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Basic Information
CAS No.: 25152-83-4
Name: decadienal,(E,Z)-2,4-decadienal
Molecular Structure:
Molecular Structure of 25152-83-4 (decadienal,(E,Z)-2,4-decadienal)
Formula: C10H16 O
Molecular Weight: 152.236
Synonyms: 2,4-Decadienal,(E,Z)- (8CI); (2E,4Z)-2,4-Decadienal; (2E,4Z)-Decadienal;(E,Z)-2,4-Decadienal; 2-trans,4-cis-Decadienal; trans,cis-2,4-Decadienal;trans-2,cis-4-Decadienal
Density: 0.854g/cm3
Boiling Point: 244.6°Cat760mmHg
Flash Point: 102.3°C
PSA: 17.07000
LogP: 2.87800
Synthetic route
119239-12-2

(3E,5Z)-undeca-3,5-diene-1,2-diol

25152-83-4

(2E,4Z)-2,4-decadienal

Conditions
ConditionsYield
With sodium periodate In tetrahydrofuran for 1h; Ambient temperature;82%
168295-36-1

(2E,4Z)-5-iodopenta-2,4-dienal

308796-10-3

1-pentylzinc bromide

25152-83-4

(2E,4Z)-2,4-decadienal

Conditions
ConditionsYield
With cobalt acetylacetonate; lithium bromide In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at -30 - 0℃; for 0.25h;81%
16195-71-4

(2E,4Z)-2,4-decadien-1-ol

25152-83-4

(2E,4Z)-2,4-decadienal

Conditions
ConditionsYield
With manganese(IV) oxide In hexane for 1.5h; Ambient temperature;72.8%
16195-71-4

(2E,4Z)-2,4-decadien-1-ol

A

25152-84-5

2,4-trans,trans-decadienal

B

25152-83-4

(2E,4Z)-2,4-decadienal

Conditions
ConditionsYield
With manganese(IV) oxide In Petroleum ether at 25℃; for 1.5h; Yield given;A 12%
B n/a
25073-24-9

3t-oxiranyl-propenal

4762-26-9

hexyltriphenylphosphonium bromide

25152-83-4

(2E,4Z)-2,4-decadienal

Conditions
ConditionsYield
(i) nBuLi, hexane, Et2O, (ii) /BRN= 1341082/, (iii) HIO4; Multistep reaction;
16195-71-4

(2E,4Z)-2,4-decadien-1-ol

A

25152-83-4

(2E,4Z)-2,4-decadienal

B

[((Z)-3-Hept-1-enyl)-oxiranyl]-methanol

(2E,4RS,5RS)-(±)-4,5-epoxy-(E)-2-decenal

cis-4,5-epoxy-(E)-2-decenal

Conditions
ConditionsYield
With sodium hypochlorite; 4-Phenylpyridine 1-oxide; (salen)-Mn(III) In dichloromethane at 0℃; Yields of byproduct given;
With sodium hypochlorite; 4-Phenylpyridine 1-oxide; (salen)-Mn(III) In dichloromethane at 0℃; Yield given. Yields of byproduct given;
4885-02-3

Dichloromethyl methyl ether

120501-75-9

(1E,3Z)-1-trimethylsilyl-1,3-nonadiene

25152-83-4

(2E,4Z)-2,4-decadienal

Conditions
ConditionsYield
With methanol; titanium tetrachloride 1.) CH2Cl2, -78 deg C, 1 h and 20 min, 2.) -20 deg C; Yield given. Multistep reaction;
66-25-1

hexanal

129422-73-7

(5-aza-5-cyclohexylpenta-2,4-dienyl)diethoxyphosphin-1-one

A

25152-84-5

2,4-trans,trans-decadienal

B

25152-83-4

(2E,4Z)-2,4-decadienal

C

5910-88-3

(2Z,4E)-deca-2,4-dienal

Conditions
ConditionsYield
With lithium diisopropyl amide In tetrahydrofuran; hexane 1.) -78 deg C, 1 h, 2.) 25 deg C, 2 h; Yield given;
With lithium diisopropyl amide In tetrahydrofuran; hexane 1.) -78 deg C, 1 h, 2.) 25 deg C, 2 h; Yield given. Yields of byproduct given;
42482-14-4

(E,Z)-nona-1,3-dienyloxirane

25152-83-4

(2E,4Z)-2,4-decadienal

Conditions
ConditionsYield
With sodium periodate In tetrahydrofuran; water

(2E,4E/Z)-1,1-Dimethoxy-2,4-decadiene

A

25152-84-5

2,4-trans,trans-decadienal

B

25152-83-4

(2E,4Z)-2,4-decadienal

Conditions
ConditionsYield
With toluene-4-sulfonic acid In acetone for 0.25h; Title compound not separated from byproducts;
With toluene-4-sulfonic acid In water; acetone at 20℃; for 0.166667h;
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