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Basic Information
CAS No.: 17015-08-6
Name: (2R,3R)-(-)-EPOXYSUCCINIC ACID
Molecular Structure:
Molecular Structure of 17015-08-6 ((2R,3R)-(-)-EPOXYSUCCINIC ACID)
Formula: C4H4 O5
Molecular Weight: 132.073
Synonyms: 2,3-Oxiranedicarboxylicacid, (2R-trans)-; Succinic acid, epoxy-, trans-(-)- (8CI);(-)-trans-2,3-Epoxysuccinic acid
Density: 1.920±0.06 g/cm3(Predicted)
Melting Point: 182-184 °C
Boiling Point: 467.5±45.0 °C(Predicted)
PSA: 87.13000
LogP: -1.07700
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Synthetic route
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trans-2,3-bis(ethoxycarbonyl)oxirane

17015-08-6

(2R,3R)-oxirane-2,3-dicarboxylic acid

Conditions
ConditionsYield
With potassium hydroxide In ethanol for 3h; Ambient temperature;93%
110-17-8

(2E)-but-2-enedioic acid

17015-08-6

(2R,3R)-oxirane-2,3-dicarboxylic acid

Conditions
ConditionsYield
With dihydrogen peroxide; sodium tungstate60%
141-36-6, 3272-11-5, 16533-72-5, 17015-08-6, 17087-75-1, 22734-83-4

DL-trans-epoxysuccinic acid

A

17087-75-1

(-)-trans-2,3-oxiranedicarboxylic acid

B

17015-08-6

(2R,3R)-oxirane-2,3-dicarboxylic acid

Conditions
ConditionsYield
Resolution of racemate;A 46%
B 41%
50-99-7

D-glucose

17015-08-6

(2R,3R)-oxirane-2,3-dicarboxylic acid

Conditions
ConditionsYield
mit Hilfe von Aspergillus fumigatus;
141-36-6, 3272-11-5, 16533-72-5, 17015-08-6, 17087-75-1, 22734-83-4

DL-trans-epoxysuccinic acid

17015-08-6

(2R,3R)-oxirane-2,3-dicarboxylic acid

Conditions
ConditionsYield
ueber das Morphin-Salz;
Yield given;
acetate of dimethyl ester of/the/ levorotatory β-chloro-malic acid I

acetate of dimethyl ester of/the/ levorotatory β-chloro-malic acid I

17015-08-6

(2R,3R)-oxirane-2,3-dicarboxylic acid

Conditions
ConditionsYield
With hydrogenchloride; methanol; water Behandeln des Reaktionsprodukts mit Natronlauge;
diethyl ester of/the/ levorotatory β-chloro-malic acid I

diethyl ester of/the/ levorotatory β-chloro-malic acid I

17015-08-6

(2R,3R)-oxirane-2,3-dicarboxylic acid

Conditions
ConditionsYield
With hydrogenchloride Behandeln mit verduennter Natronlauge;
74-89-5

methylamine

17015-08-6

(2R,3R)-oxirane-2,3-dicarboxylic acid

L-erythro-N(α)-methyl-3-hydroxy-L-aspartic acid

Conditions
ConditionsYield
In water Reflux;90%
17015-08-6

(2R,3R)-oxirane-2,3-dicarboxylic acid

7298-98-8

2-(S)-amino-3-(R)-hydroxysuccinic acid

Conditions
ConditionsYield
With ammonium hydroxide; water at 45 - 47℃; for 48h;82%
With ammonium hydroxide at 110℃; for 30h;42%
With ammonium hydroxide
77215-54-4

N-α-tert-butyloxycarbonyl-L-diaminopropanoic acid tert-butyl ester

17015-08-6

(2R,3R)-oxirane-2,3-dicarboxylic acid

1255383-49-3

Nβ-(R,R)-epoxysuccinoyl-DAP(BOC)-Otbu

Conditions
ConditionsYield
With 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; N-ethyl-N,N-diisopropylamine In N,N-dimethyl-formamide at 20℃; for 12h;79%
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