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CAS No.: | 25152-83-4 |
---|---|
Name: | decadienal,(E,Z)-2,4-decadienal |
Article Data: | 15 |
Molecular Structure: | |
Formula: | C10H16 O |
Molecular Weight: | 152.236 |
Synonyms: | 2,4-Decadienal,(E,Z)- (8CI); (2E,4Z)-2,4-Decadienal; (2E,4Z)-Decadienal;(E,Z)-2,4-Decadienal; 2-trans,4-cis-Decadienal; trans,cis-2,4-Decadienal;trans-2,cis-4-Decadienal |
Density: | 0.854g/cm3 |
Boiling Point: | 244.6°Cat760mmHg |
Flash Point: | 102.3°C |
PSA: | 17.07000 |
LogP: | 2.87800 |
(3E,5Z)-undeca-3,5-diene-1,2-diol
(2E,4Z)-2,4-decadienal
Conditions | Yield |
---|---|
With sodium periodate In tetrahydrofuran for 1h; Ambient temperature; | 82% |
(2E,4Z)-5-iodopenta-2,4-dienal
1-pentylzinc bromide
(2E,4Z)-2,4-decadienal
Conditions | Yield |
---|---|
With cobalt acetylacetonate; lithium bromide In tetrahydrofuran; 1-methyl-pyrrolidin-2-one at -30 - 0℃; for 0.25h; | 81% |
(2E,4Z)-2,4-decadien-1-ol
(2E,4Z)-2,4-decadienal
Conditions | Yield |
---|---|
With manganese(IV) oxide In hexane for 1.5h; Ambient temperature; | 72.8% |
(2E,4Z)-2,4-decadien-1-ol
A
2,4-trans,trans-decadienal
B
(2E,4Z)-2,4-decadienal
Conditions | Yield |
---|---|
With manganese(IV) oxide In Petroleum ether at 25℃; for 1.5h; Yield given; | A 12% B n/a |
3t-oxiranyl-propenal
hexyltriphenylphosphonium bromide
(2E,4Z)-2,4-decadienal
Conditions | Yield |
---|---|
(i) nBuLi, hexane, Et2O, (ii) /BRN= 1341082/, (iii) HIO4; Multistep reaction; |
(2E,4Z)-2,4-decadien-1-ol
A
(2E,4Z)-2,4-decadienal
Conditions | Yield |
---|---|
With sodium hypochlorite; 4-Phenylpyridine 1-oxide; (salen)-Mn(III) In dichloromethane at 0℃; Yields of byproduct given; | |
With sodium hypochlorite; 4-Phenylpyridine 1-oxide; (salen)-Mn(III) In dichloromethane at 0℃; Yield given. Yields of byproduct given; |
Dichloromethyl methyl ether
(1E,3Z)-1-trimethylsilyl-1,3-nonadiene
(2E,4Z)-2,4-decadienal
Conditions | Yield |
---|---|
With methanol; titanium tetrachloride 1.) CH2Cl2, -78 deg C, 1 h and 20 min, 2.) -20 deg C; Yield given. Multistep reaction; |
hexanal
(5-aza-5-cyclohexylpenta-2,4-dienyl)diethoxyphosphin-1-one
A
2,4-trans,trans-decadienal
B
(2E,4Z)-2,4-decadienal
C
(2Z,4E)-deca-2,4-dienal
Conditions | Yield |
---|---|
With lithium diisopropyl amide In tetrahydrofuran; hexane 1.) -78 deg C, 1 h, 2.) 25 deg C, 2 h; Yield given; | |
With lithium diisopropyl amide In tetrahydrofuran; hexane 1.) -78 deg C, 1 h, 2.) 25 deg C, 2 h; Yield given. Yields of byproduct given; |
(E,Z)-nona-1,3-dienyloxirane
(2E,4Z)-2,4-decadienal
Conditions | Yield |
---|---|
With sodium periodate In tetrahydrofuran; water |
A
2,4-trans,trans-decadienal
B
(2E,4Z)-2,4-decadienal
Conditions | Yield |
---|---|
With toluene-4-sulfonic acid In acetone for 0.25h; Title compound not separated from byproducts; | |
With toluene-4-sulfonic acid In water; acetone at 20℃; for 0.166667h; |