2,2'-azobis(isobutyronitrile) at 70℃;A 4.1%
B 93%
C 2%
With tri-n-butyl-tin hydride; 2,2'-azobis(isobutyronitrile) at 70℃;A 15%
B 83%
C 1.2%
With 9-borabicyclo[3.3.1]nonane dimer; tribenzyltin hydride In toluene at 0℃; Product distribution; variation of reagent;A 29%
B 68%
C 3%
150-76-5

4-methoxy-phenol

110-82-7

cyclohexane

Conditions
ConditionsYield
With rhodium contaminated with carbon; N-methyldiethanolamine trifluoromethanesulfonate; hydrogen at 150℃; under 7500.75 Torr; for 6h; Autoclave;92.3%
With hydrogen In dodecane at 224.84℃; under 30003 Torr; for 2h; Autoclave;
1655-68-1

1-methoxy-3-phenoxybenzene

A

16327-00-7, 89794-53-6

3-methoxycyclohexan-1-ol

B

110-82-7

cyclohexane

Conditions
ConditionsYield
With bis(acetylacetonate)nickel(II); cetyltrimethylammonim bromide; lithium tri-t-butoxyaluminum hydride; sodium t-butanolate; tricyclohexylphosphine In toluene at 70℃; for 5h; Micellar solution;A 92%
B 89%
946-80-5

(benzyloxy)benzene

A

110-82-7

cyclohexane

B

82166-21-0

methyl cyclohexane

Conditions
ConditionsYield
With palladium on activated charcoal; N-methyldiethanolamine trifluoromethanesulfonate; hydrogen at 150℃; under 7500.75 Torr; for 6h; Autoclave;A 91.5%
B 90.3%
With carbon nanotubes-supported ruthenium; hydrogen In dodecane; water at 220℃; under 37503.8 Torr; for 3h; Autoclave;A 95 %Chromat.
B 44 %Chromat.
With hydrogen at 130℃; under 15001.5 Torr; for 6h; Ionic liquid; Autoclave; Schlenk technique;
90-05-1

2-methoxy-phenol

A

96-37-7

methyl-cyclopentane

B

110-82-7

cyclohexane

Conditions
ConditionsYield
With hydrogen In dodecane at 300℃; under 45004.5 Torr; for 1h; Autoclave;A 6.08%
B 90.52%
With hydrogen at 320℃; under 127513 Torr; for 1h; Reagent/catalyst; Autoclave;A 6.8 %Chromat.
B 67 %Chromat.
110-82-7

cyclohexane

108-85-0

1-bromocyclohexane

Conditions
ConditionsYield
With bromine; aluminum tri-bromide; Acetyl bromide In dichloromethane at -20℃; for 3h;100%
With bromine; sodium t-butanolate In cyclohexane at 40℃; for 15h;100%
With manganese(IV) oxide; bromine at 80℃; for 0.166667h; Product distribution; Further Variations:; Reagents; reagent ratios, reaction time;99%
110-82-7

cyclohexane

355-68-0

perfluorocyclohexane

Conditions
ConditionsYield
cobalt (III) fluoride at 360℃; for 3h;100%
With fluorine Product distribution; Irradiation;30%
With lead(IV) fluoride at 200℃; zuletzt bei 400grad;
110-82-7

cyclohexane

A

108-94-1

cyclohexanone

B

108-93-0

cyclohexanol

Conditions
ConditionsYield
With Fe2(4,4″-dioxido-[1,1′:4′,1″-terphenyl]-3,3″-dicarboxylate); 1-(tert-butylsulfonyl)-2-iodosylbenzene In [D3]acetonitrile at 20℃; for 1.5h;A 100%
B 100%
With 3-chloro-benzenecarboperoxoic acid; [Ni2(L2H2)(OAc)2] at 20℃; for 1h;A 7%
B 93%
With 3-chloro-benzenecarboperoxoic acid; (5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato)iron(III) chloride In dichloromethane; acetonitrile for 1h; Product distribution; Ambient temperature; other catalysts; kinetic isotope effect;A 2%
B 89%
110-82-7

cyclohexane

1666-13-3

diphenyl diselenide

22233-91-6

phenylselenocyclohexane

Conditions
ConditionsYield
With 4-tert-butylpyridine; hydrogen sulfide; oxygen; iron(II) chloride In acetonitrile for 4h; Ambient temperature;100%
With 4-tert-butylpyridine; 2-Picolinic acid; dihydrogen peroxide; triphenylphosphine; iron(II) chloride In acetonitrile at 0℃;99%
With di-tert-butyl peroxide at 120℃; for 18h; Reagent/catalyst;96%
110-82-7

cyclohexane

66121-61-7

N,O-bistrimethylsilyl-N-(ethoxycarbonyl)hydroxylamine

A

107-46-0

Hexamethyldisiloxane

B

1541-19-1

ethyl N-cyclohexylcarbamate

C

51-79-6

urethane

Conditions
ConditionsYield
at 100℃; for 25h;A 100%
B 80%
C 8%
at 45℃; for 58h; Irradiation;A 75%
B 45%
C 55%
110-82-7

cyclohexane

84210-61-7

perpentene-4 oate de tertiobutyle

A

92-51-3

cyclohexylcyclohexane

B

1678-93-9

butylcyclohexane

C

96009-79-9

cyclohexyl-5 pentanolide-4

D

67-64-1

acetone

E

108-29-2

5-methyl-dihydro-furan-2-one

F

75-65-0

tert-butyl alcohol

Conditions
ConditionsYield
at 120℃; for 4h; Product distribution; Mechanism; different ratios of reactant, reactants, reaction times and temperatures;A 5%
B 5%
C 35%
D n/a
E 1%
F 100%
110-82-7

cyclohexane

80037-90-7

1,1,3,3-tetramethyl-2,3-dihydro-1H-isoindol-2-yloxoyl radical

37421-16-2

2-(t-butylazo)prop-2-yl hydroperoxide

A

89482-40-6

2-cyclohexyloxy-1,1,3,3-tetramethyl-2,3-dihydro-1H-isoindole

B

93524-81-3

2-tert-butoxy-1,1,3,3-tetramethylisoindoline

C

67-64-1

acetone

D

115-11-7

isobutene

Conditions
ConditionsYield
at 70℃; for 17h; Mechanism; Rate constant; Thermodynamic data; var. of nitroxide, solvent, temp., EA, ΔH(excit.), ΔS(excit.);A 96%
B 82%
C 100%
D 15%
110-82-7

cyclohexane

A

1805-22-7

perfluoro(2-methylcyclopentane)

B

355-68-0

perfluorocyclohexane

Conditions
ConditionsYield
cobalt (III) fluoride at 360℃; for 3h; Product distribution;A n/a
B 100%
110-82-7

cyclohexane

645-96-5

Benzeneselenol

22233-91-6

phenylselenocyclohexane

Conditions
ConditionsYield
With 4-tert-butylpyridine; hydrogen sulfide; oxygen; iron(II) chloride In acetonitrile for 4h; Ambient temperature;100%
110-82-7

cyclohexane

69226-51-3

2,2,2-trichloroethyl sulfamate

N-(cyclohexyl)-2,2,2-trichloroethoxysulfonamide

Conditions
ConditionsYield
With [bis(acetoxy)iodo]benzene; C32H44ClN4O4Rh2*3CH2Cl2 at 20℃; for 3h; Inert atmosphere;100%
With bis(tertbutylcarbonyloxy)iodobenzene; Rh2(esp)2 In benzene at 23℃;95%
With bis{rhodium[3,3'-(1,3-phenylene)bis(2,2-dimethylpropanoic acid)]}; [bis(acetoxy)iodo]benzene In water at 4℃; for 24h;64%
With [p-(trifluoromethyl)phenyl](diacetoxy)-λ3-bromane at 0 - 15℃; for 3h; Inert atmosphere;18%
111496-23-2

LaFe(1+)

110-82-7

cyclohexane

A

LaFeC6H6(1+)

B

1333-74-0

hydrogen

Conditions
ConditionsYield
In gas reaction in a mass spectrometer; total pressure: 4E-6 Torr;A 100%
B 100%
32308-83-1

nonafluoro-tert-butanesulfenyl chloride

110-82-7

cyclohexane

A

32308-82-0

nonafluoro-tert-butanethiol

B

542-18-7

cyclohexyl chloride

Conditions
ConditionsYield
A 100%
B 100%
A 100%
B 100%
110-82-7

cyclohexane

C44H41Cl8Cu2N5

387876-29-1

N-cyclohexyl-1-aminoadamantane

Conditions
ConditionsYield
In benzene at 80℃; for 4h; Inert atmosphere;100%
110-82-7

cyclohexane

201230-82-2

carbon monoxide

2043-61-0

cyclohexanecarbaldehyde

Conditions
ConditionsYield
With MCM-41 silicate; hydrogen; di(rhodium)tetracarbonyl dichloride at 100℃; under 21001.7 Torr; for 20h;99.4%
With Rh; benzaldehyde In benzene Mechanism; Irradiation; other d8 metal carbonyls, other aromatic ketones and aldehydes; relative quantum yields;
623-73-4

diazoacetic acid ethyl ester

110-82-7

cyclohexane

5452-75-5

ethyl 2-cyclohexylacetate

Conditions
ConditionsYield
With C28H6Ag2Au2F24N2 In cyclohexane for 12h; Inert atmosphere;99%
With C56H82Cl2Cu2N4O2P2; sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate In dichloromethane at 20℃; for 12h; Inert atmosphere; Schlenk technique;98%
With C4H11B22Br12IN2(2-)*2Li(1+); copper dichloride In tetrahydrofuran at 90℃; for 3h; Reagent/catalyst; Inert atmosphere; Reflux;92.6%
110-82-7

cyclohexane

124-04-9

Adipic acid

Conditions
ConditionsYield
With nitric acid; trifluoroacetic acid; N-hydroxy-5-carboxy-phthalimide at 23℃; for 18h; Reagent/catalyst;99%
With 2-pyrazylcarboxylic acid; FeCl2(κ3-HC(C3H3N2)3); ozone at 20℃; for 6h; Catalytic behavior; Time; Reagent/catalyst; Schlenk technique; Green chemistry;96%
In acetic acid at 115℃; under 22502.3 Torr; for 5h; Reagent/catalyst; Pressure;95%
874-14-6

1,3-dimethyluracil

110-82-7

cyclohexane

124851-78-1

5-cyclohexyl-1,3-dimethyluracil

Conditions
ConditionsYield
With dibenzoyl peroxide for 14h; Product distribution; Heating; further educts and peroxides;99%
With dilauryl peroxide for 14h; Heating;99%
With dibenzoyl peroxide at 80℃; Yield given;
  • Cyclohexane

  • Casno:

    110-82-7

    Cyclohexane

    Min.Order: 150 Kilogram

    FOB Price:  USD $ 800.0-800.0/Kilogram

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    Shandong Yanshuo Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemi

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    China (Mainland)  |  Contact Details

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    110-82-7

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    Welcome to Simagchem, your partner in China as a premier supply of bulk specialty chemicals for industry and life science. We introduce experienced quality product and exceptional JIT service with instant market intelligence in China to benefit our

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    Hebei yanxi chemical co. LTD. has expanded a compositive entity from initially only as a small manufacturer. The company dedicated to the development, production and marketing of

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    110-82-7

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    As a leading manufacturer and supplier of chemicals in China, DayangChem not only supply popular chemicals, but also DayangChem's R&D center offer custom synthesis services. DayangChem can provide different quantities of custom synthesis ch

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    Business Type:Lab/Research institutions

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    110-82-7

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    Alias: Hexahydrobenzene CAS No.: 110-82-7 EINECS No.: 203-806-2 Molecular formula: C6H12 Molecular weight: 84.16 Properties:

    Welcome to Henan Sinotech! Sinotech Corporation has exceptional sourcing ability for chemicals used in Organic Fine Chemicals and APIs; Inorganic chemicals; Flame Retardants;OLED

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    110-82-7

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    Product Name 2-Methoxyethanol Appearance colorless clear liquid CAS

    Ality Group, established in 2007, is a comprehensive Chemical Supply Group with Patent Technology as its core. Ality Group operates branches in Hong Kong, Singapore and mainland Ch

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    110-82-7

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    Cyclohexane Basic information Product Name: Cyclohexane Synonyms: NAPHTHENE;Benzene, hexahydro-;benzenehexahydride;Cicloesano;Cyclohesan;cyclohexaan;cyclohexan;Cyclohexan(FormI)

    Our company engages in Electronic chemicals such as OLED,Photoresist chemical,Electrolyte additive and Intermediate Pharmaceutical production; development of noble metal catalysts,

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    Business Type:Lab/Research institutions

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    Address:Zhengzhou International Trade New Territory,Jinshui District,Zhengzhou ,China

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    110-82-7

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    110-82-7

    MSDS/COA Download

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    Business Type:Trading Company

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    110-82-7

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    Hello, dear friend! I'm Hansen and Allen from China. Welcome to my lookchem mall! The following is a brief introduction of our company's products and services. If you are interested in our products, please contact us by email in t

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    Business Type:Lab/Research institutions

    Tel:18369939125

    Address:95A, Xingyuan East Road, Zhangdian District

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    110-82-7

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    Business Type:Trading Company

    Tel:86-533-18653328009

    Address:Economic&DevelopmentArea,Zibo,Shandong,China

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    110-82-7

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    Our company has been in existence for 10 years since its establishment. We have our own unique team. The company integrates independent research and development, production and sales. We have established famous brands at home and abroad. At present

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    110-82-7

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    Our Service: 1. Best quality in your requirement 2. Competitive price in china market 3. Mature technical support 4. Professional logistic support 5 . Full experience of large numberscontainers loading in chinese sea port 6 .Fast

    Wuhan Monad Medicine Tech Co.,LTD is a research and development, production, sales in one high-tech company, own about 100 kinds of products, can provide about more than 30000 kind

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     China (Mainland)  |  Contact Details

    Business Type:Trading Company

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    110-82-7

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    Minimum Order Qty. 10 Gram

    We, Jilin Tely Imp & Exp Co., Ltd. mainly supply and export products including: pharmaceutical raw materials,Chemical reagents, Food additives, pharmaceutical and pesticide interme

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     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:86-431-81915458

    Address:Room 302, 47 Changping Street, Chaoyang District, Changchun, Jilin Province,China

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    110-82-7

    Manufacturer Direct Sales Low Price Cyclohexane

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    Known for its best quality and competitve price, this chemicals we offered is widely appreciated by our customers.Our advantages:1, High quality with competitive price:1) Standard:BP/USP/EP/Enterprise standard2) All Purity≥99%3) We are manufacturer a

    Shaanxi Mingqi Chemical Co., Ltd is committed to the development of import and export trade in the production, operation and plant extracts of pharmaceutical raw materials and inte

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    Business Type:Lab/Research institutions

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    110-82-7

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    factory Cyclohexane with best price CAS NO.110-82-7 about our company: so far, crovell has business in more than 35 countries,most big customers come from europe and america, because among the suppliers in china,crovell can always make the prod

    Hebei Guanlang Biotechnology Co., Ltd. belongs to Guanlang Group,which was founded in 2007 , located in Shijiazhuang city which is the capital of Hebei Province and hub sector amon

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     China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+8619930503256

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    110-82-7

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    Min.Order: 1 Metric Ton

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    Item Index …Appearance:Transparent colorless liquid Package:packed in iron drums Transportation:By Sea Port:Sha

    Founded in 1995, Shanghai Rich Chemicals Co., Ltd. is a privately held chemical industry group company. With a strong focus on the development of high purity, high performance prod

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    Business Type:Trading Company

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    110-82-7

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    Quick Details CAS No.: 110-82-7 MF: C6H12 EINECS No.: 203-806-2 Place of Origin: Hebei,China Type: Syntheses Material Intermediates

    Welcome to Hebei Bosang International Trade Co.,Ltd. Hebei Bosang International Trade Co.,Ltd. specializes in exporting high quality Pharmaceutical intermediates,Pharmaceutical

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    Business Type:Trading Company

    Tel:13633214322

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    110-82-7

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    Min.Order: 1 Kilogram

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    Our company is a professional chemical raw materials manufacturer and exporter for many years in chemical market. There are more than 200 excellent staffs and four factories working for us . Company advantage: 1.Place of Origin in China with Su

    CUSTOMIZED LAB Chemtn Biological Technology Limited is one of the leading RC chemicals producer in china,we have advanced equipment and high technology,

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    China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+8615630194059

    Address:LB BLDG,Qiaoxi district,Shijiazhuang,china

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    110-82-7

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    1.Coreychem focus on high complex new type intermediates and fine chemical custom synthesis,scale-up production and rare chemicals trade.Product category including Intermediates&API,Catalyst and Electronic Chemicals.Covering 811 square meters R

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    Business Type:Lab/Research institutions

    Tel:+86-371-86658258

    Address:Building 3 of Innovation Park, East District of the National University Science Park

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    110-82-7

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    1. Subsidiary of Institute of Chemistry, Henan Academy of Sciences, national research platform;2. About 30 years’ experience in this field since 1983;3. An experienced R&D team consisting of Doctors and Masters;4. Various types of analytical instrume

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-371-65511936

    Address:NO.56,Hongzhuan Road

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    110-82-7

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    span lang="EN-US" style="font-size: 9.0pt;font-family:"Arial",sans-serif;color:#4D4D4D">As a leading manufacturer and supplier of chemicals in china, weckchem not only supply popular chemicals, but also weckchem’s r&d center off

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     China (Mainland)  |  Contact Details

    Business Type:Other

    Tel:86-15158040660

    Address:Xiaoshan district

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    110-82-7

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    J&H CHEM R&D center can offer custom synthesis according to the contract research and development services for the fine chemicals, pharmaceutical, biotechnique and some of the other chemicals. J&H CHEM has some Manufacturing base in Jia

    J&H Chemical is one of China's leading providers of integrated fine chemical services including offering, research and development, Custom manufacturing business, as well as other

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-571-87396432

    Address:No.200 Zhenhua Rd.Xihu Industrial Park, Hangzhou 310030, China

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    110-82-7

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    HangYu Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals and OLED intermediates and other fine chemicals. HangYu Chemical consis

    Zibo HangYu Chemical is a leading manufacturer and supplier of chemicals in China. We develop produce and distribute high quality pharmaceuticals, intermediates, special chemicals

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    China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:86-15988566987

    Address:Room1701, Tianxing Building,Licheng district, jinan, Shandong, China

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    110-82-7

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    BaiFuChem is a Professional chemical raw material supplier in China, our main products include Biochemical , Pharma Intermediate and Organic chemical etc. BaiFuChem have wealth of products,experience , expertise and state-of-the-art

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     China (Mainland)  |  Contact Details

    Business Type:Other

    Tel:+86 592 605 6448

    Address:No.31 Pingshan South Road, HaiCang District, Xiamen, China

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    110-82-7

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    Business Type:Trading Company

    Tel:+86-0311-89278944

    Address:hebei

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    110-82-7

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    Superior quality Appearance:colorless liquid Storage:Stored in cool, dry and ventilation place; Away from fire and heat Package:1kg/bag, 1kg/drum or 25kg/drum or as per your request. Application:Suitable for HPLC, spectrophotometry, environmental t

    Hangzhou Yunuo Chemical Co., Ltd. is located in Hangzhou City, China We are specialized in fine chemicals and basic chemical auxiliary materials, Organic compounds, rubber

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    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:0571-83715115

    Address:hangzhou

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    110-82-7

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    Product name: Cyclohexane CAS No.:110-82-7 Molecule Formula:C6H12 Molecule Weight:84.16 Purity: 99.0% Package: 200kg/drum Description:Colorless liquid Manufacture Standards:Enterprise Standard TESTING ITEMS

    Siwei Development Group Ltd. is a reputed professional enterprise in China dedicated to the Amino Acids production and sales of fine chemical products.Over the years we have been m

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    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:86-571-82881840

    Address:Rm2-2-503 Zhongdingyuan, Xianghurenjia Wenyan Xiaoshan, Hangzhou China

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    110-82-7

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    Min.Order: 1 Gram

    FOB Price:  USD $ 3.0-3.0/Gram

    We are leading fine chemicals supplier in China with ISO certificate, Our main business covers the fields below: 1.Noble Metal Catalysts (Pt.Pd...) 2.Organic Phosphine Ligands (Tert-butyl-phosphine.Cyclohexyl-phosphine...) 3.OLED

    The company is Located in Zhengzhou High-tech Development Zone with import and export license, We passed ISO 9001:2008 as well, Henan Wentao has developed more than 1000 compounds,

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-370-2722992

    Address:32 Room, 5th Floor, Building 11, No. 6 Yinxing Road, High-tech Industrial Development Zone, Zhengzhou City, Henan Province

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    110-82-7

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    Changsha EASCHEM is a leading company in marketing ang distributing chemicals and new materials with establishment in 2013 by reregistering from Easchem International from China. We, EASCHEM, are the brand with the aim for erecting up Big Chemica

    Changsha EASCHEM is a leading company in marketing ang distributing chemicals and new materials with establishment in 2013 by reregistering from Easchem International from China.

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-731-89722861 89722891

    Address:2/F-4/Bld Colorful Palace, No.605 Changsha Ave, Yuhua Area Changsha Hunan China.

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    110-82-7

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

    Tel:+86-533-2362027

    Address:No. 416, 4th floor, zhongguancun science and technology city, no. 1, west 6th road, zhangdian district

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    110-82-7

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    China (Mainland)  |  Contact Details

    Business Type:Trading Company

    Tel:+86-25-83697070

    Address:Rm.902 Longyin Plaza, No. 217 Zhongshan Rd.(N) Nanjing 210009,China

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  • Casno:

    110-82-7

    Cyclohexane

    Min.Order: 1 Kilogram

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    Cyclohexane

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  • Cyclohexane

  • Casno:

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    Cyclohexane

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History

Unlike compounds like benzene, Cyclohexane (CAS NO.110-82-7) cannot easily be obtained from natural resources such as coal. Towards the end of the nineteenth century early chemical investigators had to depend on organic synthesis. It took them 30 years to flesh out the details.
In 1867 Marcellin Berthelot reduced benzene with hydroiodic acid at elevated temperatures. He incorrectly identified the reaction product as n-hexane not only because of the convenient match in boiling point (69°C) but also because he did not believe benzene was a cyclic molecule but rather some sort of association of acetylene.
In 1870 one of his sceptics Adolf von Baeyer repeated the reaction and pronounced the same reaction product hexahydrobenzene and in 1890 Vladimir Markovnikov believed he was able to distill the same compound from Caucasus petroleum calling his concoction hexanaphtene.
In 1894 Baeyer synthesized Cyclohexane (CAS NO.110-82-7) starting with a Dieckmann condensation of pimelic acid, and in the same year E. Haworth and W.H. Perkin Jr. (1860 - 1929) did the same in a Wurtz reaction of 1,6-dibromohexane.
Surprisingly their cyclohexanes(110-82-7) boiled higher by 10°C than either hexahydrobenzene or hexanaphtene but this riddle was solved in 1895 by Markovnikov, N.M. Kishner and Nikolay Zelinsky when they re-diagnosed hexahydrobenzene and hexanaphtene as methylcyclopentane, the result of an unexpected rearrangement reaction.

Consensus Reports

Community Right-To-Know List.

Standards and Recommendations

OSHA PEL: TWA 300 ppm
ACGIH TLV: TWA 100 ppm
DFG MAK: 200 ppm (720 mg/m3)
DOT Classification:  3; Label: Flammable Liquid

Analytical Methods

For occupational chemical analysis use NIOSH: Hydrocarbons.

Specification

The Cyclohexane is an organic compound with the formula C6H12. The IUPAC name of this chemical is cyclohexane. With the CAS registry number 110-82-7, the product's categories are Analytical Chemistry; Solvents for HPLC & Spectrophotometry; Solvents for Spectrophotometry; HPLC Solvents; Aluminum Bottles; Solvent Bottles; Solvents; Alpha Sort; C; CAlphabetic; CO - CZ; Volatiles/Semivolatiles; CO - CZChemical Class; Chemical Class; Hydrocarbons; NeatsAnalytical Standards ;C-D, Puriss p.a. ACS; Analytical Reagents for General Use; Puriss p.a. ACS; Amber Glass Bottles; Spectrophotometric Grade Solvents; Spectrophotometric GradeSolvents; Anhydrous Grade SolventsSolvents; AnhydrousSolvents; Returnable Container Solvents; Carbon Steel Cans with NPT Threads; ReagentPlus(R) Solvent Grade Products; ReagentPlus(R)Semi-Bulk Solvents; ReagentPlus(R)Solvents; Pesticide Residue Analysis (PRA) Solvents Solvent Bottles; PRA; ACS Grade Solvents; ACS GradeSemi-Bulk Solvents; ACS GradeSolvents; Chromatography/CE Reagents; Pestanal/Residue Analysis; Solvents - GC/SH; LC-MS Plus and Gradient; Spectroscopy; UV/Vis Solvents; UV/Visible (UV/VIS) Spectroscopy. Besides, it is colorless liquid, which should be stored in in a cool and well-ventilated place.

Physical properties about Cyclohexane are: (1)ACD/LogP: 3.16; (2)ACD/LogD (pH 5.5): 3.163; (3)ACD/LogD (pH 7.4): 3.163; (4)ACD/BCF (pH 5.5): 149.118; (5)ACD/BCF (pH 7.4): 149.118; (6)ACD/KOC (pH 5.5): 1251.474; (7)ACD/KOC (pH 7.4): 1251.474; (8)Index of Refraction: 1.433; (9)Molar Refractivity: 27.67 cm3; (10)Molar Volume: 106.454 cm3; (11)Polarizability: 10.969×10-24cm3; (12)Surface Tension: 25.943 dyne/cm; (13)Density: 0.791 g/cm3; (14)Enthalpy of Vaporization: 29.97 kJ/mol; (15)Boiling Point: 80.719 °C at 760 mmHg; (16)Vapour Pressure: 93.669 mmHg at 25°C.

Preparation: this chemical can be quantitatively produced from benzene by hydrogenation over either a nickel or a platinum catalyst at 210 °C  and 350 to 500 psi hydrogen. Several reactors may be used in series and the yield is over 99 percent.
C6H6 + 3H2 → C6H12

Uses of Cyclohexane: commercially most of cyclohexane produced is converted into cyclohexanone-cyclohexanol mixture (or "KA oil") by catalytic oxidation. KA oil is then used as a raw material for adipic acid and caprolactam. Practically, if the cyclohexanol content of KA oil is higher than cyclohexanone, it is more likely(economical) to be converted into adipic acid, and the reverse case, caprolactam production is more likely. Such ratio in KA oil can be controlled by selecting suitable oxidation catalyst. Some of cyclohexane is used as an organic solvent. Cyclohexane is also used for calibration of Differential scanning calorimetry (DSC) instruments, because of a convenient crystal-crystal transition at -87.1 C.

When you are using this chemical, please be cautious about it as the following:
It is highly flammable and toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Please keep away from sources of ignition - No smoking and take precautionary measures against static discharges. Besides, this chemical is irritating to skin and may cause lung damage if swallowed. When you are using it, avoid contact with eyes and avoid release to the environment. Refer to special instructions/safety data sheet. This material and its container must be disposed of as hazardous waste.

You can still convert the following datas into molecular structure:
(1)SMILES: C1CCCCC1
(2)InChI: InChI=1/C6H12/c1-2-4-6-5-3-1/h1-6H2
(3)InChIKey: XDTMQSROBMDMFD-UHFFFAOYAZ
(4)Std. InChI: InChI=1S/C6H12/c1-2-4-6-5-3-1/h1-6H2
(5)Std. InChIKey: XDTMQSROBMDMFD-UHFFFAOYSA-N

The toxicity data is as follows:

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mammal (species unspecified) LC50 inhalation 70gm/m3 (70000mg/m3)   Gigiena Truda i Professional'nye Zabolevaniya. Labor Hygiene and Occupational Diseases. Vol. 32(10), Pg. 25, 1988.
mouse LCLo inhalation 70gm/m3/2H (70000mg/m3)   "Toxicometric Parameters of Industrial Toxic Chemicals Under Single Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects, GKNT, 1982Vol. -, Pg. 41, 1982.
mouse LD50 oral 813mg/kg (813mg/kg)   Raw Material Data Handbook, Vol.1: Organic Solvents, 1974. Vol. 1, Pg. 17, 1974.
rabbit LCLo inhalation 89600mg/m3/1H (89600mg/m3) BEHAVIORAL: GENERAL ANESTHETIC

BEHAVIORAL: TREMOR

BEHAVIORAL: MUSCLE CONTRACTION OR SPASTICITY)
Journal of Industrial Hygiene and Toxicology. Vol. 25, Pg. 323, 1943.
rabbit LD skin > 180gm/kg (180000mg/kg)   Journal of Industrial Hygiene and Toxicology. Vol. 25, Pg. 199, 1943.
rabbit LDLo oral 5500mg/kg (5500mg/kg) GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" Journal of Industrial Hygiene and Toxicology. Vol. 25, Pg. 199, 1943.
rat LD50 oral 12705mg/kg (12705mg/kg)   Toxicology and Applied Pharmacology. Vol. 19, Pg. 699, 1971.