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Basic Information
CAS No.: 29636-87-1
Name: 4-Hydroxymethyl-5-methylimidazole
Article Data: 18
Molecular Structure:
Molecular Structure of 29636-87-1 (4-Hydroxymethyl-5-methylimidazole)
Formula: C5H8 N2 O
Molecular Weight: 112.131
Synonyms: 1H-Imidazole-4-methanol,5-methyl- (9CI); Imidazole-4(or 5)-methanol, 5(or 4)-methyl- (7CI);Imidazole-4-methanol, 5-methyl- (8CI); 4-(Hydroxymethyl)-5-methyl-1H-imidazole;4-(Hydroxymethyl)-5-methylimidazole; 4-Methyl-5-(hydroxymethyl)imidazole;4-Methyl-5-imidazolemethanol; 5-(Hydroxymethyl)-4-methylimidazole;5-Methyl-1H-imidazole-4-methanol; 5-Methyl-4-imidazolemethanol
EINECS: 249-740-8
Density: 1.231 g/cm3
Melting Point: 136°C
Boiling Point: 389.1 °C at 760 mmHg
Flash Point: 189.1 °C
Solubility: almost transparency
Appearance: White and light brown Crystalsl Powder
Hazard Symbols: R36/37/38:Irritating to eyes, respiratory system and skin.;
Risk Codes: 36/37/38
Safety: 26-36/37/39
PSA: 48.91000
LogP: 0.21040
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With lithium aluminium tetrahydride In tetrahydrofuran at 0℃; for 4h; Reflux;89%
With lithium aluminium tetrahydride In tetrahydrofuran for 4h; Heating;55%
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formaldehyd

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5-methylimidazole-4-carboxylic acid sodium salt

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Conditions
ConditionsYield
With sodium hydroxide; formaldehyd In water65%
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Conditions
ConditionsYield
In water at 40℃;
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Conditions
ConditionsYield
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Conditions
ConditionsYield
With acetic anhydride; sodium nitrite In methanol at 10 - 20℃; for 3.5h;92%
29636-87-1

4(5)-methyl-5(4)-hydroxymethylimidazole

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Conditions
ConditionsYield
With manganese(IV) oxide In tetrahydrofuran for 3h; Oxidation; Heating;85%
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Conditions
ConditionsYield
In acetic acid for 24h; Reflux;82%
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Conditions
ConditionsYield
With manganese(IV) oxide; sodium cyanide at 20℃; for 20h; Oxidation; esterification;70%
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4-chloromethyl-5-methyl-imidazole hydrochloride

Conditions
ConditionsYield
With hydrogenchloride at 100℃; for 0.5h;67%
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Chemistry

Molecular Structure:
Appearance:white and light brown crystalsl powde.
Molecular Formula:C5H8N2O.
Molecular Weight:112.1298.
Density:1.231 g/cm3.
Melting Point:136℃.
Boiling Point:389.1 ℃ at 760 mmHg.
Flash Point:189.1 ℃.