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Tetrabutylammonium perchlorate
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Name

Tetrabutylammonium perchlorate

 EINECS 217-655-5
CAS No. 1923-70-2 Density 1.0387 (rough estimate)
PSA 74.27000 LogP 5.21790
Solubility acetonitrile: 0.1 g/mL, clear, colorless Melting Point 211-215 °C
Formula C16H36N.ClO4 Boiling Point N/A
Molecular Weight 341.919 Flash Point N/A
Transport Information UN 1479 5.1/PG 2 Appearance white powder
Safety 17-26-36-36/37/39 Risk Codes 5-8-36/37/38
Molecular Structure Molecular Structure of 1923-70-2 (Tetrabutylammonium perchlorate) Hazard Symbols OxidizingO, IrritantXi
Synonyms

Ammonium, tetrabutyl-, perchlorate;1-Butanaminium, N,N,N-tributyl-, perchlorate;Tetrabutyl ammonium perchlorate;Tetra-n-butylammonium perchlorate;

Article Data 22

Tetrabutylammonium perchlorate Synthetic route

1643-19-2

tetrabutylammomium bromide

1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
With trimethyl phosphite; perchloric acid at 0 - 60℃; for 15h; Inert atmosphere; neat (no solvent);95%
With perchloric acid
With perchloric acid
With perchloric acid
74436-10-5

(NBu4)2{palladium(μ-Br)bis(pentafluorophenyl)}2

silver perchlorate

cis-[Pd(pentafluorophenyl)2(THF)2]

B

1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In tetrahydrofuran byproducts: AgCl; Addn. of AgClO4 to soln. of Pd-complex under N2, stirring (room temp., 20 min).; Evapn. of suspn. to dryness, extg. of residue (diethyl ether), evapn., addn. of n-hexane.;A 90%
B n/a

N-n-Bu4{Au(C6Cl5)2}

silver perchlorate

A

[{Au(C6Cl5)2}Ag]n

B

1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In dichloromethane AgClO4 added to (NBu4)(Au(C6Cl5)2) in dichloromethane and stirred at room temp. for 6 h;; ppt. filtered off and washed with diethylether; elem. anal.;A 90%
B n/a

NBu4[Ag(C6F5)2]

{Ag(CH2P(C6H5)3)2}(1+)*ClO4(1-)={Ag(CH2P(C6H5)3)2}ClO4

A

{Ag(C6F5)(CH2P(C6H5)3)}

B

1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In diethyl ether stirred at room temp. for 8 h; filtered off (N(C4H9)4)(ClO4), soln. concd., addn. of n-hexane, pptn.; elem. anal.;A 85%
B n/a
86392-02-1

(NBu4)2{palladium(μ-Br)bis(pentachlorophenyl)}2

silver perchlorate

cis-[Pd(C6Cl5)2(thf)2]

B

1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In tetrahydrofuran byproducts: AgCl; Addn. of AgClO4 to soln. of Pd-complex under N2, stirring (room temp., 20 min).; Evapn. of suspn. to dryness, extg. of residue (diethyl ether), evapn., addn. of n-hexane.;A 80%
B n/a

{NBu4}{Pt(pentafluorophenyl)4}

1020072-44-9, 132018-77-0

[Ag(OClO3)(tetrahydrothiophene)]

tetrabutylammonium tetrakis(pentafluorophenyl)-1κ4C1-tetrahydrothiophene-2κS-platinumargentate (Ag-Pt)

B

1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, room temp., 5 min; evapn. to dryness, treated with Et2O, filtration, evapn. to dryness, washeed with hexane, dried in vac.;A 80%
B n/a

{NBu4}{Pt(pentafluorophenyl)4}

137400-80-7

{Ag(tetrahydrothiophene)}ClO4

tetrabutylammonium tetrakis(pentafluorophenyl)-1κ4C1-tetrahydrothiophene-2κS-platinumargentate (Ag-Pt)

B

1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, room temp., 5 min; evapn. to dryness, treated with Et2O, filtration, evapn. to dryness, washed with hexane, elem. anal.;A 79%
B n/a
73165-02-3, 623171-38-0

perchlorato(triphenylphosphane)silver(I)

{(C4H9)4N}{cis-Pt(C6F5)2(C6Cl5)(tetrahydrothiophene)}

(C4H8S)(C6Cl5)(C6F5)2PtAg(P(C6H5)3)

B

1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, washing with i-PrOH, elem. anal.;A 78%
B n/a

(NBu4)2{trans-PtCl2(C6Cl5)2}

73165-02-3, 623171-38-0

perchlorato(triphenylphosphane)silver(I)

A

N(C4H9)4(1+)*PtAgCl2(C6Cl5)2(P(C6H5)3)(1-) = (N(C4H9)4){PtAgCl2(C6Cl5)2(P(C6H5)3)}

B

1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In dichloromethane exclusion of light; addn. of Ag-compd. to soln. of Pt-compd. in CH2Cl2 (molar ratio Pt-compd./Ag-compd. 1:1), stirring (room temp., 1 h); evapn., treatment with cold MeOH (0°C), filtn., washing (MeOH); elem. anal.;A 77%
B n/a
73165-02-3, 623171-38-0

perchlorato(triphenylphosphane)silver(I)

{(C4H9)4N}{cis-Pt(C6F5)(C6Cl5)2(triphenylphosphine)}

((C6H5)3P)(C6Cl5)2(C6F5)PtAg(P(C6H5)3)

B

1923-70-2

tetrabutylammonium perchlorate

Conditions
ConditionsYield
In dichloromethane with exclusion of light, molar ratio of starting materials is 1:1, 0°C, 30 min; evapn. to dryness, extn. with Et2O, filtration, evapn. to dryness, treated with hexane, elem. anal.;A 77%
B n/a

Tetrabutylammonium perchlorate Specification

The Tetrabutylammonium perchlorate is an organic compound with the formula C16H36N.ClO4. The systematic name of this chemical is N,N,N-tributylbutan-1-aminium perchlorate. With the CAS registry number 1923-70-2, it is also named as Ammonium, tetrabutyl-, perchlorate. The product's categories are Ammonium Polyhalides, etc. (Quaternary); Oxidation; Quaternary Ammonium Compounds; Synthetic Organic Chemistry; Detergents A to ZSynthetic Reagents; Detergents; Perchlorates; Ammonium SaltsSynthetic Reagents; Greener Alternatives: Catalysis; Phase Transfer Catalysts; Ammonium SaltsAnalytical Reagents; Electrochemistry; Supporting Electrolytes for Electrochemistry. Besides, it should be stored in a closed cool and dry place.

Physical properties about Tetrabutylammonium perchlorate are: (1)ACD/LogP: -1.72; (2)ACD/LogD (pH 5.5): -1.72; (3)ACD/LogD (pH 7.4): -1.72; (4)ACD/BCF (pH 5.5): 1; (5)ACD/BCF (pH 7.4): 1; (6)ACD/KOC (pH 5.5): 2.78; (7)ACD/KOC (pH 7.4): 2.78; (8)#H bond acceptors: 1; (9)#Freely Rotating Bonds: 12.

When you are using this chemical, please be cautious about it as the following:
It contacts with combustible material may cause fire. Please keep away from combustible material. Besides, this chemical is irritating to eyes, respiratory system and skin. When you are using it, wear suitable gloves and eye/face protection. In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

You can still convert the following datas into molecular structure:
(1)SMILES: [O-]Cl(=O)(=O)=O.CCCC[N+](CCCC)(CCCC)CCCC
(2)InChI: InChI=1/C16H36N.ClHO4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;(H,2,3,4,5)/q+1;/p-1
(3)InChIKey: KBLZDCFTQSIIOH-REWHXWOFAG
(4)Std. InChI: InChI=1S/C16H36N.ClHO4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;(H,2,3,4,5)/q+1;/p-1
(5)Std. InChIKey: KBLZDCFTQSIIOH-UHFFFAOYSA-M

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