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CAS No.: | 10024-97-2 |
---|---|
Name: | NITROUS OXIDE |
Article Data: | 1290 |
Molecular Structure: | |
Formula: | N2O |
Molecular Weight: | 44.0134 |
Synonyms: | Dinitrogenmonoxide;Dinitrogen oxide;Dinitrogen oxide (N2O);Factitious air;Hyponitrousacid anhydride;Laughing gas;Nitrous oxide;R 744A;? Nitrous oxide; |
EINECS: | 233-032-0 |
Density: | 1.469 g/cm3 |
Melting Point: | -91 °C(lit.) |
Boiling Point: | -88 °C(lit.) |
Solubility: | 670,000 mg l-1 |
Appearance: | Colourless gas with sweetish odour |
Hazard Symbols: | O |
Risk Codes: | 8 |
Safety: | 38 |
Transport Information: | UN 1070 2.2 |
PSA: | 54.46000 |
LogP: | 0.06366 |
ammonia
oxygen
A
nitrogen
B
nitrogen(II) oxide
C
dinitrogen monoxide
Conditions | Yield |
---|---|
With oxygen In neat (no solvent) Fe-ZSM-5 catalyst prepared by ion exchange and heat-treated at 400, 425or 450 °C, 100 % NH3 conversion, 100 % N2 selectivity, 1000 ppm NH3 in 2 % O2-contg. He; | A 100% B 0% C 0% |
With catalyst:Fe-mordenite In neat (no solvent) Fe-mordenite catalyst prepared by ion exchange and heat-treated at 425 °C, 92 % NH3 conversion, 99 % N2 selectivity, 1000 ppm NH3 in 2 %O2-contg. He; | A 92% B n/a C 0% |
With catalyst:Fe-ZSM-5 In neat (no solvent) Fe-ZSM-5 catalyst prepared by ion exchange and heat-treated at 375 °C, 90 % NH3 conversion, 99 % N2 selectivity, 1000 ppm NH3 in 2 % O2-contg. He; | A 90% B n/a C 0% |
dinitrogen monoxide
Conditions | Yield |
---|---|
With cobaltocene In dichloromethane at 20℃; for 0.0166667h; Kinetics; Time; Temperature; Concentration; | 100% |
Conditions | Yield |
---|---|
With oxygen In neat (no solvent) Fe-mordenite catalyst prepared by ion exchange and heat-treated at 450 °C, 99 % NH3 conversion, 100 % N2 selectivity, 1000 ppm NH3 in 2 % O2-contg. He; | A 99% B 0% C 0% |
With oxygen; platinum high excess O2,500 °C; | A <1 B n/a C n/a |
With oxygen; platinum at 300 °C; | A n/a B <9 C n/a |
[CuI(tris(2-pyridylmethyl)amine)(CH3CN)]2+
nitrogen(II) oxide
A
[Cu(tris(2-pyridylmethyl)amine)(H2O)](2+)
B
dinitrogen monoxide
Conditions | Yield |
---|---|
In water room temp., pH = 7.0; reaction followed by gas chromy.; | A 99% B n/a |
A
nitrogen
B
nitrogen(II) oxide
C
Nitrogen dioxide
D
dinitrogen monoxide
Conditions | Yield |
---|---|
at 220-260°C, nearly 98% N2O, 2% N2; troces of NO and NO2 (0.001%); | A 2% B n/a C n/a D 98% |
trifluoromethyldifluorophosphine
nitrogen(II) oxide
A
Trifluormethylphosphonsaeuredifluorid
B
dinitrogen monoxide
Conditions | Yield |
---|---|
20°C (7 d); oxydation; | A 98% B n/a |
nitrogen(II) oxide
A
[copper(I)(tris(2-pyridylmethyl)amine)](1+)
C
dinitrogen monoxide
Conditions | Yield |
---|---|
In tetrahydrofuran; methanol for 8h; Solvent; Inert atmosphere; Schlenk technique; | A 96% B 85% C 98% |
B
dinitrogen monoxide
Conditions | Yield |
---|---|
With P(C6H5)3 In not given byproducts: OP(C6H5)3; react. of 1 equiv. N(C4H9)4(NO2) with (Cu2(NO)N6OC36H39)(2+) in presence of P(C6H5)3 (1 equiv.);; elem. anal.; | A 60% B 97% |
In not given byproducts: O2; react. of 1 equiv. N(C4H9)4(NO2) with (Cu2(NO)N6OC36H39)(2+);; elem. anal.; | A 60% B 79% |
Cu2(I)(C6H3(O)(CH2N(C2H4-2-pyridyl)2)2)(1+)
nitrogen(II) oxide
B
dinitrogen monoxide
Conditions | Yield |
---|---|
In dichloromethane exposure of (Cu2N6OC36H39)(1+) to NO(g) in CH2Cl2 at -80 °C, warming;; | A 55% B 96% |
nitric acid
B
water
C
Nitrogen dioxide
D
nitrosylchloride
E
dinitrogen monoxide
Conditions | Yield |
---|---|
In nitric acid byproducts: Cl2; to Ru complex was added concd. HNO3; mixt. heated under reflux for 5 min; cooled to room temp.; ppt. filtered off; washed (water, alc., ether); dried (vac.); recrystd. (aq. HNO3); elem. anal.; | A 95% B n/a C n/a D n/a E n/a |
IUPAC Name: Nitrous oxide
Molecular formula: N2O
Molar mass: 44.01
EINECS: 233-032-0
Appearance: colorless gas
Index of Refraction: 1.469
Molar Refractivity: 8.35 cm3
Molar Volume: 29.9 cm3
Surface Tension: 70.7 dyne/cm
Density: 1.46 g/cm3
Melting point: -90.86 °C (182.29 K)
Boiling point: -88.48 °C (184.67 K)
Solubility in water: 0.15 g/100 ml (15 °C)
Stability: Oxidant, strongly supports combustion. May react violently with some materials. Thermal decomposition yields toxic products. Incompatible with aluminium, boron oxides, hydrazine, strong reducing agents.
log P: 0.35
Vapor pressure: 5150 kPa (20 °C)
Classification Code of Nitrous oxide (CAS NO.10024-97-2): Analgesics; Analgesics, non-narcotic; Anesthetic [inhalation]; Anesthetics; Anesthetics, General; Anesthetics, inhalation; Central Nervous System Agents; Central Nervous System Depressants; Human Data; Mutation data; Peripheral Nervous System Agents; Reproductive Effect; Sensory System Agents; Tumor data
In the year 1775, Nitrous oxide (CAS NO.10024-97-2) was first synthesized by English chemist and natural philosopher Joseph Priestley,who called it phlogisticated nitrous air. Priestley describes the preparation of "nitrous air diminished" by heating iron filings dampened with nitric acid in Experiments and Observations on Different Kinds of Air (1775).
Humphry Davy in the 1790s tested the gas on himself and some of his friends, including the poet Samuel Taylor Coleridge. They realized that Nitrous oxide (CAS NO.10024-97-2) considerably dulled the sensation of pain, even if the inhaler were still semi-conscious. After it was publicized extensively by Gardner Quincy Colton in the United States in the 1840s, it came into use as an anaesthetic, particularly by dentists, who do not typically have access to the services of an anesthesiologist and who may benefit from a patient who can respond to verbal commands.
Nitrous oxide (CAS NO.10024-97-2) is used in surgery and dentistry for its anesthetic and analgesic effects. It is also used as an oxidizer in rocketry and in motor racing to increase the power output of engines.
Nitrous oxide(10024-97-2) is manufactured by heating very pure ammonium nitrate to 200 to 260 °C in aluminum retorts,
NH4NO3 → N2O + 2H2
It is purified by treatment with caustic to remove nitric acid and with dichromate to remove nitric oxide.
1. | sln-dmg-ihl 99 pph/6M-C | ENVRAL Environmental Research. 7 (1974),286. | ||
2. | dni-rat-ihl 75,000 ppm/24H AACRAT 62,738,83 | |||
3. | ihl-hmn TDLo:24 mg/kg/2H:CNS,CVS,MET | BJANAD British Journal of Anesthesia. 35 (1963),631. | ||
4. | ihl-rat LC50:160 mg/m3/6H | GISAAA Gigiena i Sanitariya. 50 (4)(1985),89. | ||
5. | ihl-rat TCLo:30 mg/m3/6H/61D-I | GISAAA Gigiena i Sanitariya. 50 (4)(1985),89. | ||
6. | ihl-rat TCLo:14 mg/m3/6H/17W-I | GISAAA Gigiena i Sanitariya. 50 (4)(1985),89. | ||
7. | ihl-mus TCLo:50 ppm/6H/13W-I | TXCYAC Toxicology. 6 (1990),57. |
Reported in EPA TSCA Inventory. EPA Genetic Toxicology Program.
Moderately toxic by inhalation. Human systemic effects by inhalation: general anesthetic, decreased pulse rate without blood pressure fall, and body temperature decrease. An experimental teratogen. Experimental reproductive effects. Mutation data reported. An asphyxiant. Does not burn but is flammable by chemical reaction and supports combustion. Moderate explosion hazard; it can form an explosive mixture with air. Violent reaction with Al, B, hydrazine, LiH, LiC6H5, PH3, Na, tungsten carbide. Also self-explodes at high temperatures.
Hazard Codes:O
Risk Statements: 8
R8: Contact with combustible material may cause fire
Safety Statements: 38
S38: In case of insufficient ventilation, wear suitable respiratory equipment
F: 4.5-31: Do not heat over 50 °C. Do not puncture.
RIDADR: UN 1070 2.2
WGK Germany: 1
HazardClass: 2.2
RTECS: QX1350000
OSHA PEL: OSHA PEL (Shipyard): Simple asphyxiant-inert gas and vapor
ACGIH TLV: 50 ppm; Not Classifiable as a Human Carcinogen
DFG MAK: 100 ppm (180 mg/m3)
NIOSH REL: (Waste Anesthetic Gases and Vapors) TWA 25 ppm
DOT Classification: 2.2; Label: Nonflammable Gas
For occupational chemical analysis use NIOSH: Nitrous Oxide (Field-Readable), 6600.
Nitrous oxide (CAS NO.10024-97-2), its Synonyms are Dinitrogen monoxide ; Dinitrogen oxide ; Hyponitrous acid anhydride ; Laughing gas ; Nitrogen hypoxide ; Nitrogen monoxide ; Nitrous oxide, compressed ; Nitrous oxide, refrigerated liquid ; Oxido nitroso . It is a colorless non-flammable gas, with a pleasant, slightly sweet odor and taste.