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29617-66-1

Basic Information
CAS No.: 29617-66-1
Name: (S)-(-)-2-Chloropropionic acid
Molecular Structure:
Molecular Structure of 29617-66-1 ((S)-(-)-2-Chloropropionic acid)
Formula: C3H5ClO2
Molecular Weight: 108.52
Synonyms: (2S)-2-chloropropanoic acid;(S)-2-Chloropropionic acid;Propionic acid, 2-chloro-, L- (8CI);Propanoic acid, 2-chloro-, (S)-;alpha-L-Chloropropionic acid;S-2-Chloropropionic acid;(S)-2-Chloropropanoic acid;L-2-Chloropropanoic acid;(2S)-Chloropropanoic acid;L-2-chloropropinonical;
EINECS: 411-150-5
Density: 1.285 g/cm3
Melting Point: 4 °C
Boiling Point: 189 °C at 760 mmHg
Flash Point: 68.1 °C
Solubility: soluble in water
Appearance: colourless oil
Hazard Symbols: CorrosiveC
Risk Codes: 21/22-35
Safety: 23-26-28-36/37/39-45
Transport Information: UN 2511 8/PG 3
PSA: 37.30000
LogP: 0.69830
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    Chemical Name: (S)-(-)-2-Chloropropionic acid CAS No.: 29617-66-1 Molecular Fomula:C3H5ClO2 Chemical Structure: Molecular weight: 108.52 Appearance: colorless liquid Assay:98% Appearance: Colorless Liquid Storage:RT. Package:drum Applica

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Chemistry

The Molecular Structure of (S)-(-)-2-Chloropropionic acid (CAS NO.29617-66-1):

Empirical Formula: C3H5ClO2
Molecular Weight: 108.5236 
CAS registry number: 29617-66-1
Appearance: Colourless Oil
IUPAC Name: (2S)-2-chloropropanoic acid  
Nominal Mass: 108 Da
Average Mass: 108.5236 Da
Monoisotopic Mass: 107.997807 Da
Index of Refraction: 1.441
Molar Refractivity: 22.31 cm3
Molar Volume: 84.4 cm3
Surface Tension: 37.6 dyne/cm
Density: 1.285 g/cm3
Flash Point: 68.1 °C
Enthalpy of Vaporization: 46.87 kJ/mol
Boiling Point: 189 °C at 760 mmHg
Vapour Pressure: 0.26 mmHg at 25°C 
InChI
InChI=1/C3H5ClO2/c1-2(4)3(5)6/h2H,1H3,(H,5,6)/t2-/m0/s1
Smiles
C([C@@H](Cl)C)(O)=O
Synonyms: (2S)-Chloropropanoic acid ; (S)-2-Chloropropanoic acid ; (S)-2-Chloropropionic acid ; 2(S)-Chloropropionic acid ; L-2-Chloropropanoic acid ; L-2-Chloropropionic acid ; alpha-L-Chloropropionic acid ; Propanoic acid, 2-chloro-, (S)- ; Propionic acid, 2-chloro-, L- (8CI)  
Product Categories: Chiral Compounds;chiral;Miscellaneous Reagents;Building Blocks for Liquid Crystals;Carboxylic Acids (Chiral);Chiral Building Blocks;Chiral Compounds (Building Blocks for Liquid Crystals);Functional Materials;Synthetic Organic Chemistry

Uses

 (S)-(-)-2-Chloropropionic acid (CAS NO.29617-66-1) is used in the synthesis of muramic acid derivatives;  Preparation of its ester and reaction with protected amino acid  CESIUM salts to depsipeptides.

Toxicity Data With Reference

1、RTECS#: CAS# 29617-66-1: UA2451950 
2、LD50/LC50: RTECS: Not available. 
3、Carcinogenicity: (S)-(-)-2-Chloropropionic Acid - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
4、Other: See actual entry in RTECS for complete information.  

Safety Profile

Hazard Codes: CorrosiveC
Risk Statements: 21/22-35 
R21/22: Harmful in contact with skin and if swallowed
R35: Causes severe burns
Safety Statements: 23-26-28-36/37/39-45 
S23: Do not breathe vapour
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S28: After contact with skin, wash immediately with plenty of soap-suds
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection
S45: In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
RIDADR: UN 2511 8/PG 3
WGK Germany: 1
RTECS: UA2451950
HazardClass: 8
PackingGroup: III
HS Code: 29159080

Specification

(1)Fire Fighting Measures of (S)-(-)-2-Chloropropionic acid (CAS NO.29617-66-1):
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. 
Extinguishing Media: Use foam, dry chemical, or CARBON dioxide      
(2)Handling and Storage of (S)-(-)-2-Chloropropionic Acid
Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood. 
Storage: Store in a cool, dry place. Store in a tightly closed container. Corrosives area.