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CAS No.: | 334-99-6 | ||||||||||||
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Name: | TRIFLUORONITROSOMETHANE | ||||||||||||
Article Data: | 53 | ||||||||||||
Molecular Structure: | |||||||||||||
Formula: | CF3 N O | ||||||||||||
Molecular Weight: | 99.0123 | ||||||||||||
Synonyms: | Nitrosotrifluoromethane;Trifluoromethyl nitroxide; Trifluoronitrosomethane | ||||||||||||
Density: | 1.54g/cm3 | ||||||||||||
Melting Point: | -196,6°C | ||||||||||||
Boiling Point: | -85°C | ||||||||||||
Flash Point: | °C | ||||||||||||
Hazard Symbols: | |||||||||||||
Risk Codes: | 26/27/28 | ||||||||||||
Safety: |
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PSA: | 29.43000 | ||||||||||||
LogP: | 1.27260 |
(trifluoromethyl)trimethylsilane
trifluoronitrosomethane
Conditions | Yield |
---|---|
With nitrosylchloride; cesium fluoride In 1,2-dimethoxyethane at -196 - 25℃; for 3h; | 92% |
perfluoro-NN'-dimethylethane-1,2-bis(amino-oxyl) diradical
A
trifluoronitrosomethane
B
perfluoro(4,7-dimethyl-1,3-dioxa-2-tetrafluorothia-4,7-diazacycloheptane)
Conditions | Yield |
---|---|
With sulfur tetrafluoride at -196℃; for 24h; | A n/a B 87% |
trifluoronitrosomethane
Conditions | Yield |
---|---|
With Trimethylzinn-nitrat monohydrat In acetonitrile Ambient temperature; | 60% |
Perfluoro-2-azapropen
A
carbon tetrafluoride
B
trifluoronitrosomethane
C
perfluoro(2,4-dimethyl-3-oxa-2,4-diazapentane)
Conditions | Yield |
---|---|
With difluoroether; fluorine; cesium fluoride at -78 - 25℃; for 48h; Addition; Decomposition; | A 11% B 12% C 77% |
trifluoronitrosomethane
Conditions | Yield |
---|---|
With aluminium trichloride; isopropyl nitrate at -15℃; | 47% |
trifluoronitrosomethane
Conditions | Yield |
---|---|
With nitrosylchloride | 98% |
bis(trifluoroacetyl)peroxide
A
trifluoronitrosomethane
B
bis-trifluoromethyl-aminooxyl
Conditions | Yield |
---|---|
With sodium nitrite In 1,1,2-Trichloro-1,2,2-trifluoroethane at 20℃; |
Conditions | Yield |
---|---|
With silver(II) fluoride | A n/a B 90% |
N,N-bis(trifluoromethyl)hydroxylamine
A
hypofluorous acid trifluoromethyl ester
B
trifluoronitrosomethane
C
difluoramino trifluoromethane
D
fluoro-bis-trifluoromethyl-amine
Conditions | Yield |
---|---|
With fluorine; cesium fluoride In trichlorofluoromethane at -78℃; for 24h; Fluorination; Further byproducts given; |
Conditions | Yield |
---|---|
With nitric oxide anion In gas at 36.9℃; Rate constant; | |
With nitrogen(II) oxide Irradiation.im UV-Licht; | |
With nitrogen(II) oxide under 200 Torr; Irradiation; |