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32765-81-4

Basic Information
CAS No.: 32765-81-4
Name: 1-BROMO-6-(TRIMETHYLAMMONIUM)HEXYL BROMIDE
Article Data: 7
Molecular Structure:
Molecular Structure of 32765-81-4 (1-BROMO-6-(TRIMETHYLAMMONIUM)HEXYL BROMIDE)
Formula: C9H21BrN.Br
Molecular Weight: 303.08
Synonyms: 1-Bromo-6-(trimethylammonium)hexyl Bromide;(6-bromohexyl)-trimethylammonium bromide;6-Bromo-N,N,N-trimethyl-1-hexanaminium Bromide;(6-Brom-hexyl)-trimethyl-ammonium,Bromid;
Melting Point: 98-100 °C
PSA: 0.00000
LogP: -0.34810
Synthetic route
629-03-8

1 ,6-dibromohexane

75-50-3

trimethylamine

32765-81-4

(6-bromohexyl)-trimethylammonium bromide

Conditions
ConditionsYield
In tetrahydrofuran for 24h; Ambient temperature;78%
In tetrahydrofuran at 20℃; for 24h;56%
In diethyl ether; ethanol at 25℃; for 48h;14%
With benzene
In acetone
629-03-8

1 ,6-dibromohexane

32765-81-4

(6-bromohexyl)-trimethylammonium bromide

Conditions
ConditionsYield
With trimethylamine In tetrahydrofuran
With trimethylamine In tetrahydrofuran
26342-09-6

6-amino-1-bromo-n-hexane

616-38-6

carbonic acid dimethyl ester

32765-81-4

(6-bromohexyl)-trimethylammonium bromide

Conditions
ConditionsYield
Stage #1: 6-amino-1-bromo-n-hexane; carbonic acid dimethyl ester In ethanol; toluene at 55℃; under 7500.75 Torr; for 3h;
Stage #2: With hydrogen bromide In ethanol; toluene at 20℃; Solvent; Temperature; Pressure;
553-26-4

4,4'-bipyridine

32765-81-4

(6-bromohexyl)-trimethylammonium bromide

C28H50N4(4+)*4Br(1-)

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 100℃; for 72h; Inert atmosphere; Schlenk technique; Glovebox;80%

telluropheno[2,3-c:5,4-c']bipyridine

32765-81-4

(6-bromohexyl)-trimethylammonium bromide

C28H48N4Te(4+)*4Br(1-)

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 100℃; for 72h; Inert atmosphere; Schlenk technique; Glovebox;75%

selenopheno[2,3-c:5,4-c']bipyridine

32765-81-4

(6-bromohexyl)-trimethylammonium bromide

C28H48N4Se(4+)*4Br(1-)

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 100℃; for 72h; Inert atmosphere; Schlenk technique; Glovebox;72%
41303-74-6

N-desmethyl galantamine

32765-81-4

(6-bromohexyl)-trimethylammonium bromide

10-N-demethyl-10-N-(6'-trimethylammoniumhexyl)-galanthamine bromide

Conditions
ConditionsYield
With sodium carbonate In acetonitrile at 50℃; for 20h;71%
33063-38-6

thieno<2,3-c:5,4-c'>dipyridine

32765-81-4

(6-bromohexyl)-trimethylammonium bromide

C28H48N4S(4+)*4Br(1-)

Conditions
ConditionsYield
In N,N-dimethyl-formamide at 100℃; for 72h; Inert atmosphere; Schlenk technique; Glovebox;70%
32765-81-4

(6-bromohexyl)-trimethylammonium bromide

7-[(3-hydroxy-2-phenylpropanoyl)oxy]-9-methyl-9-[6-(N,N,N-trimethylammonio)hexyl]-3-oxa-9-azatricyclo[3.3.1.02,4]nonan-9-ium dibromide

Conditions
ConditionsYield
In acetonitrile Heating; Sealed tube;31%
51-55-8

Atropine

32765-81-4

(6-bromohexyl)-trimethylammonium bromide

3-[(hydroxy-2-phenylpropanoyl)oxy]-8-methyl-8-[6-(N,N,N-trimethylammonio)hexyl]-8-azabicyclo[3.2.1]octan-8-ium dibromide

Conditions
ConditionsYield
In acetonitrile Heating; Sealed tube;20%
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