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CAS No.: | 19597-69-4 |
---|---|
Name: | LITHIUM AZIDE |
Article Data: | 22 |
Molecular Structure: | |
Formula: | LiN3 |
Molecular Weight: | 48.9611 |
Synonyms: | Lithiumazide (6CI,7CI,8CI) |
Density: | g/cm3 |
Melting Point: | decomposes at 115–298℃ [CRC10] |
Boiling Point: | °Cat760mmHg |
Flash Point: | °C |
Solubility: | g/100g H2O: 61.3 (0°C), 67.2 (20°C), 86.6 (60°C) [LAN05] |
Hazard Symbols: | |
Risk Codes: | 26/27/28-32 |
Safety: | The moist or dry salt explodes when heated to 115-298°C. Forms very shock-sensitive explosive mixtures with alkyl nitrates or dimethylformamide above 200°C. Incompatible with CS2. When heated to decomposition it emits very toxic fumes of Li2O and NOx. See also AZIDES and LITHIUM COMPOUNDS. |
PSA: | 49.75000 |
LogP: | 0.21376 |
Molecular Structure of Lithium azide (CAS NO. 19597-69-4):
EINECS: 243-177-1
IUPAC Name: Lithium azide
Molecular Formula: LiN3
Molecular Weight: 48.961100 g/mol
H-Bond Donor: 0
H-Bond Acceptor: 2
Canonical SMILES: [Li+].[N-]=[N+]=[N-]
InChI: InChI=1S/Li.N3/c;1-3-2/q+1;-1
InChIKey: GUWHRJQTTVADPB-UHFFFAOYSA-N
Density: 1.088 g/mL at 25 °C
Boiling Point: 103 °C
Safety Information of Lithium azide (CAS NO. 19597-69-4):
Hazard Codes: T+
Risk Statements: 26/27/28-32
R26/27/28:Very toxic by inhalation, in contact with skin and if swallowed
R32:Contact with acid liberates very toxic gas
Safety Statements: 23-36/37/39-45
S23:Do not breathe vapour
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 3287 6.1/PG 2
HazardClass: 4.1
The moist or dry salt explodes when heated to 115-298°C. Forms very shock-sensitive explosive mixtures with alkyl nitrates or dimethylformamide above 200°C. Incompatible with CS2. When heated to decomposition it emits very toxic fumes of Li2O and NOx. See also AZIDES and LITHIUM COMPOUNDS.
Lithium azide with cas registry number of 19597-69-4 is clear colorless solution, also known as Lithium azide (Li(N3)) ; Lithium triazide .