Name: Lithium carbonate
SKU: 554-13-2

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Basic Information

Molecular Structure:
CAS No.:	554-13-2
Name:	Lithium carbonate

Formula:	Li₂CO₃
Molecular Weight:	73.8912
Synonyms:	Lithane;Lithium carbonate;Lithiumcarbonate;Plenur;Liticar;Litard;Limas;Eutimin;Lithea;Priadel;Li2CO3;Phasal;
EINECS:	209-062-5
Density:	2.11 g/cm³
Melting Point:	720 °C
Boiling Point:	333.6 °C at 760 mmHg
Flash Point:	169.8 °C
Solubility:	water: 13 g/L (20 °C)
Appearance:	white fine crystalline powder
Hazard Symbols:	Xn,C,F
Risk Codes:	36/38-41-36/37/38-22-36-34-20/21/22-15-14-11
Safety:	8-43-45-37/39-26-36/37-24/25-36/37/39-16-7/8-3/7/9
Transport Information:	UN 3264 8/PG 3
PSA:	63.19000
LogP:	-2.44700

Synthetic route

: 124-38-9
carbon dioxide

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
With C14H14B2(2-)*2Li(1+) In tetrahydrofuran at 25℃; under 760.051 Torr; Sealed tube; Cooling with liquid nitrogen; Inert atmosphere;	83%
With Tri-n-octylamine; water; lithium chloride In butan-1-ol under 7.50075E-06 Torr;
With lithium hydroxide monohydrate In water for 2.68333h; Kinetics; Time;
With C2H3OS2(1-)*Li(1+) In methanol

: 2Li(1+)*W(CO)5(2-)=Li2{W(CO)5}

: 124-38-9
carbon dioxide

A: 14040-11-0
tungsten hexacarbonyl

B: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In tetrahydrofuran reductive disproportionation; mechanism discussed;; IR;;	A 82% B 74%
In tetrahydrofuran soln. of the W-compound was treated with gasous CO2 at -78°C, warmed to 25°C; solvent removed (vac.), extd. (diethyl ether), ether removed (vac.); IR, MAS;	A 82% B 74%

...Expand

: 584-08-7
potassium carbonate

: lithium chloride

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In not given pptn. from concd. LiCl soln. with excess of K2CO3;;
In not given pptn. from concd. LiCl soln. with excess of K2CO3;;

: lithium nitrate

: 584-08-7
potassium carbonate

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In not given pptn. from concd. LiNO3 soln. with excess of K2CO3;;
In not given pptn. from concd. LiNO3 soln. with excess of K2CO3;;

: lithium sulfate

: 584-08-7
potassium carbonate

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In not given
In not given pptn. from concd. Li2SO4 soln. with excess of K2CO3;;
In not given
In not given pptn. from concd. Li2SO4 soln. with excess of K2CO3;;

: 6108-17-4, 61013-21-6, 61013-23-8, 67299-15-4, 116277-84-0
lithium acetate dihydrate

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
With poly(methyl methacrylate); oxalic acid; Ni(CH3COO)2*4H2O In methanol byproducts: NiO; poly(methyl methacrylate) added; pptd. by adding of oxalic acid soln.; calcined at 298-400°C for 1-15 h in mixed atm. air/N2, at 400-600°C in air or O2; powder XRD;
In neat (no solvent, solid phase) heated for 1 h at 500°C; XRD;

: 6108-17-4, 61013-21-6, 61013-23-8, 67299-15-4, 116277-84-0
lithium acetate dihydrate

: 6018-89-9
nickel(II) acetate tetrahydrate

A: 1313-99-1
nickel(II) oxide

B: lithium nickelate(III)

C: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In water mixt. stirred, heated at 120 °C to remove water, heated at 250 °C for 24 h or at 370 °C for 24 h; detd. by XRD;

...Expand

: 1310-66-3
lithium hydroxide monohydrate

: 6018-89-9
nickel(II) acetate tetrahydrate

A: 1313-99-1
nickel(II) oxide

B: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In neat (no solvent) LiOH*H2O and Ni acetate separately dissolved in H2O; mixed; pH adjusted to 8.5-9.5; heated at 110°C until they were dry; calcined at 300-500°C; monitored by X-ray diffraction;

...Expand

: 1310-66-3
lithium hydroxide monohydrate

: 6018-89-9
nickel(II) acetate tetrahydrate

A: Li2Ni8O10

B: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
In neat (no solvent) LiOH*H2O and Ni acetate separately dissolved in H2O; mixed; pH adjusted to 8.5-9.5; heated at 110°C until they were dry; calcined at 600°C; monitored by X-ray diffraction;

...Expand

: lithium peroxide

: 124-38-9
carbon dioxide

: 554-13-2
lithium carbonate

Conditions

Conditions	Yield
High Pressure; at 400°C, pressure of CO2: 2100 at for 6 h;

Raw Materials

6018-89-9

124-38-9

546-89-4

6108-17-4

1310-66-3

553-91-3

556-63-8

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Specification

Lithium carbonate, its cas register number is 554-13-2. It also can be called Lithonate; Lithium hydroxide, solution; Eskalith; and Lithobid. Lithium carbonate, the most widely used of the compounds, is employed in the production of lithium metal and ft-its and enamels. Together with lithium fluoride (LiF), it serves as an additive for cryolite in the elec-trolytic pot line production of primary aluminum. It also is used to treat manic states and bipolar disorder, and is used in the manufacture of most LITHIUM-ion battery cathodes, which are made of lithlum cobalt oxide. It is manufactured from spodumene, which is by far the most important lithium-containing ore.

Physical properties about Lithium carbonate are: (1)ACD/LogP: -0.809; (2)ACD/LogD (pH 5.5): -1.98; (3)ACD/LogD (pH 7.4): -3.77; (4)ACD/BCF (pH 5.5): 1.00; (5)ACD/BCF (pH 7.4): 1.00; (6)ACD/KOC (pH 5.5): 1.00; (7)ACD/KOC (pH 7.4): 1.00; (8)#H bond acceptors: 3; (9)#H bond donors: 2; (10)Flash Point: 169.8 °C; (11)Enthalpy of Vaporization: 63.37 kJ/mol; (12)Boiling Point: 333.6 °C at 760 mmHg; (13)Vapour Pressure: 2.58E-05 mmHg at 25°C

You can still convert the following datas into molecular structure:
(1)InChI=1S/CH2O3.2Li/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2;
(2)InChIKey=XGZVUEUWXADBQD-UHFFFAOYSA-L;
(3)SmilesC(=O)([O-])[O-].[Li+].[Li+];

The toxicity data is as follows:

Organism	Test Type	Route	Reported Dose (Normalized Dose)	Effect	Source
dog	LD50	oral	500mg/kg (500mg/kg)		"Psychotropic Drugs and Related Compounds," 2nd ed., Usdin, E., and D.H. Efron, Washington, DC, 1972Vol. -, Pg. 436, 1972.
human	TDLo	oral	4111mg/kg (4111mg/kg)	GASTROINTESTINAL: OTHER CHANGES BEHAVIORAL: TREMOR BEHAVIORAL: MUSCLE WEAKNESS	New England Journal of Medicine. Vol. 287, Pg. 867, 1972.
man	TDLo	oral	8mg/kg (8mg/kg)	GASTROINTESTINAL: NAUSEA OR VOMITING SKIN AND APPENDAGES (SKIN): "DERMATITIS, OTHER: AFTER SYSTEMIC EXPOSURE"	American Journal of Psychiatry. Vol. 141, Pg. 909, 1984.
man	TDLo	oral	54mg/kg (54mg/kg)	BEHAVIORAL: SLEEP BEHAVIORAL: "HALLUCINATIONS, DISTORTED PERCEPTIONS"	New Zealand Medical Journal. Vol. 97, Pg. 23, 1984.
man	TDLo	oral	1080mg/kg/13W (1080mg/kg)	SKIN AND APPENDAGES (SKIN): "DERMATITIS, ALLERGIC: AFTER SYSTEMIC EXPOSURE"	Journal of Clinical Psychiatry. Vol. 47, Pg. 330, 1986.
man	TDLo	oral	25gm/kg/4Y-I (25000mg/kg)	BEHAVIORAL: TREMOR SENSE ORGANS AND SPECIAL SENSES: MIOSIS (PUPILLARY CONSTRICTION): EYE	Journal of Clinical Psychiatry. Vol. 46, Pg. 292, 1985.
mouse	LD50	intraperitoneal	236mg/kg (236mg/kg)	BEHAVIORAL: ATAXIA BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX) BEHAVIORAL: EXCITEMENT	Kiso to Rinsho. Clinical Report. Vol. 7, Pg. 1273, 1973.
mouse	LD50	intravenous	497mg/kg (497mg/kg)	LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX)	Kiso to Rinsho. Clinical Report. Vol. 7, Pg. 1273, 1973.
mouse	LD50	oral	531mg/kg (531mg/kg)		Russian Pharmacology and Toxicology Vol. 33, Pg. 266, 1970.
mouse	LD50	subcutaneous	413mg/kg (413mg/kg)		Russian Pharmacology and Toxicology Vol. 33, Pg. 266, 1970.
rat	LD50	intraperitoneal	156mg/kg (156mg/kg)	GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA" LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY)	Kiso to Rinsho. Clinical Report. Vol. 7, Pg. 1273, 1973.
rat	LD50	intravenous	241mg/kg (241mg/kg)	BEHAVIORAL: ALTERED SLEEP TIME (INCLUDING CHANGE IN RIGHTING REFLEX) LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION	Kiso to Rinsho. Clinical Report. Vol. 7, Pg. 1273, 1973.
rat	LD50	oral	525mg/kg (525mg/kg)	LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION BEHAVIORAL: SOMNOLENCE (GENERAL DEPRESSED ACTIVITY) GASTROINTESTINAL: "HYPERMOTILITY, DIARRHEA"	Kiso to Rinsho. Clinical Report. Vol. 7, Pg. 1273, 1973.
rat	LD50	subcutaneous	434mg/kg (434mg/kg)	SENSE ORGANS AND SPECIAL SENSES: LACRIMATION: EYE LUNGS, THORAX, OR RESPIRATION: RESPIRATORY DEPRESSION SKIN AND APPENDAGES (SKIN): HAIR: OTHER	Kiso to Rinsho. Clinical Report. Vol. 7, Pg. 1273, 1973.
women	TDLo	oral	120mg/kg/10D- (120mg/kg)	BEHAVIORAL: EXCITEMENT	Journal of Clinical Psychiatry. Vol. 48, Pg. 81, 1987.
women	TDLo	oral	612mg/kg/44D- (612mg/kg)	SKIN AND APPENDAGES (SKIN): "DERMATITIS, ALLERGIC: AFTER SYSTEMIC EXPOSURE" BEHAVIORAL: SLEEP	American Journal of Psychiatry. Vol. 152, Pg. 956, 1995.
women	TDLo	oral	8760mg/kg/2Y- (8760mg/kg)	ENDOCRINE: EVIDENCE OF THYROID HYPERFUNCTION ENDOCRINE: THYROID WEIGHT (GOITER)	American Journal of Medicine. Vol. 99, Pg. 575, 1995.
women	TDLo	oral	36500mg/kg/10 (36500mg/kg)	ENDOCRINE: DIABETES INSIPIDUS (NEPHROGENIC OR CNS) KIDNEY, URETER, AND BLADDER: URINE VOLUME INCREASED KIDNEY, URETER, AND BLADDER: "CHANGES IN TUBULES (INCLUDING ACUTE RENAL FAILURE, ACUTE TUBULAR NECROSIS)"	Annales de Medecine Interne. Vol. 148, Pg. 284, 1997.
women	TDLo	unreported	556mg/kg/32D (556mg/kg)	BEHAVIORAL: TOXIC PSYCHOSIS	JAMA, Journal of the American Medical Association. Vol. 213, Pg. 865, 1970.

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