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CAS No.: | 1923-70-2 |
---|---|
Name: | Tetrabutylammonium perchlorate |
Article Data: | 22 |
Molecular Structure: | |
Formula: | C16H36N.ClO4 |
Molecular Weight: | 341.919 |
Synonyms: | Ammonium, tetrabutyl-, perchlorate;1-Butanaminium, N,N,N-tributyl-, perchlorate;Tetrabutyl ammonium perchlorate;Tetra-n-butylammonium perchlorate; |
EINECS: | 217-655-5 |
Density: | 1.0387 (rough estimate) |
Melting Point: | 211-215 °C |
Solubility: | acetonitrile: 0.1 g/mL, clear, colorless |
Appearance: | white powder |
Hazard Symbols: | O, Xi |
Risk Codes: | 5-8-36/37/38 |
Safety: | 17-26-36-36/37/39 |
Transport Information: | UN 1479 5.1/PG 2 |
PSA: | 74.27000 |
LogP: | 5.21790 |
Conditions | Yield |
---|---|
With trimethyl phosphite; perchloric acid at 0 - 60℃; for 15h; Inert atmosphere; neat (no solvent); | 95% |
With perchloric acid | |
With perchloric acid | |
With perchloric acid |
(NBu4)2{palladium(μ-Br)bis(pentafluorophenyl)}2
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In tetrahydrofuran byproducts: AgCl; Addn. of AgClO4 to soln. of Pd-complex under N2, stirring (room temp., 20 min).; Evapn. of suspn. to dryness, extg. of residue (diethyl ether), evapn., addn. of n-hexane.; | A 90% B n/a |
Conditions | Yield |
---|---|
In dichloromethane AgClO4 added to (NBu4)(Au(C6Cl5)2) in dichloromethane and stirred at room temp. for 6 h;; ppt. filtered off and washed with diethylether; elem. anal.; | A 90% B n/a |
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In diethyl ether stirred at room temp. for 8 h; filtered off (N(C4H9)4)(ClO4), soln. concd., addn. of n-hexane, pptn.; elem. anal.; | A 85% B n/a |
(NBu4)2{palladium(μ-Br)bis(pentachlorophenyl)}2
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In tetrahydrofuran byproducts: AgCl; Addn. of AgClO4 to soln. of Pd-complex under N2, stirring (room temp., 20 min).; Evapn. of suspn. to dryness, extg. of residue (diethyl ether), evapn., addn. of n-hexane.; | A 80% B n/a |
Conditions | Yield |
---|---|
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, room temp., 5 min; evapn. to dryness, treated with Et2O, filtration, evapn. to dryness, washeed with hexane, dried in vac.; | A 80% B n/a |
Conditions | Yield |
---|---|
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, room temp., 5 min; evapn. to dryness, treated with Et2O, filtration, evapn. to dryness, washed with hexane, elem. anal.; | A 79% B n/a |
perchlorato(triphenylphosphane)silver(I)
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, washing with i-PrOH, elem. anal.; | A 78% B n/a |
perchlorato(triphenylphosphane)silver(I)
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In dichloromethane exclusion of light; addn. of Ag-compd. to soln. of Pt-compd. in CH2Cl2 (molar ratio Pt-compd./Ag-compd. 1:1), stirring (room temp., 1 h); evapn., treatment with cold MeOH (0°C), filtn., washing (MeOH); elem. anal.; | A 77% B n/a |
perchlorato(triphenylphosphane)silver(I)
B
tetrabutylammonium perchlorate
Conditions | Yield |
---|---|
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, extn. with Et2O, filtration, evapn. to dryness, treated with hexane, elem. anal.; | A 77% B n/a |
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The Tetrabutylammonium perchlorate is an organic compound with the formula C16H36N.ClO4. The systematic name of this chemical is N,N,N-tributylbutan-1-aminium perchlorate. With the CAS registry number 1923-70-2, it is also named as Ammonium, tetrabutyl-, perchlorate. The product's categories are Ammonium Polyhalides, etc. (Quaternary); Oxidation; Quaternary Ammonium Compounds; Synthetic Organic Chemistry; Detergents A to ZSynthetic Reagents; Detergents; Perchlorates; Ammonium SaltsSynthetic Reagents; Greener Alternatives: Catalysis; Phase Transfer Catalysts; Ammonium SaltsAnalytical Reagents; Electrochemistry; Supporting Electrolytes for Electrochemistry. Besides, it should be stored in a closed cool and dry place.
Physical properties about Tetrabutylammonium perchlorate are: (1)ACD/LogP: -1.72; (2)ACD/LogD (pH 5.5): -1.72; (3)ACD/LogD (pH 7.4): -1.72; (4)ACD/BCF (pH 5.5): 1; (5)ACD/BCF (pH 7.4): 1; (6)ACD/KOC (pH 5.5): 2.78; (7)ACD/KOC (pH 7.4): 2.78; (8)#H bond acceptors: 1; (9)#Freely Rotating Bonds: 12.
When you are using this chemical, please be cautious about it as the following:
It contacts with combustible material may cause fire. Please keep away from combustible material. Besides, this chemical is irritating to eyes, respiratory system and skin. When you are using it, wear suitable gloves and eye/face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
You can still convert the following datas into molecular structure:
(1)SMILES: [O-]Cl(=O)(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC
(2)InChI: InChI=1/C16H36N.ClHO4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;(H,2,3,4,5)/q+1;/p-1
(3)InChIKey: KBLZDCFTQSIIOH-REWHXWOFAG
(4)Std. InChI: InChI=1S/C16H36N.ClHO4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;(H,2,3,4,5)/q+1;/p-1
(5)Std. InChIKey: KBLZDCFTQSIIOH-UHFFFAOYSA-M