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294-40-6

Basic Information
CAS No.: 294-40-6
Name: Cyclopentasiloxane
Article Data: 3
Molecular Structure:
Molecular Structure of 294-40-6 (Cyclopentasiloxane)
Formula: H10O5 Si5
Molecular Weight: 230.504
Synonyms: 1,3,5,7,9-Pentaoxa-2,4,6,8,10-pentasilacyclodecane;Jeesile CPS 312
PSA: 46.15000
LogP: -4.92300
Synthetic route
4109-96-0

Dichlorosilane

A

cyclotetrasiloxane

B

294-40-6

1,1,3,3,5,5,7,7,9,9-decahydrocyclopentasiloxane

C

295-01-2

1,1,3,3,5,5,7,7,9,9,11,11-dodecahydro-cyclohexasiloxane

Conditions
ConditionsYield
With water In dichloromethane hydrolysis H2SiCl2 in dichloromethane soln. either with stoich. amt. water at -30 to -20°C or by slow, controlled addn. slight excess water at 0°C; products isolated by GC;A 6.1%
B 22.6%
C 12%
4109-96-0

Dichlorosilane

A

cyclotetrasiloxane

B

294-40-6

1,1,3,3,5,5,7,7,9,9-decahydrocyclopentasiloxane

C

295-01-2

1,1,3,3,5,5,7,7,9,9,11,11-dodecahydro-cyclohexasiloxane

D

cyclooctasiloxane

E

295-47-6

cycloheptasiloxane

Conditions
ConditionsYield
In diethyl ether SiH2Cl2 and ether was mixed at -40°C, warming to room temp., addn. of H2O dropwise over 7 min, stirring at room temp. for 30 min; further products; not isolated, detected by GLC;
4109-96-0

Dichlorosilane

A

cyclotetrasiloxane

B

294-40-6

1,1,3,3,5,5,7,7,9,9-decahydrocyclopentasiloxane

C

295-01-2

1,1,3,3,5,5,7,7,9,9,11,11-dodecahydro-cyclohexasiloxane

D

295-47-6

cycloheptasiloxane

Conditions
ConditionsYield
In pentane SiH2Cl2 and ether was mixed at -40°C, warming to room temp., addn. of H2O dropwise over 7 min, stirring at room temp. for 30 min; further products; not isolated, detected by GLC;
4109-96-0

Dichlorosilane

743369-26-8

zinc(II) carbonate

A

cyclotetrasiloxane

B

294-40-6

1,1,3,3,5,5,7,7,9,9-decahydrocyclopentasiloxane

C

295-01-2

1,1,3,3,5,5,7,7,9,9,11,11-dodecahydro-cyclohexasiloxane

Conditions
ConditionsYield
In hexane Product distribution / selectivity; Cooling;
4109-96-0

Dichlorosilane

calcium carbonate

A

cyclotetrasiloxane

B

294-40-6

1,1,3,3,5,5,7,7,9,9-decahydrocyclopentasiloxane

C

295-01-2

1,1,3,3,5,5,7,7,9,9,11,11-dodecahydro-cyclohexasiloxane

Conditions
ConditionsYield
In ethyl acetate Cooling;
554-13-2

lithium carbonate

4109-96-0

Dichlorosilane

A

cyclotetrasiloxane

B

294-40-6

1,1,3,3,5,5,7,7,9,9-decahydrocyclopentasiloxane

C

295-01-2

1,1,3,3,5,5,7,7,9,9,11,11-dodecahydro-cyclohexasiloxane

Conditions
ConditionsYield
In ethyl acetate Cooling;
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     China (Mainland)  |  Contact Details

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    Nanjing Raymon Biotech Co., Ltd. is specialized in developing and marketing middle & high level pharmaceutical intermediates. We are supplying different categories of high-quality

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     China (Mainland)  |  Contact Details

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  • 294-40-6

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    China (Mainland)  |  Contact Details

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    Address:hebei

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    294-40-6

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    Shanghai PengMo Biotechnology Co., Ltd. is engaging in researching, developing, manufacturing and exporting advanced pharmaceutical intermediates and other fine chemicals. Our comp

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     China (Mainland)  |  Contact Details

    Business Type:Lab/Research institutions

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    Do best quality products, erect the morality model Application:Please email us, thanks

    Wuxi Morality Chemical Co., Ltd is specialized in the development and manufacture of industrial additives, bulk chemical intermediates, pharmaceutical raw materials and pesticide

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     China (Mainland)  |  Contact Details

    Business Type:Other

    Tel:+86-510-83597286 17768505220

    Address:B/7F, 321th WuYun Rd, Wanda Plaza, Wuxi City, 214174, China

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