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| CAS No.: | 3775-90-4 |
|---|---|
| Name: | 2-(TERT-BUTYLAMINO)ETHYL METHACRYLATE |
| Molecular Structure: | |
|
|
|
| Formula: | C10H19 N O2 |
| Molecular Weight: | 185.266 |
| Synonyms: | Methacrylicacid, 2-(tert-butylamino)ethyl ester (6CI,7CI,8CI); Ethanol, 2-(tert-butylamino)-,methacrylate (ester) (8CI); 2-(tert-Butylamino)ethyl methacrylate; Ageflex FM4; Mhoromer BM 615; N-tert-Butylaminoethyl methacrylate; t-Butylaminoethylmethacrylate; tert-Butylaminoethyl methacrylate |
| EINECS: | 223-228-4 |
| Density: | 0.914 g/mL at 25 °C(lit.) |
| Melting Point: | 100～105℃/12 mm |
| Boiling Point: | 248 °C at 760 mmHg |
| Flash Point: | 103.8 °C |
| Solubility: | 10 % water in ester |
| Appearance: | clear, colourless up to yellowish liquid |
| Hazard Symbols: |
 Xi
|
| Risk Codes: | 36/38-43 |
| Safety: | Poison by intraperitoneal route. See also ESTERS and AMINES. Combustible when exposed to heat or flame. To fight fire, use alcohol foam, water spray or mist, dry chemical. When heated to decomposition it emits toxic fumes of NOx. |
| PSA: | 38.33000 |
| LogP: | 1.88470 |
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- 3775-90-4
2-tert-butylaminoethyl methacrylate
- 24801-88-5
3-(triethoxypropyl) isocyanate
| Conditions | Yield |
|---|---|
| at 45℃; | 100% |
| Conditions | Yield |
|---|---|
| In 2-methyltetrahydrofuran at 90℃; for 4h; Inert atmosphere; Sealed tube; Green chemistry; regioselective reaction; | 89% |
- 3775-90-4
2-tert-butylaminoethyl methacrylate
- 38565-53-6
(2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,9-heptadecafluorononyl)oxirane
| Conditions | Yield |
|---|---|
| With hydroquinone at 150℃; for 17h; | 84% |
| Conditions | Yield |
|---|---|
| With triethylamine In dichloromethane at -10 - 20℃; for 2h; Inert atmosphere; | 80% |
| Conditions | Yield |
|---|---|
| Stage #1: phosgene; 2-(4-aminophenyl)benzothiazole In chloroform; toluene Reflux; Stage #2: 2-tert-butylaminoethyl methacrylate In dichloromethane for 0.0166667h; | 52% |
- 3775-90-4
2-tert-butylaminoethyl methacrylate
- 506-77-4
cyanogen chloride
- 86239-80-7
1-(tert-butyl-cyano-amino)-2-methacryloyloxy-ethane
| Conditions | Yield |
|---|---|
| With potassium carbonate |
| Conditions | Yield |
|---|---|
| With N-propyl 2-pyridinylmethanimine; copper(I) bromide In toluene at 90℃; |
- 79-41-4
poly(methacrylic acid)
- 3775-90-4
2-tert-butylaminoethyl methacrylate
- 97-63-2
methyl methacrylate
- 79-39-0
Methacrylamide
- 79-10-7
acrylic acid
| Conditions | Yield |
|---|---|
| Stage #1: poly(methacrylic acid); 2-tert-butylaminoethyl methacrylate; methyl methacrylate; Methacrylamide; acrylic acid In ethanol; water at 65 - 70℃; for 9h; Stage #2: With tert-butyl peroxypivalate In ethanol; water at 70 - 80℃; for 2.5h; Stage #3: With N-methyl-3-hydroxypropylamine In ethanol; water for 0.166667h; |
- 79-41-4
poly(methacrylic acid)
- 1663-39-4
tert-Butyl acrylate
- 3775-90-4
2-tert-butylaminoethyl methacrylate
- 79-10-7
acrylic acid
| Conditions | Yield |
|---|---|
| Stage #1: poly(methacrylic acid); tert-Butyl acrylate; 2-tert-butylaminoethyl methacrylate; acrylic acid With α,α'-azodiizobutyramidine-dihydrochloride In ethanol; water at 70 - 73℃; for 9h; Stage #2: With tert-butyl peroxyisobutyrate In ethanol; water at 70 - 80℃; for 4.66667h; Stage #3: With 2-Amino-2-methyl-1-propanol In ethanol; water for 0.166667h; Product distribution / selectivity; | |
| Stage #1: poly(methacrylic acid); tert-Butyl acrylate; 2-tert-butylaminoethyl methacrylate; acrylic acid With α,α'-azodiizobutyramidine-dihydrochloride In ethanol; water at 70 - 73℃; for 9h; Stage #2: With tert-butyl peroxyisobutyrate In ethanol; water at 70 - 80℃; for 4.66667h; Stage #3: With 2-Amino-2-methyl-1-propanol In ethanol; water for 0.166667h; Product distribution / selectivity; |
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Chemistry
Product Name: 2-(TERT-BUTYLAMINO)ETHYL METHACRYLATE
Synonyms: 2-(tert-butylamino)-ethanomethacrylate(ester);2-Methyl-2-propenoicacid,2-[(1,1-dimethylethyl)amino]ethylester;2-(tert-Butylamino)ethyl 2-methylacrylate;;2-[(1,1-Dimethylethyl)amino]ethyl2-methyl-2-propenoate;2-Propenoic acid, 2-methyl-, 2-[(1,1-dimethylethyl)amino]ethyl ester;2-propenoicacid,2-methyl-,2-((1,1-dimethylethyl)amino)ethylester;2-[(1,1-Dimethylethyl)amino ]ethyl 2-methyl-2-propenoate
Molecular formula: C10H19NO2
Molar mass: 185.26
Boiling point: 82 °C10 mm Hg(lit.)
density : 0.914 g/mL at 25 °C(lit.)
refractive index : n20/D 1.442(lit.)
Fp : 160 °F
Toxicity Data With Reference
| 1. | ipr-mus LD50:174 mg/kg | JDREAF Journal of Dental Research. 51 (1972),526. |
Consensus Reports
Safety Profile
Poison by intraperitoneal route. See also ESTERS and AMINES. Combustible when exposed to heat or flame. To fight fire, use alcohol foam, water spray or mist, dry chemical. When heated to decomposition it emits toxic fumes of NOx.
Risk Statements :36/38: Irritating to eyes and skin ;43: May cause sensitization by skin contact
Safety Statements : 26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
Hazard Codes : Xi
RIDADR : 1760
WGK Germany : 1