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CAS No.: | 41481-66-7 | ||||||
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Name: | Bis(3-allyl-4-hydroxyphenyl)sulfone | ||||||
Article Data: | 14 | ||||||
Molecular Structure: | |||||||
Formula: | C18H18 O4 S | ||||||
Molecular Weight: | 330.405 | ||||||
Synonyms: | Phenol,4,4'-sulfonylbis[2-(2-propenyl)- (9CI);3,3'-Diallyl-4,4'-dihydroxydiphenylsulfone; 4,4'-Sulfonylbis(2-allylphenol);Bis(3-allyl-4-hydroxyphenyl) sulfone; Bis(4-hydroxy-3-allylphenyl) sulfone;TG-SA; TGSH | ||||||
Density: | 1.253±0.06 g/cm3(Predicted) | ||||||
Melting Point: | 138.5 °C(Solv: toluene (108-88-3)) | ||||||
Boiling Point: | 544.5±50.0 °C(Predicted) | ||||||
Flash Point: | 283.1oC | ||||||
Hazard Symbols: | |||||||
Risk Codes: | 43-51/53 | ||||||
Safety: |
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PSA: | 82.98000 | ||||||
LogP: | 4.46840 |
4,4'-sulfonediphenol
allyl tosylate
3,3′-diallyl-4,4′-dihydroxydiphenylsulfone
Conditions | Yield |
---|---|
With tetrabutyl-ammonium chloride; potassium carbonate In N,N-dimethyl-formamide at 110 - 120℃; for 8h; Large scale; | 98.5% |
With potassium carbonate In N,N-dimethyl-formamide | 30.4 parts (92.1%) |
4,4’-sulfonylbis((allyloxy)benzene)
3,3′-diallyl-4,4′-dihydroxydiphenylsulfone
Conditions | Yield |
---|---|
With α-alanine-N-diacetic acid at 198 - 200℃; for 7h; Temperature; Inert atmosphere; | 96.2% |
With 1,10-Phenanthroline; ethylenediaminetetraacetic acid; sodium hydroxide In paraffin oil at 203 - 207℃; for 7h; Inert atmosphere; | 93.7% |
With iron(III) chloride In 1,2-dichloro-ethane at 60℃; for 15h; Reagent/catalyst; Solvent; Temperature; | 93.9% |
4,4'-sulfonediphenol
3-chloroprop-1-ene
3,3′-diallyl-4,4′-dihydroxydiphenylsulfone
Conditions | Yield |
---|---|
With sodium carbonate; sodium hydroxide In water at 95 - 100℃; for 5h; Solvent; Reagent/catalyst; Temperature; Autoclave; Large scale; | 84.4% |
4,4'-sulfonediphenol
3-chloroprop-1-ene
A
3,3′-diallyl-4,4′-dihydroxydiphenylsulfone
Conditions | Yield |
---|---|
With tetrabutyl-ammonium chloride; sodium carbonate; sodium hydroxide In water; paraffin oil; kerosene at 95 - 100℃; for 5h; Autoclave; Large scale; | A 73.9% B 10.2% |
4,4'-sulfonediphenol
allyl tosylate
3-chloroprop-1-ene
A
3,3′-diallyl-4,4′-dihydroxydiphenylsulfone
Conditions | Yield |
---|---|
Stage #1: 4,4'-sulfonediphenol; allyl tosylate With tetrabutyl-ammonium chloride; potassium carbonate In N,N-dimethyl-formamide at 110 - 120℃; for 8h; Large scale; Stage #2: 3-chloroprop-1-ene In N,N-dimethyl-formamide at 200 - 220℃; for 6h; Large scale; | A 35.3% B 8.6% |
4,4'-sulfonediphenol
3,3′-diallyl-4,4′-dihydroxydiphenylsulfone
Conditions | Yield |
---|---|
Multi-step reaction with 2 steps 1: NaOH, Me4NBr / toluene; H2O / 15 h / 49.9 - 59.9 °C 2: 85 percent / various solvent(s) / 30 h / 207.9 °C View Scheme | |
Multi-step reaction with 2 steps 1.1: potassium carbonate / acetone / 1 h / Inert atmosphere; Reflux 1.2: Reflux; Inert atmosphere 2.1: 4 h / 220 °C / Inert atmosphere View Scheme | |
Multi-step reaction with 2 steps 1: potassium carbonate / acetone / 80 °C / Inert atmosphere 2: 1,2-dichloro-benzene / 8 h / 190 °C / Inert atmosphere View Scheme |
4,4’-sulfonylbis((allyloxy)benzene)
B
3-allyl-4'-allyloxy-4-hydroxydiphenyl sulfone
D
3,3′-diallyl-4,4′-dihydroxydiphenylsulfone
Conditions | Yield |
---|---|
With dmap at 160 - 280℃; for 0.0833333 - 0.333333h; Product distribution / selectivity; Microwave irradiation; | |
With 1,10-Phenanthroline; ascorbic acid In 1,2,3-trichlorobenzene at 210℃; for 7h; Product distribution / selectivity; | |
With 1,10-Phenanthroline; ascorbic acid at 160 - 280℃; for 0.266667h; Product distribution / selectivity; Microwave irradiation; |
4,4’-sulfonylbis((allyloxy)benzene)
3,3′-diallyl-4,4′-dihydroxydiphenylsulfone
Conditions | Yield |
---|---|
With 1,2,3-trichlorobenzene In water | 14.0 parts (93.3%) |
3,3′-diallyl-4,4′-dihydroxydiphenylsulfone
Conditions | Yield |
---|---|
In hexane; acetone at 5℃; for 336h; | 41.7% |
3,3′-diallyl-4,4′-dihydroxydiphenylsulfone
Conditions | Yield |
---|---|
With sodium hydroxide In N,N-dimethyl acetamide |