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1888-71-7

Basic Information
CAS No.: 1888-71-7
Name: 1-Propene,1,1,2,3,3,3-hexachloro-
Article Data: 35
Cas Database
Molecular Structure:
Molecular Structure of 1888-71-7 (1-Propene,1,1,2,3,3,3-hexachloro-)
Formula: C3Cl6
Molecular Weight: 248.751
Synonyms: Propene,hexachloro- (6CI,7CI,8CI); 1,1,1,2,3,3-Hexachloropropene; Hexachloro-1-propene;Hexachloropropene; Hexachloropropylene; NSC 7297; Perchloropropene;Perchloropropylene
EINECS: 217-560-9
Density: 1.765 g/mL at 25 °C(lit.)
Melting Point: -73°C
Boiling Point: 209-210 °C(lit.)
Flash Point: 209-210°C
Solubility:

Stability

    Stable. Incompatible with strong oxidizing agents.

Toxicology

    Harmful if swallowed, inhaled or absorbed through the skin.Lachrymator. Skin, eye and respiratory irritant. Repeated skin contactmay
Appearance: colourless liquid
Hazard Symbols: T
Risk Codes: R23; R36/37/38
Safety: A poison by inhalation and intraperitoneal routes. A powerful irritant. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl. See also CHLORINATED HYDROCARBONS, ALIPHATIC.
Transport Information: N/A
PSA: 0.00000
LogP: 4.24210
Synthetic route
594-89-8

1,1,1,2,2,3,3-heptachloropropane

1888-71-7

perchloropropene

Conditions
ConditionsYield
With methyl diethylphosphinate at 180℃; for 14.5h;56%
With potassium hydroxide
at 250 - 420℃;
131367-96-9

trichloro(heptachloropropyl)silane

1888-71-7

perchloropropene

Conditions
ConditionsYield
With aluminium trichloride at 160 - 180℃;52%
87651-34-1

pentachloro-2-(trimethylsiloxy)propene

A

75-77-4

chloro-trimethyl-silane

B

1768-31-6

pentachloroacetone

C

1888-71-7

perchloropropene

Conditions
ConditionsYield
With phosphorus pentachloride at 150℃; for 15h; Yields of byproduct given;A 52%
B n/a
C n/a
With phosphorus pentachloride at 150℃; for 15h; Yield given. Title compound not separated from byproducts;A 52%
B n/a
C n/a
67-66-3

chloroform

1888-71-7

perchloropropene

Conditions
ConditionsYield
With hydrogen
3849-33-0

1,1,1,2,3,3,3-heptachloropropane

1888-71-7

perchloropropene

Conditions
ConditionsYield
at 350℃;
815-15-6

2-fluoropentachloropropylene

1888-71-7

perchloropropene

Conditions
ConditionsYield
With aluminium trichloride
25290-40-8

heptachloro-butyraldehyde

1888-71-7

perchloropropene

Conditions
ConditionsYield
With sodium ethanolate
3228-99-7

pentaerythrityl tetrachloride

1888-71-7

perchloropropene

Conditions
ConditionsYield
With chlorine at 200℃; Irradiation;
594-90-1

octachloropropane

1888-71-7

perchloropropene

Conditions
ConditionsYield
With sodium hydroxide; N-benzyl-N,N,N-triethylammonium chloride In chloroform
18608-30-5

perchloroallene

1888-71-7

perchloropropene

Conditions
ConditionsYield
With chlorine In dichloromethane
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Chemistry

IUPAC Name: 1,1,2,3,3,3-Hexachloroprop-1-ene 
Molecular Formula: C3Cl6
Molecular Weight: 248.73g/mol
EINECS: 217-560-9
Transport information: UN 3382 6.1/PG 1
Properties colourless liquid
Density: 1.781 g/cm3 
Flash Point: 69.9 °C 
Boiling Point: 209.5 °C at 760 mmHg
Freely Rotating Bonds: 0
Polar Surface Area: 0 Å2
Index of Refraction: 1.554
Molar Refractivity: 44.75 cm3
Molar Volume: 139.6 cm3
Polarizability: 17.74 ×10-24 cm3
Surface Tension: 42.6 dyne/cm
Enthalpy of Vaporization: 42.76 kJ/mol
Vapour Pressure: 0.292 mmHg at 25°C 
Stability: stable,incompatible with strong oxidizing agents. 
Solubility: insoluble in water
The Cas Register Number of Hexachloropropene is 1888-71-7.The chemical synonyms of Hexachloropropene (CAS NO.1888-71-7) are 1,1,1,2,3,3-Hexachloropropene ; 1,1,2,3,3,3-Hexachloro-1-propen ; 1,1,2,3,3,3-Hexachloro-1-propene ; 1,1,2,3,3-Hexachloro-1-propene ; 1-Propene, hexachloro- ; 1-Propene,1,1,2,3,3,3-hexachloro ; 1-Propene,1,1,2,3,3,3-hexachloro- ; Hexachloro-1-propene .The molecular structure of Hexachloropropene (CAS NO.1888-71-7) is.

Uses

 Hexachloropropene (CAS NO.1888-71-7) is used as  plasticizer and hydraulic fluid .And it also is used in organic synthesis.

Production

Its raw materials are Potassium ethylate and 1,1,1,2,2,3,3-Heptachloropropane .

Toxicity Data With Reference

1.    

mmo-sat 15 µmol/L

    MUREAV    Mutation Research. 170 (1986),1.
2.    

ihl-rat LC50:425 ppm/30M

    XEURAQ    U.S. Atomic Energy Commission, University of Rochester, Research and Development Reports. (Rochester, NY) MDDC-1715 .
3.    

ipr-rat LD50:400 mg/kg

    XEURAQ    U.S. Atomic Energy Commission, University of Rochester, Research and Development Reports. (Rochester, NY) MDDC-1715 .
4.    

ihl-mus LCLo:300 ppm/30M

    XEURAQ    U.S. Atomic Energy Commission, University of Rochester, Research and Development Reports. (Rochester, NY) MDDC-1715 .
5.    

ipr-mus LDLo:64 mg/kg

    CBCCT*    “Summary Tables of Biological Tests“ National Research Council Chemical-Biological Coordination Center. 1 (1949),46.
6.    

ihl-rbt LCLo:85 ppm/30M

    XEURAQ    U.S. Atomic Energy Commission, University of Rochester, Research and Development Reports. (Rochester, NY) MDDC-1715 .

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

A poison by inhalation and intraperitoneal routes. A powerful irritant. Mutation data reported. When heated to decomposition it emits toxic fumes of Cl. See also CHLORINATED HYDROCARBONS, ALIPHATIC.
Hazard Codes: ToxicT
Risk Statements: 23-36/37/38 
R23: Toxic by inhalation. 
R36/37/38: Irritating to eyes, respiratory system and skin.
Safety Statements: 26-36/37/39-45 
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection. 
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)