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| CAS No.: | 4207-56-1 |
|---|---|
| Name: | Phenyltrimethylammonium tribromide |
| Article Data: | 4 |
| Molecular Structure: | |
|
|
|
| Formula: | C9H14N.Br3 |
| Molecular Weight: | 375.929 |
| Synonyms: | Trimethylphenylammonium tribromide;Benzenaminium, N,N,N-trimethyl-, (tribromide);Jacques reagent;Benzenaminium,N,N,N-trimethyl-,(tribromide);40379-10-0;Benzenaminium, N,N, N-trimethyl-, (tribromide);Ammonium, trimethylphenyl-, (tribromide);3426-74-2; |
| EINECS: | 224-127-8 |
| Density: | 2.2071 (rough estimate) |
| Melting Point: | 110-115 °C |
| Solubility: | insoluble |
| Appearance: | orange crystalline powder |
| Hazard Symbols: |
|
| Risk Codes: | 34-37 |
| Safety: | 26-36/37/39-45-24/25 |
| Transport Information: | UN 3261 |
| PSA: | 0.00000 |
| LogP: | 0.57850 |
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N,N,N-trimethylanilinium bromide
- 4207-56-1
phenyltrimethylammonium tribromide
| Conditions | Yield |
|---|---|
| With bromine |
- 4207-56-1
phenyltrimethylammonium tribromide
| Conditions | Yield |
|---|---|
| With bromine |
| Conditions | Yield |
|---|---|
| Stage #1: N,N-dimethyl-aniline; dimethyl sulfate Stage #2: With hydrogen bromide; bromine |
| Conditions | Yield |
|---|---|
| Stage #1: methyl bromide; N,N-dimethyl-aniline Stage #2: With bromine |
- 1445973-84-1
(E)-1-(2-(2-nitrostyryl)-1-(phenylsulfonyl)-1H-indol-3-yl)ethanone
- 4207-56-1
phenyltrimethylammonium tribromide
- 1597408-27-9
(E)-2-bromo-1-[2-(2-nitrostyryl)-1-(phenylsulfonyl)-1H-indol-3-yl]-ethanone
| Conditions | Yield |
|---|---|
| In tetrahydrofuran at 10℃; for 1h; | 78% |
- 27628-06-4
1-(3,4-bis(benzyloxy)phenyl)ethan-1-one
- 4207-56-1
phenyltrimethylammonium tribromide
- 27628-05-3
2-bromo-3',4'-bis(benzyloxy)acetophenone
| Conditions | Yield |
|---|---|
| In tetrahydrofuran for 0.5h; Ambient temperature; | 77.9% |
- 139-28-6
3-acetylphenyl benzoate
- 4207-56-1
phenyltrimethylammonium tribromide
- 139-27-5
3-benzoyloxy-ω-bromoacetophenone
| Conditions | Yield |
|---|---|
| In tetrahydrofuran at 20℃; Inert atmosphere; | 62% |
- 4207-56-1
phenyltrimethylammonium tribromide
A
- 177702-82-8
Ni[(CH3)2Si(NC(CH3)3)2Sn]4Br2
B
- 54677-67-7
(Me2Si(N-t-Bu)2)2Sn
C
- 119395-68-5
1,3-di-t-butyl-2,2-dimethyl-4,4-dibromo-1,3,2,4-diazasilastannetidine
| Conditions | Yield |
|---|---|
| In hexane byproducts: NiBr2, SnBr2; N2-atmosphere; dropwise addn. of ammonium salt to Ni-complex soln. at -78°C; concn., crystn. (-30°C); | A 2.8% B 29% C 28% |
| Conditions | Yield |
|---|---|
| beim gelinden Erwaermen; |
| Conditions | Yield |
|---|---|
| beim Kochen; |
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Chemistry
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Product Name: Phenyltrimethylammonium tribromide
Empirical Formula: C9H14Br3N
Molecular Weight: 375.92616
Canonical SMILES: C[N+](C)(C)C1=CC=CC=C1.Br[Br-]Br
InChI: InChI=1S/C9H14N.Br3/c1-10(2,3)9-7-5-4-6-8-9; 1-3-2/h4-8H,1-3H3; /q+1; -1
InChIKey: PRXNKYBFWAWBNZ-UHFFFAOYSA-N
EINECS: 224-127-8
Product Categories: Ammonium Polyhalides, etc. (Quaternary); Bromination; Halogenation; Quaternary Ammonium Compounds; Synthetic Organic Chemistry
Melting Point: 110-115 °C (dec.)(lit.)
storage temp.: Refrigerator
solubility: ethanol: 10 mg/mL hot, clear
Water Solubility: Insoluble
Sensitive: Hygroscopic
Appearance of Phenyltrimethylammonium tribromide (CAS NO.4207-56-1): orange crystalline powder
Safety Profile
Hazard Codes: 
C
Risk Statements: 34-37
R34:Causes burns.
R37:Irritating to respiratory system
Safety Statements: 26-36/37/39-45-24/25
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection.
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S24/25:Avoid contact with skin and eyes.
RIDADR: UN 3261 8/PG 2
WGK Germany: 3
HazardClass: 6.1(b)
PackingGroup: II
Specification
Phenyltrimethylammonium tribromide (CAS NO.4207-56-1), its Synonyms are Trimethylphenylammonium tribromide ; Jacques reagent ; Ammonium, trimethylphenyl-, (tribromide) ; Benzenaminium, N,N,N-trimethyl-, (tribromide) ; Benzenaminium, N,N,N-trimethyl-, (tribromide) (1:1) .